Addition/Correction pubs.acs.org/JACS
Correction to “Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp3)−H Bonds” Xuesong Wu, Yan Zhao, and Haibo Ge* J. Am. Chem. Soc. 2014, 136, 1789−1792. DOI: 10.1021/ja413131m Page 1789. The symbols after the authors’ names should be corrected to show Xuesong Wu,† Yan Zhao,†,‡,§ Haibo Ge*,†
Page 1791. On the basis of results of deuterium labeling studies described in the text and Supporting Information, the step from nickel complex A to intermediate B in Scheme 1 might be an irreversible process. Therefore, the text describing Scheme 1 should be corrected to read, “Coordination of amide 1 to a NiII species followed by a ligand exchange process under basic conditions generates nickel complex A, which gives rise to the intermediate B via a cyclometalation process.” Correspondingly, Scheme 1 should be corrected as follows: Scheme 1. Proposed Reaction Mechanism
© XXXX American Chemical Society
A
DOI: 10.1021/jacs.5b00104 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
Correction to “Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp3)−H Bonds” Xuesong Wu, Yan Zhao, and Haibo Ge* J. Am. Chem. Soc. 2014, 136, 1789−1792. DOI: 10.1021/ja413131m Page 1789. The symbols after the authors’ names should be corrected to show Xuesong Wu,† Yan Zhao,†,‡,§ Haibo Ge*,†
Page 1791. On the basis of results of deuterium labeling studies described in the text and Supporting Information, the step from nickel complex A to intermediate B in Scheme 1 might be an irreversible process. Therefore, the text describing Scheme 1 should be corrected to read, “Coordination of amide 1 to a NiII species followed by a ligand exchange process under basic conditions generates nickel complex A, which gives rise to the intermediate B via a cyclometalation process.” Correspondingly, Scheme 1 should be corrected as follows: Scheme 1. Proposed Reaction Mechanism
© XXXX American Chemical Society
A
DOI: 10.1021/jacs.5b00104 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
