Surface plasmon resonance modulation in nanopatterned Au gratings by the insulatormetal transition in vanadium dioxide films M. Beebe,1,* L. Wang,1 S. E. Madaras,1 J. M. Klopf,1 Z. Li,1 D. Brantley,1 M. Heimburger,1 R. A. Wincheski,2 S. Kittiwatanakul,3 J. Lu,3 S. A. Wolf,3,4 and R. A. Lukaszew1 1
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187, USA 2 NASA Langley Research Center, Hampton, Virginia 23681, USA 3 Department of Material Sciences and Engineering, University of Virginia, Charlottesville, Virginia 22904, USA 4 Department of Physics, University of Virginia, Charlottesville, Virginia 22904, USA *[email protected]
Abstract: Correlated experimental and simulation studies on the modulation of Surface Plasmon Polaritons (SPP) in Au/VO2 bilayers are presented. The modification of the SPP wave vector by the thermallyinduced insulator-to-metal phase transition (IMT) in VO2 was investigated by measuring the optical reflectivity of the sample. Reflectivity changes are observed for VO2 when transitioning between the insulating and metallic states, enabling modulation of the SPP in the Au layer by the thermally induced IMT in the VO2 layer. Since the IMT can also be optically induced using ultrafast laser pulses, we postulate the viability of SPP ultrafast modulation for sensing or control. ©2015 Optical Society of America OCIS codes: (050.2770) Gratings; (240.0310) Thin films; (240.6680) Surface plasmons; (310.6860) Thin films, optical properties; (310.6628) Subwavelength structures, nanostructures; (310.6845) Thin film devices and applications.
References and links 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13.
N. I. Zheludev and Y. S. Kivshar, “From metamaterials to metadevices,” Nat. Mater. 11(11), 917–924 (2012). L. Wang, K. Yang, C. Clavero, A. J. Nelson, K. J. Carroll, E. E. Carpenter, and R. A. Lukaszew, “Localized surface plasmon resonance enhanced magneto-optical activity in core-shell Fe-Ag nanoparticles,” J. Appl. Phys. 107, 09B303 (2010). X. Huang, I. H. El-Sayed, W. Qian, and M. A. El-Sayed, “Cancer cell imaging and photothermal therapy in the near-infrared region by using Gold nanorods,” J. Am. Chem. Soc. 128(6), 2115–2120 (2006). W. L. Barnes, A. Dereux, and T. W. Ebbesen, “Surface plasmon subwavelength optics,” Nature 424(6950), 824– 830 (2003). A. Cavalleri, C. Tóth, C. W. Siders, J. A. Squier, F. Ráksi, P. Forget, and J. C. Kieffer, “Femtosecond structural dynamics in VO2 during an ultrafast solid-solid phase transition,” Phys. Rev. Lett. 87(23), 237401 (2001). F. J. Morin, “Oxides which show a metal-to-insulator transition at the Neel temperature,” Phys. Rev. Lett. 3(1), 34–36 (1959). S. Kittiwatanakul, J. Laverock, D. Newby, K. E. Smith, S. A. Wolf, and J. Lu, “Transport behavior and electronic structure of phase pure VO2 thin films grown on c-plane sapphire under different O2 partial pressure,” J. Appl. Phys. 114(5), 053703 (2013). S. Lysenko, A. Rúa, V. Vikhnin, F. Fernández, and H. Liu, “Insulator-to-metal phase transition and recovery processes in VO2 thin films after femtosecond laser excitation,” Phys. Rev. B 76(3), 035104 (2007). M. Rini, Z. Hao, R. W. Schoenlein, C. Giannetti, F. Parmigiani, S. Fourmaux, J. C. Kieffer, A. Fujimori, M. Onoda, S. Wall, and A. Cavalleri, “Optical switching in VO2 films by below-gap excitation,” Appl. Phys. Lett. 92(18), 181904 (2008). B. Wang and G. P. Wang, “Plasmon Bragg reflectors and nanocavities on flat metallic surfaces,” Appl. Phys. Lett. 87(1), 013107 (2005). H. Raether, Surface Plasmons on Smooth and Rough Surfaces and on Gratings (Springer-Verlag, 1986). J. Nag, “The solid-solid phase transition in vanadium dioxide thin films: synthesis, physics and application,” Ph.D. thesis (Vanderbilt, Nashville, TN, 2011). J. Y. Suh, E. U. Donev, R. Lopez, L. C. Feldman, and R. F. Haglund, “Modulated optical transmission of subwavelength hole arrays in metal-VO2 films,” Appl. Phys. Lett. 88(13), 133115 (2006).
#232977 - $15.00 USD © 2015 OSA
Received 22 Jan 2015; revised 1 May 2015; accepted 4 May 2015; published 12 May 2015 18 May 2015 | Vol. 23, No. 10 | DOI:10.1364/OE.23.013222 | OPTICS EXPRESS 13222
14. M. J. Dicken, K. Aydin, I. M. Pryce, L. A. Sweatlock, E. M. Boyd, S. Walavalkar, J. Ma, and H. A. Atwater, “Frequency tunable near-infrared metamaterials based on VO2 phase transition,” Opt. Express 17(20), 18330– 18339 (2009). 15. K. G. West, J. Lu, J. Yu, D. Kirkwood, W. Chen, Y. Pei, J. Claassen, and S. A. Wolf, “Growth and characterization of vanadium dioxide thin films prepared by reactive-biased target ion beam deposition,” J. Vac. Sci. Technol. A 26(1), 133–139 (2008). 16. L. Wang, E. Radue, S. Kittiwatanakul, C. Clavero, J. Lu, S. A. Wolf, I. Novikova, and R. A. Lukaszew, “Surface plasmon polaritons in VO2 thin films for tunable low-loss plasmonic applications,” Opt. Lett. 37(20), 4335–4337 (2012). 17. E. Radue, E. Crisman, L. Wang, S. Kittiwatanakul, J. Lu, S. A. Wolf, R. Wincheski, R. A. Lukaszew, and I. Novikova, “Effect of a substrate-induced microstructure on the optical properties of the insulator-metal transition temperature in VO2 thin films,” J. Appl. Phys. 113(23), 233104 (2013). 18. Grating Solver Development Co.”, retrieved http://www.gsolver.com/. 19. E. D. Palik, Handbook of Optical Constants of Solids (Academic, 1998). 20. H. W. Verleur, A. S. Barker, and C. N. Berglund, “Optical properties of VO2 between 0.25 and 5 eV,” Phys. Rev. 172(3), 788–798 (1968).
1. Introduction Current interest in SPP technology is focused on the development of nanoscale optical devices to control the propagation of light in sub-wavelength geometries [1–4]. The use of photons and electrons together in such technologies is desirable for developing optoelectronic protocols to speed up information processing and transmission, as well as for biological sensing and new imaging techniques. There are a number of materials and structures with unique properties that can be exploited for these applications, including vanadium dioxide (VO2). VO2 is well-known as a material exhibiting an insulator-to-metal phase transition (IMT) that can be optically [5], thermally [6], and electrically [7] induced, and optical switches using VO2 have gained attention due to their extremely fast switching speeds (
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187, USA 2 NASA Langley Research Center, Hampton, Virginia 23681, USA 3 Department of Material Sciences and Engineering, University of Virginia, Charlottesville, Virginia 22904, USA 4 Department of Physics, University of Virginia, Charlottesville, Virginia 22904, USA *[email protected]
Abstract: Correlated experimental and simulation studies on the modulation of Surface Plasmon Polaritons (SPP) in Au/VO2 bilayers are presented. The modification of the SPP wave vector by the thermallyinduced insulator-to-metal phase transition (IMT) in VO2 was investigated by measuring the optical reflectivity of the sample. Reflectivity changes are observed for VO2 when transitioning between the insulating and metallic states, enabling modulation of the SPP in the Au layer by the thermally induced IMT in the VO2 layer. Since the IMT can also be optically induced using ultrafast laser pulses, we postulate the viability of SPP ultrafast modulation for sensing or control. ©2015 Optical Society of America OCIS codes: (050.2770) Gratings; (240.0310) Thin films; (240.6680) Surface plasmons; (310.6860) Thin films, optical properties; (310.6628) Subwavelength structures, nanostructures; (310.6845) Thin film devices and applications.
References and links 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13.
N. I. Zheludev and Y. S. Kivshar, “From metamaterials to metadevices,” Nat. Mater. 11(11), 917–924 (2012). L. Wang, K. Yang, C. Clavero, A. J. Nelson, K. J. Carroll, E. E. Carpenter, and R. A. Lukaszew, “Localized surface plasmon resonance enhanced magneto-optical activity in core-shell Fe-Ag nanoparticles,” J. Appl. Phys. 107, 09B303 (2010). X. Huang, I. H. El-Sayed, W. Qian, and M. A. El-Sayed, “Cancer cell imaging and photothermal therapy in the near-infrared region by using Gold nanorods,” J. Am. Chem. Soc. 128(6), 2115–2120 (2006). W. L. Barnes, A. Dereux, and T. W. Ebbesen, “Surface plasmon subwavelength optics,” Nature 424(6950), 824– 830 (2003). A. Cavalleri, C. Tóth, C. W. Siders, J. A. Squier, F. Ráksi, P. Forget, and J. C. Kieffer, “Femtosecond structural dynamics in VO2 during an ultrafast solid-solid phase transition,” Phys. Rev. Lett. 87(23), 237401 (2001). F. J. Morin, “Oxides which show a metal-to-insulator transition at the Neel temperature,” Phys. Rev. Lett. 3(1), 34–36 (1959). S. Kittiwatanakul, J. Laverock, D. Newby, K. E. Smith, S. A. Wolf, and J. Lu, “Transport behavior and electronic structure of phase pure VO2 thin films grown on c-plane sapphire under different O2 partial pressure,” J. Appl. Phys. 114(5), 053703 (2013). S. Lysenko, A. Rúa, V. Vikhnin, F. Fernández, and H. Liu, “Insulator-to-metal phase transition and recovery processes in VO2 thin films after femtosecond laser excitation,” Phys. Rev. B 76(3), 035104 (2007). M. Rini, Z. Hao, R. W. Schoenlein, C. Giannetti, F. Parmigiani, S. Fourmaux, J. C. Kieffer, A. Fujimori, M. Onoda, S. Wall, and A. Cavalleri, “Optical switching in VO2 films by below-gap excitation,” Appl. Phys. Lett. 92(18), 181904 (2008). B. Wang and G. P. Wang, “Plasmon Bragg reflectors and nanocavities on flat metallic surfaces,” Appl. Phys. Lett. 87(1), 013107 (2005). H. Raether, Surface Plasmons on Smooth and Rough Surfaces and on Gratings (Springer-Verlag, 1986). J. Nag, “The solid-solid phase transition in vanadium dioxide thin films: synthesis, physics and application,” Ph.D. thesis (Vanderbilt, Nashville, TN, 2011). J. Y. Suh, E. U. Donev, R. Lopez, L. C. Feldman, and R. F. Haglund, “Modulated optical transmission of subwavelength hole arrays in metal-VO2 films,” Appl. Phys. Lett. 88(13), 133115 (2006).
#232977 - $15.00 USD © 2015 OSA
Received 22 Jan 2015; revised 1 May 2015; accepted 4 May 2015; published 12 May 2015 18 May 2015 | Vol. 23, No. 10 | DOI:10.1364/OE.23.013222 | OPTICS EXPRESS 13222
14. M. J. Dicken, K. Aydin, I. M. Pryce, L. A. Sweatlock, E. M. Boyd, S. Walavalkar, J. Ma, and H. A. Atwater, “Frequency tunable near-infrared metamaterials based on VO2 phase transition,” Opt. Express 17(20), 18330– 18339 (2009). 15. K. G. West, J. Lu, J. Yu, D. Kirkwood, W. Chen, Y. Pei, J. Claassen, and S. A. Wolf, “Growth and characterization of vanadium dioxide thin films prepared by reactive-biased target ion beam deposition,” J. Vac. Sci. Technol. A 26(1), 133–139 (2008). 16. L. Wang, E. Radue, S. Kittiwatanakul, C. Clavero, J. Lu, S. A. Wolf, I. Novikova, and R. A. Lukaszew, “Surface plasmon polaritons in VO2 thin films for tunable low-loss plasmonic applications,” Opt. Lett. 37(20), 4335–4337 (2012). 17. E. Radue, E. Crisman, L. Wang, S. Kittiwatanakul, J. Lu, S. A. Wolf, R. Wincheski, R. A. Lukaszew, and I. Novikova, “Effect of a substrate-induced microstructure on the optical properties of the insulator-metal transition temperature in VO2 thin films,” J. Appl. Phys. 113(23), 233104 (2013). 18. Grating Solver Development Co.”, retrieved http://www.gsolver.com/. 19. E. D. Palik, Handbook of Optical Constants of Solids (Academic, 1998). 20. H. W. Verleur, A. S. Barker, and C. N. Berglund, “Optical properties of VO2 between 0.25 and 5 eV,” Phys. Rev. 172(3), 788–798 (1968).
1. Introduction Current interest in SPP technology is focused on the development of nanoscale optical devices to control the propagation of light in sub-wavelength geometries [1–4]. The use of photons and electrons together in such technologies is desirable for developing optoelectronic protocols to speed up information processing and transmission, as well as for biological sensing and new imaging techniques. There are a number of materials and structures with unique properties that can be exploited for these applications, including vanadium dioxide (VO2). VO2 is well-known as a material exhibiting an insulator-to-metal phase transition (IMT) that can be optically [5], thermally [6], and electrically [7] induced, and optical switches using VO2 have gained attention due to their extremely fast switching speeds (
