Angewandte

Chemie

. Angewandte Corrigendum The absolute configuration of maximiscin (1) has been revised as shown. The authors determined an isomeric product was formed when 1 was held in [D6]DMSO under the experimental conditions employed for VCD spectroscopy. In this instance, the resulting artifact led to a misinterpretation of the experimental VCD data and an incorrect assignment of the absolute configuration of 1. The revised assignment is supported based on a reconsideration of 1H NMR 3JH–H data, tracking the fate and disposition of several selectively labeled (13C) positions in the shikimate-derived portion of 1, and by comparing the experimental ECD spectrum of 1 with DFT-calculated data prepared for several of its diastereomers.

Crowdsourcing Natural Products Discovery to Access Uncharted Dimensions of Fungal Metabolite Diversity L. Du, A. J. Robles, J. B. King, D. R. Powell, A. N. Miller, S. L. Mooberry,* R. H. Cichewicz*

804–809

Angew. Chem. 2014, 53 DOI: 10.1002/anie.201306549

Angew. Chem. Int. Ed. 2015, 53, 6657 – 6671

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6671