Supporting Information Copyright Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, 2014
Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO2 Nanowire Microspheres Mosaed Alhumaimess,[a, b] Zhongjie Lin,[a] Qian He,[c] Li Lu,[c] Nickolaos Dimitratos,[a] Nicholas F. Dummer,[a] Marco Conte,[a] Stuart H. Taylor,[a] Jonathan K. Bartley,[a] Christopher J. Kiely,[b] and Graham J. Hutchings*[a]
chem_201303355_sm_miscellaneous_information.pdf
Supplemental information
Oxidation of benzyl alcohol and carbon monoxide using gold nanoparticles supported on nanostructured MnO2 Mosaed Alhumaimess,[a][b] Zhongjie Lin,[a] Qian He,[c] Li Lu,[c] Nickolaos Dimitratos,[a] Nicholas F. Dummer[a], Marco Conte,[a] Stuart H. Taylor,[a] Jonathan K. Bartley,[a] Christopher J. Kiely[c] and Graham J. Hutchings*[a]
Figure S1 CO oxidation over Au/MnO2 catalysts prepared using the sol-immobilisation method: a) flow rate of 20 ml min-1, 100 mg catalyst; b) flow rate of 40 ml min-1.
a WSI 1% Au/MnO2-96h WSI 1% Au/MnO2-72h WSI 1% Au/MnO2-120h WSI 1% Au/MnO2-240h WSI 1% Au/MnO2-48h
100
Conversion/%
80 60
WSI 1% Au/MnO2-24h WSI 1% Au/MnO2-6h WSI 1% Au/MnO2-12h
40
SI 1% Au/MnO2-96h SI 1% Au/MnO -72h SI 1% Au/MnO22-120h SI 1% Au/MnO -240h SI 1% Au/MnO22-48h
20 0
SI 1% Au/MnO -24h SI 1% Au/MnO22-12h SI 1% Au/MnO2-6h
0
20
40
60
80
100 120 140 160
Time (min)
b WSI 1% Au//MnO2-96h,100mg WSI 1% Au/MnO2-72h,100mg WSI 1% Au//MnO2-120h,100mg WSI 1% Au//MnO2-240h,100mg WSI 1% Au/MnO2-96h,50mg WSI 1% Au/MnO2-48h,100mg
100
Conversion/%
80 60
WSI 1% Au/MnO2-72h,50mg
40
WSI 1% Au/MnO2-120h,50mg
20 0
0
20
40
60
80
100 120 140 160
Time/min
Figure S2 CO oxidation over Au/MnO2 catalysts prepared using deposition precipitation: a) flow rate of 20 ml min-1, 100 mg catalyst; b) flow rate of 40 ml min-1.
a 1%Au/MnO2-96h 1%Au/MnO2-72h 1%Au/MnO2-120h 1%Au/MnO2-240h 1%Au/MnO2-48h
100
Conversion/%
80 60
1%Au/MnO2-12h
40 20 0
0
20
40
60
80
100 120 140 160
Time/min)
b 1% Au/MnO2-96h,100mg 1% Au/MnO2-72h,100mg 1% Au/MnO2-120h,100mg 1% Au/MnO2-240h, 100mg 1% Au/MnO2-96h,50mg 1% Au/MnO2-48h,100mg
Conversion/%
100 80
1% Au/MnO2-72h,50mg 1% Au/MnO2-120h,50mg 1% Au/MnO2-96h,25mg
60
1% Au/MnO2-240h,50mg
40 20 0
0
20
40
60
80
100 120 140 160
Time/min
Oxidation of Benzyl Alcohol and Carbon Monoxide Using Gold Nanoparticles Supported on MnO2 Nanowire Microspheres Mosaed Alhumaimess,[a, b] Zhongjie Lin,[a] Qian He,[c] Li Lu,[c] Nickolaos Dimitratos,[a] Nicholas F. Dummer,[a] Marco Conte,[a] Stuart H. Taylor,[a] Jonathan K. Bartley,[a] Christopher J. Kiely,[b] and Graham J. Hutchings*[a]
chem_201303355_sm_miscellaneous_information.pdf
Supplemental information
Oxidation of benzyl alcohol and carbon monoxide using gold nanoparticles supported on nanostructured MnO2 Mosaed Alhumaimess,[a][b] Zhongjie Lin,[a] Qian He,[c] Li Lu,[c] Nickolaos Dimitratos,[a] Nicholas F. Dummer[a], Marco Conte,[a] Stuart H. Taylor,[a] Jonathan K. Bartley,[a] Christopher J. Kiely[c] and Graham J. Hutchings*[a]
Figure S1 CO oxidation over Au/MnO2 catalysts prepared using the sol-immobilisation method: a) flow rate of 20 ml min-1, 100 mg catalyst; b) flow rate of 40 ml min-1.
a WSI 1% Au/MnO2-96h WSI 1% Au/MnO2-72h WSI 1% Au/MnO2-120h WSI 1% Au/MnO2-240h WSI 1% Au/MnO2-48h
100
Conversion/%
80 60
WSI 1% Au/MnO2-24h WSI 1% Au/MnO2-6h WSI 1% Au/MnO2-12h
40
SI 1% Au/MnO2-96h SI 1% Au/MnO -72h SI 1% Au/MnO22-120h SI 1% Au/MnO -240h SI 1% Au/MnO22-48h
20 0
SI 1% Au/MnO -24h SI 1% Au/MnO22-12h SI 1% Au/MnO2-6h
0
20
40
60
80
100 120 140 160
Time (min)
b WSI 1% Au//MnO2-96h,100mg WSI 1% Au/MnO2-72h,100mg WSI 1% Au//MnO2-120h,100mg WSI 1% Au//MnO2-240h,100mg WSI 1% Au/MnO2-96h,50mg WSI 1% Au/MnO2-48h,100mg
100
Conversion/%
80 60
WSI 1% Au/MnO2-72h,50mg
40
WSI 1% Au/MnO2-120h,50mg
20 0
0
20
40
60
80
100 120 140 160
Time/min
Figure S2 CO oxidation over Au/MnO2 catalysts prepared using deposition precipitation: a) flow rate of 20 ml min-1, 100 mg catalyst; b) flow rate of 40 ml min-1.
a 1%Au/MnO2-96h 1%Au/MnO2-72h 1%Au/MnO2-120h 1%Au/MnO2-240h 1%Au/MnO2-48h
100
Conversion/%
80 60
1%Au/MnO2-12h
40 20 0
0
20
40
60
80
100 120 140 160
Time/min)
b 1% Au/MnO2-96h,100mg 1% Au/MnO2-72h,100mg 1% Au/MnO2-120h,100mg 1% Au/MnO2-240h, 100mg 1% Au/MnO2-96h,50mg 1% Au/MnO2-48h,100mg
Conversion/%
100 80
1% Au/MnO2-72h,50mg 1% Au/MnO2-120h,50mg 1% Au/MnO2-96h,25mg
60
1% Au/MnO2-240h,50mg
40 20 0
0
20
40
60
80
100 120 140 160
Time/min
