The millimeter wave spectrum of methyl cyanate: a laboratory study and astronomical search in space.

Europe PMC Funders Group Author Manuscript Astron Astrophys. Author manuscript; available in PMC 2016 October 07. Published in final edited form as: Astron Astrophys. 2016 July ; 591: . doi:10.1051/0004-6361/201628140.

Europe PMC Funders Author Manuscripts

The millimeter wave spectrum of methyl cyanate: a laboratory study and astronomical search in space ⋆,,⋆⋆ L. Kolesniková1, J. L. Alonso1, C. Bermúdez1, E. R. Alonso1, B. Tercero2, J. Cernicharo2, and J.-C. Guillemin3 1Grupo

de Espectroscopía Molecular (GEM), Edificio Quifima, Área de Química-Física, Laboratorios de Espectroscopia y Bioespectroscopia, Parque Científico UVa, Unidad Asociada CSIC, Universidad de Valladolid, 47011 Valladolid, Spain

2Instituto

de Ciencia de Materiales de Madrid, CSIC, C/ Sor Juana Inés de la Cruz 3, 28049 Cantoblanco, Spain

3Institut

des Sciences Chimiques de Rennes, École Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, 11 Allée de Beaulieu, CS 50837, 35708 Rennes Cedex 7, France

Abstract Aims—The recent discovery of methyl isocyanate (CH3NCO) in Sgr B2(N) and Orion KL makes methyl cyanate (CH3OCN) a potential molecule in the interstellar medium. The aim of this work is to fulfill the first requirement for its unequivocal identification in space, i.e. the availability of transition frequencies with high accuracy.


Methods—The room-temperature rotational spectrum of methyl cyanate was recorded in the millimeter wave domain from 130 to 350 GHz. All rotational transitions revealed A-E splitting owing to methyl internal rotation and were globally analyzed using the ERHAM program. Results—The data set for the ground torsional state of methyl cyanate exceeds 700 transitions within J″ = 10 – 35 and and newly derived spectroscopic constants reproduce the spectrum close to the experimental uncertainty. Spectral features of methyl cyanate were then searched for in Orion KL, Sgr B2(N), B1-b, and TMC-1 molecular clouds. Upper limits to the column density of methyl cyanate are provided. Keywords astrochemistry; ISM: molecules; line: identification; astronomical databases: miscellaneous; ISM: individual objects: Orion KL, Sgr B2(N), B1-b, TMC-1

1

Introduction Organic molecules containing abundant interstellar elements H, C, N, and O are the prime target for both astrophysicists and spectroscopists to intensively search for in the interstellar

⋆⋆Tables 3 and 4 are only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http:// cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/ ⋆This paper makes use of the following ALMA data: ADS/JAO.ALMA#2011.0.00009.SV.

Kolesniková et al.

Page 2


medium (ISM). One of the simplest, the isocyanic acid (HNCO), was detected with high abundances in a variety of Galactic sources, as well as in the external galaxies (see Quan et al. 2010; Brünken et al. 2010, and references therein). Cyanic acid (HOCN) and fulminic acid (HCNO), two energetically less stable isomers of isocyanic acid with predicted relative energies of 24.7 and 70.7 kcal mol−1, respectively (see Schuurman et al. 2004), were also successfully observed in space (Brünken et al. 2010, 2009; Marcelino et al. 2010, 2009). The choice of new molecules to be searched for is usually justified by analogy with the detected molecules and plausible chemical reactions that occur in the ISM. Methyl substituted derivatives of isocyanic acid and its isomers could thus be suggested as logical candidates. Among the members of the open-chain methyl derivatives, methyl isocyanate (CH3NCO) is the lowest-energy isomer, followed by methyl cyanate (CH3OCN), acetonitrile N-oxide (CH3CNO), and methyl fulminate (CH3ONC). Very recently, methyl isocyanate was detected on the surface of the comet 67P/Churyumov-Gerasimenko (Goesmann et al. 2015) as well as in the molecular clouds Sgr B2 and Orion KL (Halfen et al. 2015; Cernicharo et al. 2016). Owing to relatively high abundances of methyl isocyanate found by Cernicharo et al. (2016), the search for methyl cyanate in space, which uses millimeter wave astronomy, looks promising. Methyl cyanate (Fig. 1) is predicted to be higher in energy with respect to methyl isocyanate by 25.1 kcal mol−1 (Pasinszki & Westwood 2001), i.e. close to that of cyanic acid with respect to isocyanic acid. Moreover, sizable dipole moment components of | µa| = 4.07 (6) D and |µb| = 1.24 (40) D (Sakaizumi et al. 1990) make the possible detection of this metastable isomer relatively favourable.


An attempt to observe methyl cyanate unambiguously in the ISM requires a previous good knowledge of its rotational spectrum in the laboratory. Until this work, only Stark-modulated spectra were recorded up to 50 GHz (Sakaizumi et al. 1990, 1993, 1995). Seven A and seven E transitions, which resulted from the methyl group internal rotation, were reported and analyzed for the ground torsional state and a barrier to internal rotation of 399 cm−1 was derived (Sakaizumi et al. 1995). Lack of accurate laboratory millimeter wave data thus initiated new spectroscopic measurements over the frequency range from 130 to 350 GHz. A new set of spectroscopic constants could reproduce the millimeter wave spectrum within the experimental uncertainty, which could then be used to guide the search for millimeter wave signatures of methyl cyanate towards various interstellar sources. In this work, a search was conducted towards the molecular clouds Orion KL, Sgr B2(N), B1-b and TMC-1, and the results are discussed in Section 4.

2

Experimental details Methyl cyanate was generated according to Pasinszki & Westwood (1995) by gas-solid reaction of the evaporated O-methyl thiocarbamate (CH3OC(S)NH2) with yellow mercury oxide (HgO, Sigma Aldrich) packed into a tube in half-section in a vacuum line (0.3 mbar pressure). A sample of O-methyl thiocarbamate was prepared according to the method given in Davies & Maclaren (1951). To remove the water, which is a by-product, the reaction products were passed through a short tube (15 cm) filled in half-section with phosphorus pentoxide (P2O5, Sigma Aldrich). Dried products were collected in the liquid nitrogen Utube trap, which was then connected to the sample cell of the spectrometer. Vapour pressure of the trapped sample near −60°C was enough to fill the cell up to a total pressure of about Astron Astrophys. Author manuscript; available in PMC 2016 October 07.

Kolesniková et al.

Page 3

25 µbar. Undiluted methyl cyanate has been described as an extremely unstable compound (Jensen et al. 1965). Initial experiments were performed in the flow mode. However, later it was found that the measurements could be performed in the closed cell for several hours. Isocyanic acid and methyl isocyanate were found to be major impurities.


The rotational spectra were recorded at room temperature using the Valladolid millimeter wave spectrometer described in detail elsewhere (Daly et al. 2014). The measured frequency region from 130 to 350 GHz was reached by sequential multiplication of the basic synthesizer frequency (≤ 20 GHz) by amplifier-multiplier chains (VDI, Inc.). The synthesizer output was frequency modulated at f = 10.2 kHz with a modulation depth of 30 kHz. The signal was detected by solid-state zero-bias detectors (VDI, Inc.) and further processed by a lock-in amplifier using 2 f detection. The resulting second derivative shape of the lines was fitted to the Gaussian profile function and the uncertainty of the isolated welldeveloped lines was estimated to be better than 50 kHz.

3

Analysis of the spectra


Methyl cyanate is a near-prolate asymmetric top with Cs symmetry and its molecular geometry is shown in Fig. 1. Two characteristic features can be found in the methyl cyanate rotational spectra. Firstly, the dipole moment component along the a-axis is much larger than the component along the b-axis, therefore, the rotational spectrum is dominated by strong atype R-branch transitions. These transitions usually occur in groups with the central part situated approximately at (B +C)(J″ + 1). Each group corresponds to specific J″ + 1 ← J″ and is formed by transitions with different Ka. Figure 2 illustrates an example of this type of group for J″ = 13. Two transitions always appear for each Ka > 0 and lower Ka pairs are more widely split than the higher Ka ones (see Fig. 2). Secondly, methyl cyanate contains one C3v internal rotor (methyl group), which can undergo a torsion motion with respect to the rest of the molecule leading to the splitting of the rotational levels into A and E sublevels. As a result, all transitions appear as the A-E doublets with separation from units to tens of MHz (see Fig. 2), which leads to higher line density of the spectrum and complicates its analysis. For completeness, methyl cyanate moreover possess one nucleus with a nonzero electric quadrupole moment (14N), however, no quadrupole hyperfine structure has been observed in the rotational spectra. After eliminating the lines that correspond to the isocyanic acid and methyl isocyanate, the assignment was started with the search for the strongest low-Ka transitions using predictions based on the results of Sakaizumi et al. (1995). An example of the predictions of the rotational transitions in the millimeter wave domain is shown in the upper part of Fig. 3. If compared with the experimental spectrum in the middle part of Fig. 3, large discrepancies occur between the observed and predicted frequencies. This is a typical problem of the extrapolation outside the experimentally known data set that makes the confident search in the millimeter wave line surveys impossible. Loomis-Wood-type plots from AABS package (Kisiel et al. 2005) were very useful for reaching conclusive assignments. The first set of rotational and centrifugal distortion constants was obtained from the separate fit of the A transitions with standard Watson’s A-reduced semirigid rotor Hamiltonian

Astron Astrophys. Author manuscript; available in PMC 2016 October 07.

Kolesniková et al.

Page 4

(Watson 1977). Next, the E transitions were searched for and added step-by-step, starting at low J and Ka and moving up progressively. Both A and E transitions were finally assigned


within J″ = 10−35 and and analyzed simultaneously using the ERHAM program (Groner 1997, 2012). The structural model from Sakaizumi et al. (1993) was adopted to derive initial values of the internal motion parameters ρ and β, which represent the magnitude of the ρ-vector and the angle between this vector and the principal a-axis, respectively. The rotational line sequences of α-type R-branch transitions for J″ ≤ 25 and K ″ ≤ 8 were analyzed using the set of the rotational constants, centrifugal distortion constants up to the sixth order, ρ and β parameters, first two energy tunneling parameters εq (q = 1, 2), and two tunneling parameters with q = 1, which were associated with the rotational constants (see Groner 1997, 2012, for definitions and nomenclature of these parameters). Larger discrepancies were found between observed and calculated frequencies for J″ > 25 which could not be rectified with the addition of the tunneling and for even lower components of the quartic centrifugal distortion constants. These deviations could be partly removed using the tunneling components of the rotational constants with q = 2. The


tunneling parameters associated with the Coriolis operators were also applied to decrease those deviations but the ρ and β values were significantly changed leading to the unusual value of the moment of inertia of the methyl group. Therefore, these parameters were finally excluded from the fit. The left and middle part of Table 1 present the 25 spectroscopic parameters determined from the nonlinear least-square fit of 390 A transitions (290 distinct frequency lines owing to the line blending) and 341 E transitions, which lead to the root mean square deviations of 77 kHz and 83 kHz for the sets of A and E transitions, respectively. The moment of inertia of the methyl top, together with other derived internal rotation parameters, are presented on the right side of Table 1. The experimental frequencies can be found in the online version of Table 3, along with the assignments to the rotational quantum numbers J, Ka, Kc and νobs − νcalc quantities, where νobs and νcalc are the observed and calculated frequencies, respectively. The spectroscopic parameters from Table 1 were used to predict the transition frequencies and line strengths multiplied by the square of the corresponding dipole moment component, which are indispensable for a correct molecular identification. These predictions are gathered in the online version of Table 4 along with the estimated uncertainties of the predicted frequencies and energies of the lower and upper state energy levels.

4

Radioastronomical observations The new set of the spectroscopic constants of methyl cyanate allow us to attempt a rigorous search for this species in space. The high abundance of molecules containing methoxy (CH3O−) and cyano (−CN) groups in Orion KL (Tercero et al. 2015; López et al. 2014) and the recent detection of CH3NCO as one of the most abundant CH3−X species towards the source (Cernicharo et al. 2016) could suggest the presence of methyl cyanate (CH3OCN) in Orion KL. Cernicharo et al. (2016) report an upper limit to its column density of 1 × 1014 cm−2 in Orion KL, according to the IRAM 30m data (Tercero et al. 2010). We obtained similar results searching for CH3OCN in different positions of the ALMA Science Verification (SV) data of this source. Using the MADEX code (Cernicharo 2012), we derived an upper limit of 2 × 1014 cm−2 in the two emission peaks of CH3NCO (see Astron Astrophys. Author manuscript; available in PMC 2016 October 07.

Kolesniková et al.

Page 5


Cernicharo et al. 2016). These positions correspond approximately to the middle of the hot core clumpy structure (see e.g. Favre et al. 2011) and the MM4 source shown in Wu et al. (2014). According to the CH3NCO column densities, we derived the ratio N(CH3NCO)/ N(CH3OCN) ≥ 35 and 20 in the hot core and MM4, respectively. Owing to the richness of the compact ridge in molecules containing the methoxy group (Tercero et al. 2015), we also looked for methyl cyanate in this component, but we did not find this species above the detection limit of the data. Adopting the physical parameters of the compact ridge for transethyl methyl ether derived by Tercero et al. (2015), we found an upper limit to the CH3OCN column density of 1 × 1014 cm−2. Figure 4 shows the ALMA SV data of these three positions at selected frequencies, together with the synthetic spectra obtained using the column densities given above as upper limits. Above the limit established by these models, it becames clear that lines were missing or mismatched.


As CH3NCO has also been detected in Sgr B2(N) (Halfen et al. 2015; Cernicharo et al. 2016), we modelled the emission of CH3OCN according to the physical parameters for CH3NCO in Sgr B2(N) (Cernicharo et al. 2016) to search for this species in the public IRAM 30m spectrum at 3 mm of this source (Belloche et al. 2013). Nevertheless, similar to the Orion case, only upper limits to its column density were derived: 1 × 1016 cm−2 and 5 × 1015 cm−2 for the 63 km s−1 component and for the second component at 73 km s−1, respectively, i.e. a factor ∼50 below that of the column density values of CH3NCO (Cernicharo et al. 2016). However, HOCN, an isomer of HNCO, which contains the −OCN group, has been detected in this source (Brünken et al. 2010) so we also expected the presence of methyl cyanate in the cold gas. To explore this possibility, we searched for CH3OCN in the previous data, considering the two extended components at 14 K that were derived by Brünken et al. (2010) for HOCN in Sgr B2(N). Once again, only an upper limit to the column density of 2 × 1013 cm−2 was derived for each component. We also did not find evidence of the presence of this species in the public PRIMOS survey of this source (Neill et al. 2012). Finally, we concluded this attempt to detect CH3OCN in space by searching for this species in dark clouds. We found an upper limit to its column density of 2 × 1011 cm−2 in B1-b and TMC-1 using the data of Cernicharo et al. (2012). Table 2 shows the physical parameters for each cloud adopted for these calculations, as well as the rotational partition function used to derive the upper limits to the CH3OCN column density.

Acknowledgements This paper makes use of the following ALMA data: ADS/JAO.ALMA#2011.0.00009.SV. ALMA is a partnership of ESO (representing its member states), NSF (USA), and NINS (Japan) with NRC (Canada), NSC, and ASIAA (Taiwan), and KASI (Republic of Korea), in cooperation with the Republic of Chile. The Joint ALMA Observatory is operated by ESO, AUI/NRAO, and NAOJ. This work was also based on observations carried out with the IRAM 30-meter telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany), and IGN (Spain). The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013) / ERC-2013- SyG, Grant Agreement n. 610256 NANOCOSMOS, Ministerio de Ciencia e Innovación (Grants CTQ2010-19008, CTQ2013-40717-P, AYA2012-32032, and Consolider-Ingenio 2010 CSD2009-00038 program ASTROMOL) and Junta de Castilla y León (Grant VA175U13). J.-C. G. thanks the Centre National d’Etudes Spatiales (CNES) and the CNRS program Physique et Chimie du Milieu Interstellaire (PCMI) for financial support. C.B. also wishes to thank the Ministerio de Ciencia e Innovacion for an FPI grant (BES 2011-047695).


Kolesniková et al.

Page 6

References

Europe PMC Funders Author Manuscripts Europe PMC Funders Author Manuscripts

Belloche A, Müller HSP, Menten KM, Schilke P, Comito C. A&A. 2013; 559:A47. Brünken S, Belloche A, Martín S, Verheyen L, Menten KM. A&A. 2010; 516:A109. Brünken S, Gottlieb CA, McCarthy MC, Thaddeus P. ApJ. 2009; 697:880. Cernicharo, J. ECLA-2011: Proceedings of the European Conference on Laboratory Astrophysics, Laboratory Astrophysics and Astrochemistry in the Herschel/ALMA Era; 2012. p. 251 Cernicharo J, Kisiel Z, Tercero B, et al. A&A. 2016; 587:L4. Cernicharo J, Marcelino N, Roueff E, et al. ApJ. 2012; 759:L43. Daly A, Kolesniková L, Mata S, Alonso J. J Mol Spectrosc. 2014; 306:11. Davies W, Maclaren JA. J Chem Soc. 1951:1434. Favre C, Wootten HA, Remijan AJ, et al. ApJ. 2011; 739:L12. Goesmann F, Rosenbauer H, Bredehöft JH, et al. Science. 2015; 349:aa0689. Groner P. J Chem Phys. 1997; 107:4483. Groner P. J Mol Spectrosc. 2012; 278:52. Halfen DT, Ilyushin VV, Ziurys LM. ApJ. 2015; 812:L5. Jensen KA, Due M, Holm A. Acta Chem Scand. 1965; 19:438. Kisiel Z, Pszczółkowski L, Medvedev IR, et al. J Mol Spectrosc. 2005; 233:231. http:// www.ifpan.edu.pl/∼kisiel/aabs/aabs.htm#aabs. López A, Tercero B, Kisiel Z, et al. A&A. 2014; 572:A44. Marcelino N, Brünken S, Cernicharo J, et al. A&A. 2010; 516:A105. Marcelino N, Cernicharo J, Tercero B, Roueff E. ApJ. 2009; 690:L27. Neill JL, Muckle MT, Zaleski DP, et al. ApJ. 2012; 755:153. Pasinszki T, Westwood NPC. J Phys Chem. 1995; 99:1649. Pasinszki T, Westwood NPC. J Phys Chem A. 2001; 105:1244. Quan D, Herbst E, Osamura Y, Roueff E. ApJ. 2010; 725:2101. Sakaizumi T, Mure H, Ohashi O, Yamaguchi I. J Mol Spectrosc. 1990; 140:62. Sakaizumi T, Namikawa M, Ohashi O. J Mol Struct. 1995; 345:189. Sakaizumi T, Sekishita K, Furuya K, et al. J Mol Spectrosc. 1993; 161:114. Schuurman MS, Muir SR, Allen WD, Schaefer HF. J Chem Phys. 2004; 120:11586. [PubMed: 15268193] Tercero B, Cernicharo J, López A, et al. A&A. 2015; 582:L1. Tercero B, Cernicharo J, Pardo JR, Goicoechea JR. A&A. 2010; 517:A96. Watson, JKG. Vibrational Spectra and Structure. Durig, JR., editor. Vol. 6. Amsterdam: Elsevier; 1977. p. 1-89. Wu Y, Liu T, Qin S-L. ApJ. 2014; 791:123.


Kolesniková et al.

Page 7


Fig. 1.

Methyl cyanate depicted in the principal axis system.


Kolesniková et al.

Page 8


Fig. 2.

Section of the methyl cyanate rotational spectrum with the assignment of the A-E doublets of the a-type R-branch transitions (∆J = +1, ∆Ka = 0, ∆Kc = +1) within the cluster for J″ = 13. The quantum numbers of the lower energy levels, the A components for Ka ≥ 5 are doubly degenerate.

are indicated. Transitions of


Kolesniková et al.

Page 9


Fig. 3.

Comparison of the predicted positions of the ground torsional state a-type R-branch transitions of methyl cyanate with the experimentally observed spectrum. The blue model shows predictions based on the previous work of Sakaizumi et al. (1995) and ∆ν quantity provides the difference between the observed and predicted frequencies. Predictions based on the results of this work are represented by the red model.

Europe PMC Funders Author Manuscripts Astron Astrophys. Author manuscript; available in PMC 2016 October 07.

Kolesniková et al.

Page 10


Fig. 4.

ALMA SV data of three different positions towards Orion KL at selected frequencies, together with the synthetic spectra obtained using the column densities given in Sect. 4 as upper limits. A vLSR of +9.0 km s−1 is assumed.


Kolesniková et al.

Page 11

Table 1

Spectroscopic parameters of methyl cyanate in its ground torsional state.


Parametera

Unit

Value

Parameterb

Unit

A

MHz

38989.07 (20)d

ρ

Unitless

B

MHz

5322.2520 (15)

β

°

C

MHz

4821.3091 (13)

ε1

ΔJ

kHz

3.40965 (66)

ΔJK

kHz

ΔK

δJ δK

kHz

ΦJ

Hz

ΦJK

Hz

−0.2671 (36)

ΦKJ

Hz

φJ

Hz

σrms

Derived parameterc

Unit

0.186763 (67)

Iα

uÅ

3.1962 (44)

6.822 (19)

Ir

uÅ

2.7037 (40)

MHz

−286.44 (43)

F

cm−1

6.2349 (92)

ε2

MHz

−1.32 (12)

ΔEE−A

MHz

863.3 (15)

−81.406 (10)

[A − (B + C)/2]1

kHz

1127 (29)

∠(i, a)

°

41.232 (83)

kHz

1727 (23)

[A − (B + C)/2]2

kHz

−126 (16)

∠(i, b)

°

48.768 (83)

kHz

0.79149 (89)

[(B + C)/2]1

kHz

−4.76 (89)

∠(i, c)

°

90.0e

1.72 (11)

[(B + C)/2]2

kHz

−2.08 (14)

0.01009 (28)

[(B − C)/4]1

kHz

4.33 (27)

[(B − C)/4]2

kHz

0.62 (13)

−8.249 (66)

−[ΔJ]1

Hz

1.06 (21)

0.00457 (39)

−[ΔJK]1

Hz

−35.8 (17)

−[δK]1

Hz

−186.2 (95)

kHz

Value

Value

95

Notes.

(a) Rotational constants A, B, C, quartic centrifugal distortion constants ΔJ, ΔJK, ΔK, δJ, δK, and sextic centrifugal distortion constants ΦJ, ΦJK, ΦKJ, φJ are given in the notation of Watson’s A-reduction scheme in Ir -representation (Watson 1977).


(b)

The value ρ is the magnitude of the ρ-vector, β represents the angle between the ρ-vector and the principal a-axis, ε1 and ε2 are the first and

second energy tunneling parameters, respectively. Tunneling parameters associated with the rotational and centrifugal distortion constants are given in the notation [X]q, where X is a linear combination of the rotational constants or centrifugal distortion constants and the subscript q designates the tunneling component (see Groner 1997, 2012, for details).

(c) Iα is the moment of inertia of the methyl top, Ir is the reduced moment of inertia, F is the reduced rotational constant, ΔEE−A is the torsional energy difference, and ∠(i, a), ∠(i, b), ∠(i, c) are the angles between the internal rotation axis i and the principal axis a, b, c. (d)

Numbers in parenthesis represent the 1σ uncertainty (67% confidence level) in units of the last decimal digit.

(e) Fixed value.


Kolesniková et al.

Page 12

Table 2

Physical parameters of the considered cloud cores


υLSR(km s−1)

Source

ΔυFWHM(km s−1)

dsou(″)

Trot(K)

N(CH3OCN) × 1014 (cm−2)

Qrot A state

E state

Orion KL (ALMA SV) Hot core

8.0 6.0

3.0 8.0

3.0 3.0

150 150

≤(1.0±0.3) ≤(1.0±0.3)

8823 8823

8825 8825

Orion KL (ALMA SV) Compact ridge

7.5

2.0

3.0

100

≤(1.0±0.3)

5183

5185

Orion KL (ALMA SV) MM4

8.0 5.0

3.0 3.0

3.0 3.0

150 150

≤(1.0±0.3) ≤(1.0±0.3)

8823 8823

8825 8825

Sgr B2(N) (IRAM 30m) Hot gas

63.0 73.0

7.0 7.0

2.4 1.9

200 200

≤(100±35) ≤(50±20)

12300 12300

12303 12303

Sgr B2(N) (IRAM 30m) Cold gas

64.0 75.0

9.0 12.0

60.0 60.0

14 14

≤(0.20±0.06) ≤(0.20±0.06)

281 281

281 281

B1-b (IRAM 30m)

6.7

0.7

60.0

12

≤(0.0020±0.0006)

223

223

TMC-1 (IRAM 30m)

6.0

0.7

60.0

10

≤(0.0020±0.0006)

170

170

Europe PMC Funders Author Manuscripts Astron Astrophys. Author manuscript; available in PMC 2016 October 07.

Kolesniková et al.

Page 13

Table 3

Observed rotational transition frequencies of methyl cyanate in the ground torsional state.


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b

νobs – νcalc (MHz)c

0

13

0

13

12

0

12

129980.4908

-0.0053

0

14

0

14

13

0

13

139708.1290

-0.0056

0

15

0

15

14

0

14

149398.6925

-0.0268

0

16

0

16

15

0

15

159057.4269

-0.0679

0

17

0

17

16

0

16

168690.1850

-0.0416

0

18

0

18

17

0

17

178302.7001

-0.0445

0

19

0

19

18

0

18

187900.5164

-0.0237

0

20

0

20

19

0

19

197488.3494

-0.1186

0

21

0

21

20

0

20

207070.5515

-0.0216

0

22

0

22

21

0

21

216649.9363

-0.0983

0

23

0

23

22

0

22

226229.1081

-0.0948

0

24

0

24

23

0

23

235809.5500

-0.1457

0

25

0

25

24

0

24

245392.5125

-0.0118

0

26

0

26

25

0

25

254978.2189

-0.0056

0

27

0

27

26

0

26

264566.8085

-0.1709

0

28

0

28

27

0

27

274158.6956

-0.0273

0

29

0

29

28

0

28

283753.2022

-0.0224

0

30

0

30

29

0

29

293350.0874

-0.0664

0

31

0

31

30

0

30

302949.0597

-0.0676

0

32

0

32

31

0

31

312549.6950

-0.0479

0

33

0

33

32

0

32

322151.4777

-0.1235

0

36

0

36

35

0

35

350960.8698

-0.0794

1

13

0

13

12

0

12

129972.7920

0.0405

1

14

0

14

13

0

13

139700.4288

0.0560

1

15

0

15

14

0

14

149391.1084

0.0892

1

16

0

16

15

0

15

159049.9721

0.0493

1

17

0

17

16

0

16

168682.9085

0.0733

1

18

0

18

17

0

17

178295.5996

0.0278

1

19

0

19

18

0

18

187893.7030

0.0925

1

20

0

20

19

0

19

197481.7848

-0.0092

1

22

0

22

21

0

21

216643.9009

0.0293

1

23

0

23

22

0

22

226223.2908

0.0087

1

25

0

25

24

0

24

245387.1075

0.0641

1

26

0

26

25

0

25

254972.9089

-0.0298

1

27

0

27

26

0

26

264561.8523

-0.0194

1

28

0

28

27

0

27

274153.8526

0.0753

1

29

0

29

28

0

28

283748.4905

0.0644

1

30

0

30

29

0

29

293345.5407

0.0521

1

31

0

31

30

0

30

302944.6555

0.0726

Commentd,e

E

E


Kolesniková et al.

Page 14


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

32

0

32

31

0

31

312545.3595

0.0515

1

33

0

33

32

0

32

322147.3150

0.0490

1

34

0

34

33

0

33

331750.1131

0.0369

1

36

0

36

35

0

35

350956.9502

0.0872

0

13

1

12

12

1

11

134545.1762

-0.1366

0

14

1

13

13

1

12

144779.6851

-0.0271

0

15

1

14

14

1

13

154984.8109

-0.0704

0

16

1

15

15

1

14

165157.5536

-0.0599

0

17

1

16

16

1

15

175294.6349

0.0196

0

18

1

17

17

1

16

185392.5043

-0.0812

0

19

1

18

18

1

17

195448.2801

-0.0457

0

21

1

20

20

1

19

215421.5280

-0.1985

0

23

1

22

22

1

21

235197.2351

-0.1805

0

24

1

23

23

1

22

245008.9918

-0.0809

0

25

1

24

24

1

23

254770.8986

-0.0684

0

26

1

25

25

1

24

264485.3517

-0.0256

0

27

1

26

26

1

25

274155.7331

-0.0400

0

28

1

27

27

1

26

283786.5990

-0.0771

0

29

1

28

28

1

27

293383.3689

-0.0506

0

31

1

30

30

1

29

312497.8277

-0.0661

0

32

1

31

31

1

30

322027.3895

0.0020

0

33

1

32

32

1

31

331545.5197

-0.1062

0

35

1

34

34

1

33

350566.0392

-0.0323

1

13

1

12

12

1

11

134529.5472

0.0735

1

14

1

13

13

1

12

144763.0272

0.0724

1

15

1

14

14

1

13

154967.3236

0.0528

1

16

1

15

15

1

14

165139.3176

0.0921

1

17

1

16

16

1

15

175275.3902

-0.1446

1

18

1

17

17

1

16

185373.0040

0.0971

1

19

1

18

18

1

17

195428.2410

0.0887

1

21

1

20

20

1

19

215401.0294

0.1272

1

24

1

23

23

1

22

244988.2757

0.0923

1

25

1

24

24

1

23

254750.4309

0.1351

1

26

1

25

25

1

24

264465.1128

0.0811

1

27

1

26

26

1

25

274135.9380

0.0906

1

28

1

27

27

1

26

283767.3221

0.0745

1

29

1

28

28

1

27

293364.6173

0.0707

1

30

1

29

29

1

28

302933.6249

0.0708

1

31

1

30

30

1

29

312480.2534

0.0264

1

32

1

31

31

1

30

322010.2721

-0.0616

1

33

1

32

32

1

31

331529.1904

0.0198

1

35

1

34

34

1

33

350550.6801

-0.0464

Commentd,e

E


Kolesniková et al.

Page 15


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


0

14

1

14

13

1

13

137939.5642

0.0036

0

15

1

15

14

1

14

147714.2273

0.0374

0

16

1

16

15

1

15

157476.4745

0.0210

0

17

1

17

16

1

16

167226.6237

0.0361

0

18

1

18

17

1

17

176964.9835

0.0421

0

19

1

19

18

1

18

186691.9991

0.0383

0

20

1

20

19

1

19

196408.1446

-0.0252

0

22

1

22

21

1

21

215810.4953

-0.0342

0

25

1

25

24

1

24

244848.5255

-0.0009

0

26

1

26

25

1

25

254512.9819

0.0300

0

28

1

28

27

1

27

273823.0508

-0.0002

0

29

1

29

28

1

28

283469.8536

0.0528

0

30

1

30

29

1

29

293111.6367

-0.0250

0

31

1

31

30

1

30

302749.0194

-0.0398

0

32

1

32

31

1

31

312382.3191

-0.0533

0

33

1

33

32

1

32

322011.7861

-0.1490

0

34

1

34

33

1

33

331637.9942

-0.0438

0

36

1

36

35

1

35

350880.7821

-0.0464

1

14

1

14

13

1

13

137935.7468

-0.0250

1

15

1

15

14

1

14

147710.2023

-0.0151

1

16

1

16

15

1

15

157472.3117

-0.0103

1

17

1

17

16

1

16

167222.3340

0.0137

1

18

1

18

17

1

17

176960.5486

-0.0121

1

20

1

20

19

1

19

196403.5327

-0.0922

1

22

1

22

21

1

21

215805.8342

-0.0614

1

24

1

24

23

1

23

235172.5435

0.1349

1

25

1

25

24

1

24

244843.8716

-0.0031

1

26

1

26

25

1

25

254508.3285

0.0094

1

27

1

27

26

1

26

264166.4262

0.0900

1

28

1

28

27

1

27

273818.5302

0.0467

1

29

1

29

28

1

28

283465.3162

0.0393

1

30

1

30

29

1

29

293107.2043

0.0175

1

31

1

31

30

1

30

302744.6896

0.0521

1

32

1

32

31

1

31

312378.0326

0.0258

1

33

1

33

32

1

32

322007.7478

0.1201

1

34

1

34

33

1

33

331633.8454

0.0556

1

36

1

36

35

1

35

350876.8029

0.1038

0

13

2

11

12

2

10

133392.1462

0.0511

0

14

2

12

13

2

11

143854.7468

0.0214

0

15

2

13

14

2

12

154338.7458

-0.0315

0

16

2

14

15

2

13

164837.7348

0.0006

0

17

2

15

16

2

14

175344.5561

0.0582

Commentd,e

E


Kolesniková et al.

Page 16


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


0

18

2

16

17

2

15

185851.8023

-0.0305

0

19

2

17

18

2

16

196352.6446

-0.1114

0

21

2

19

20

2

18

217310.2458

-0.0322

0

23

2

21

22

2

20

238173.9439

-0.0691

0

24

2

22

23

2

21

248560.1909

-0.0439

0

25

2

23

24

2

22

258911.4851

-0.0160

0

26

2

24

25

2

23

269224.7681

-0.0905

0

27

2

25

26

2

24

279497.4575

-0.1132

0

29

2

27

28

2

26

299910.7153

-0.0381

0

30

2

28

29

2

27

310046.2737

-0.0258

0

31

2

29

30

2

28

320131.3392

-0.0424

0

32

2

30

31

2

29

330163.8751

-0.0266

0

34

2

32

33

2

31

350064.5391

0.0152

1

13

2

11

12

2

10

133376.0928

0.0439

1

14

2

12

13

2

11

143839.0856

0.0324

1

15

2

13

14

2

12

154322.9030

0.0361

1

16

2

14

15

2

13

164821.2271

0.0177

1

18

2

16

17

2

15

185833.3929

-0.0950

1

19

2

17

18

2

16

196333.4207

0.0526

1

21

2

19

20

2

18

217288.8505

0.0681

1

23

2

21

22

2

20

238150.6238

0.0476

1

24

2

22

23

2

21

248536.0222

0.0824

1

25

2

23

24

2

22

258886.5005

0.0585

1

26

2

24

25

2

23

269199.2893

0.1485

1

27

2

25

26

2

24

279471.4225

0.1129

1

29

2

27

28

2

26

299883.8783

0.0913

1

30

2

28

29

2

27

310019.2250

0.0382

1

31

2

29

30

2

28

320104.3309

0.0620

1

32

2

30

31

2

29

330136.9559

0.0154

1

34

2

32

33

2

31

350038.3030

-0.0281

0

13

2

12

12

2

11

131531.4243

-0.0778

0

14

2

13

13

2

12

141586.9303

0.0045

0

15

2

14

14

2

13

151628.7952

-0.0222

0

16

2

15

15

2

14

161656.3720

0.0018

0

17

2

16

16

2

15

171668.8170

-0.0121

0

18

2

17

17

2

16

181665.6030

0.1043

0

19

2

18

18

2

17

191645.7514

-0.0004

0

20

2

19

19

2

18

201609.0207

-0.0172

0

21

2

20

20

2

19

211554.7970

-0.0948

0

23

2

22

22

2

21

231392.8535

-0.0583

0

25

2

24

24

2

23

251158.0831

0.0284

0

26

2

25

25

2

24

261013.2431

0.0252

Commentd,e


Kolesniková et al.

Page 17


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


0

27

2

26

26

2

25

270850.3676

0.0804

0

28

2

27

27

2

26

280669.5772

0.0452

0

29

2

28

28

2

27

290471.4741

0.1494

0

30

2

29

29

2

28

300256.2453

0.1118

0

31

2

30

30

2

29

310024.6163

0.1024

0

32

2

31

31

2

30

319777.2501

0.1531

0

33

2

32

32

2

31

329514.7271

0.1497

0

35

2

34

34

2

33

348947.3958

0.1510

1

13

2

12

12

2

11

131528.5313

-0.0597

1

14

2

13

13

2

12

141581.8422

-0.0065

1

15

2

14

14

2

13

151622.1920

0.0303

1

16

2

15

15

2

14

161648.5438

0.0395

1

17

2

16

16

2

15

171660.0009

0.0071

1

19

2

18

18

2

17

191635.4550

0.0299

1

20

2

19

19

2

18

201598.1247

0.0105

1

21

2

20

20

2

19

211543.4165

-0.0260

1

25

2

24

24

2

23

251145.0751

0.0314

1

27

2

26

26

2

25

270836.8025

0.0368

1

28

2

27

27

2

26

280655.7880

-0.0284

1

29

2

28

28

2

27

290457.4005

-0.0536

1

30

2

29

29

2

28

300242.0959

-0.0498

1

31

2

30

30

2

29

310010.3411

-0.1039

1

32

2

31

31

2

30

319762.9021

-0.0795

1

33

2

32

32

2

31

329500.3550

-0.0929

1

35

2

34

34

2

33

348932.9962

-0.1801

0

13

3

10

12

3

9

132182.1520

0.0248

0

14

3

11

13

3

10

142410.1341

-0.0518

0

15

3

12

14

3

11

152655.2156

-0.0755

0

16

3

13

15

3

12

162919.7346

-0.0559

0

17

3

14

16

3

13

173206.0283

-0.0894

0

18

3

15

17

3

14

183516.5893

-0.1226

0

19

3

16

18

3

15

193853.8882

-0.0167

0

20

3

17

19

3

16

204219.7047

-0.0716

0

21

3

18

20

3

17

214615.8737

-0.1031

0

23

3

20

22

3

19

235502.5603

-0.0568

0

24

3

21

23

3

20

245992.3818

-0.0176

0

25

3

22

24

3

21

256510.7461

-0.1081

0

26

3

23

25

3

22

267054.6458

-0.0605

0

27

3

24

26

3

23

277619.5066

0.0583

0

28

3

25

27

3

24

288199.4391

-0.0315

0

30

3

27

29

3

26

309378.8339

-0.0372

0

31

3

28

30

3

27

319963.9307

-0.0024

Commentd,e

E


Kolesniková et al.

Page 18


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


0

32

3

29

31

3

28

330536.3133

0.0042

1

13

3

10

12

3

9

132130.8403

-0.0173

1

14

3

11

13

3

10

142352.2928

-0.0259

1

15

3

12

14

3

11

152597.0318

-0.0285

1

16

3

13

15

3

12

162867.7129

0.0742

1

17

3

14

16

3

13

173163.3266

0.0480

1

18

3

15

17

3

14

183482.8937

0.0783

1

19

3

16

18

3

15

193826.9913

0.1113

1

20

3

17

19

3

16

204197.5667

0.1464

1

21

3

18

20

3

17

214596.5948

0.0637

1

24

3

21

23

3

20

245975.5237

0.0401

1

25

3

22

24

3

21

256493.6883

0.0430

1

26

3

23

25

3

22

267036.9916

0.0852

1

27

3

24

26

3

23

277600.8196

-0.0360

1

28

3

25

27

3

24

288180.0325

0.0753

1

29

3

26

28

3

25

298767.8379

0.0477

1

30

3

27

29

3

26

309357.4397

0.0810

1

31

3

28

30

3

27

319941.6261

0.1930

1

32

3

29

31

3

28

330512.9284

0.0501

0

13

3

11

12

3

10

132068.6300

-0.0302

0

14

3

12

13

3

11

142245.9698

-0.0541

0

15

3

13

14

3

12

152424.2263

-0.0197

0

16

3

14

15

3

13

162602.3874

-0.0246

0

17

3

15

16

3

14

172779.5738

0.0891

0

18

3

16

17

3

15

182954.4062

0.0855

0

22

3

20

21

3

19

223605.7060

-0.0581

0

24

3

22

23

3

21

243883.7880

0.0106

0

25

3

23

24

3

22

254006.1343

0.0369

0

26

3

24

25

3

23

264115.6344

0.0719

0

27

3

25

26

3

24

274210.9384

-0.0111

0

28

3

26

27

3

25

284291.1451

0.0346

0

29

3

27

28

3

26

294355.0400

0.0565

0

31

3

29

30

3

28

314430.2002

0.0994

0

32

3

30

31

3

29

324439.8980

0.1727

0

33

3

31

32

3

30

334430.0279

0.1946

0

35

3

33

34

3

32

354349.6869

0.1658

1

13

3

11

12

3

10

132109.7922

0.0888

1

14

3

12

13

3

11

142292.7629

0.1092

1

15

3

13

14

3

12

152470.2694

0.0923

1

16

3

14

15

3

13

162641.1946

0.0484

1

17

3

15

16

3

14

172807.7189

-0.0102

1

20

3

18

19

3

17

203296.0812

-0.0451

Commentd,e

E


Kolesniková et al.

Page 19


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

24

3

22

23

3

21

243876.0019

-0.0097

1

25

3

23

24

3

22

253996.9477

-0.0010

1

26

3

24

25

3

23

264105.3576

0.0567

1

28

3

26

27

3

25

284279.1301

-0.0268

1

29

3

27

28

3

26

294342.3150

-0.0542

1

30

3

28

29

3

27

304388.3642

-0.0540

1

31

3

29

30

3

28

314416.4177

-0.0086

1

32

3

30

31

3

29

324425.5073

-0.1218

1

33

3

31

32

3

30

334415.2519

-0.1276

1

35

3

33

34

3

32

354334.3366

-0.1958

0

15

4

11

14

4

10

152371.5013

-0.0752

0

16

4

12

15

4

11

162555.1617

-0.0869

0

17

4

13

16

4

12

172744.4682

-0.0137

0

18

4

14

17

4

13

182939.7407

-0.1703

0

20

4

16

19

4

15

203352.2779

-0.0776

0

21

4

17

20

4

16

213571.0659

-0.0758

0

24

4

20

23

4

19

244291.0167

-0.0744

0

25

4

21

24

4

20

254556.7442

-0.0764

0

26

4

22

25

4

21

264838.0549

-0.0201

0

27

4

23

26

4

22

275136.5019

-0.1549

0

28

4

24

27

4

23

285454.4874

0.0077

0

29

4

25

28

4

24

295793.4397

-0.0863

0

30

4

26

29

4

25

306155.6931

-0.0928

0

31

4

27

30

4

26

316543.3458

0.1730

0

32

4

28

31

4

27

326957.3510

-0.0631

0

34

4

30

33

4

29

347871.5557

-0.0660

1

13

4

9

12

4

8

132010.2766

0.0927

1

14

4

10

13

4

9

142182.8489

0.0144

1

15

4

11

14

4

10

152359.5329

0.0054

1

16

4

12

15

4

11

162540.5804

-0.0210

1

17

4

13

16

4

12

172726.3785

-0.0696

1

18

4

14

17

4

13

182917.5634

-0.0012

1

20

4

16

19

4

15

203318.7233

-0.0258

1

21

4

17

20

4

16

213531.4187

-0.0816

1

24

4

20

23

4

19

244247.0840

-0.0904

1

25

4

21

24

4

20

254518.6646

-0.0327

1

26

4

22

25

4

21

264807.1353

-0.0295

1

27

4

23

26

4

22

275112.5279

0.1293

1

28

4

24

27

4

23

285435.4567

0.0740

1

29

4

25

28

4

24

295778.1114

0.0913

1

30

4

26

29

4

25

306142.6522

0.0814

1

31

4

27

30

4

26

316531.3708

0.1023

Commentd,e

E


Kolesniková et al.

Page 20


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

32

4

28

31

4

27

326946.0570

-0.0497

1

34

4

30

33

4

29

347860.2164

0.1209

0

13

4

10

12

4

9

132016.2494

0.0081

0

14

4

11

13

4

10

142188.6385

-0.0221

0

15

4

12

14

4

11

152364.5725

-0.0748

0

17

4

14

16

4

13

172727.6007

-0.1207

0

18

4

15

17

4

14

182914.8983

0.0193

0

20

4

17

19

4

16

203300.0241

-0.1136

0

21

4

18

20

4

17

213497.8282

-0.0672

0

24

4

21

23

4

20

244107.6952

-0.0703

0

25

4

22

24

4

21

254314.8722

-0.0566

0

26

4

23

25

4

22

264522.7825

-0.1570

0

27

4

24

26

4

23

274730.9333

-0.0538

0

28

4

25

27

4

24

284938.1194

-0.0398

0

29

4

26

28

4

25

295143.3651

-0.0828

0

30

4

27

29

4

26

305345.5924

-0.1646

0

31

4

28

30

4

27

315543.9834

0.0702

0

32

4

29

31

4

28

325736.6997

0.0216

0

33

4

30

32

4

29

335922.9162

0.1539

0

34

4

31

33

4

30

346100.8467

0.0056

1

13

4

10

12

4

9

132023.8548

0.1445

1

14

4

11

13

4

10

142197.5015

0.1050

1

15

4

12

14

4

11

152375.1783

0.0992

1

16

4

13

15

4

12

162557.1698

0.1461

1

17

4

14

16

4

13

172743.5645

0.1069

1

18

4

15

17

4

14

182934.6026

0.0802

1

20

4

17

19

4

16

203330.2664

0.1803

1

21

4

18

20

4

17

213533.5278

0.2039

1

24

4

21

23

4

20

244145.6363

0.1753

1

25

4

22

24

4

21

254346.1518

0.1142

1

26

4

23

25

4

22

264546.1319

0.1564

1

27

4

24

26

4

23

274746.5070

0.0649

1

28

4

25

27

4

24

284947.4469

-0.0056

1

29

4

26

28

4

25

295148.0841

0.0084

1

30

4

27

29

4

26

305346.8236

-0.1208

1

31

4

28

30

4

27

315542.5713

0.0070

1

32

4

29

31

4

28

325733.3987

-0.0332

1

33

4

30

32

4

29

335917.9606

-0.1039

1

34

4

31

33

4

30

346094.8895

-0.1135

0

13

5

8

12

5

7

131982.7971

0.0445

B

0

13

5

9

12

5

8

131982.7971

0.0445

B

0

14

5

9

13

5

8

142144.5340

-0.0633

B

Commentd,e

E


Kolesniková et al.

Page 21


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

14

5

10

13

5

9

142144.5340

-0.0633

B

0

15

5

10

14

5

9

152308.4308

-0.0738

B

0

15

5

11

14

5

10

152308.4308

-0.0738

B

0

16

5

11

15

5

10

162474.5322

-0.0881

B

0

16

5

12

15

5

11

162474.5322

-0.0881

B

0

17

5

12

16

5

11

172642.9875

-0.1030

B

0

17

5

13

16

5

12

172642.9875

-0.1030

B

0

19

5

15

18

5

14

192987.1490

-0.0774

0

20

5

16

19

5

15

203163.3064

-0.0708

0

21

5

17

20

5

16

213342.2749

-0.0726

0

24

5

20

23

5

19

243897.0618

-0.0641

0

25

5

21

24

5

20

254088.1899

-0.0554

0

26

5

22

25

5

21

264282.3699

-0.1574

0

27

5

23

26

5

22

274479.8551

-0.1157

0

28

5

24

27

5

23

284680.4954

-0.0450

0

29

5

25

28

5

24

294884.1362

-0.0249

0

30

5

26

29

5

25

305090.7602

0.0479

0

31

5

27

30

5

26

315299.9720

-0.0498

0

32

5

28

31

5

27

325511.7726

-0.0870

0

33

5

29

32

5

28

335725.8549

-0.0772

0

34

5

30

33

5

29

345941.8465

-0.0297

1

13

5

9

12

5

8

131992.8883

-0.0116

1

15

5

11

14

5

10

152320.1007

0.0429

1

16

5

12

15

5

11

162486.9055

0.0556

1

17

5

13

16

5

12

172656.0434

0.0666

1

18

5

14

17

5

13

182827.6497

0.0658

1

20

5

16

19

5

15

203178.9350

0.1090

1

21

5

17

20

5

16

213358.8802

0.1225

1

25

5

21

24

5

20

254110.7703

0.1318

1

26

5

22

25

5

21

264307.4757

0.2113

1

27

5

23

26

5

22

274507.6293

0.1889

1

28

5

24

27

5

23

284710.7710

-0.2185

1

29

5

25

28

5

24

294917.6574

0.2108

1

30

5

26

29

5

25

305126.0836

0.1464

1

31

5

27

30

5

26

315335.3602

0.1230

1

32

5

28

31

5

27

325544.3213

0.0078

1

33

5

29

32

5

28

335753.1315

-0.0492

1

34

5

30

33

5

29

345962.8455

-0.0972

0

19

5

14

18

5

13

192988.0799

-0.0641

0

20

5

15

19

5

14

203164.7251

-0.1150

0

21

5

16

20

5

15

213344.5107

-0.1134

0

24

5

19

23

5

18

243904.6606

-0.0517

E


Kolesniková et al.

Page 22


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


0

25

5

20

24

5

19

254099.1119

-0.0703

0

26

5

21

25

5

20

264298.0691

0.0161

0

27

5

22

26

5

21

274501.6694

-0.0279

0

29

5

24

28

5

23

294925.0435

-0.0319

0

30

5

25

29

5

24

305145.7293

-0.1317

0

31

5

26

30

5

25

315373.4824

-0.0607

0

32

5

27

31

5

26

325608.7418

-0.1181

0

33

5

28

32

5

27

335852.6050

-0.0482

0

34

5

29

33

5

28

346105.7893

-0.0883

1

13

5

8

12

5

7

131980.5217

0.1389

1

15

5

10

14

5

9

152305.6751

0.0676

1

16

5

11

15

5

10

162471.7602

0.3251

1

17

5

12

16

5

11

172639.6340

0.0339

1

18

5

13

17

5

12

182810.2670

0.0181

1

19

5

14

18

5

13

192983.5952

0.0652

1

20

5

15

19

5

14

203159.6428

0.0489

1

21

5

16

20

5

15

213338.5587

-0.0362

1

24

5

19

23

5

18

243894.8823

0.0049

1

25

5

20

24

5

19

254087.3034

-0.0642

1

26

5

21

25

5

20

264283.7191

-0.0842

1

27

5

22

26

5

21

274484.4777

-0.0856

1

28

5

23

27

5

22

284690.1492

-0.0645

1

29

5

24

28

5

23

294901.5299

-0.1021

1

30

5

25

29

5

24

305120.0710

-0.0613

1

31

5

26

30

5

25

315347.4059

-0.0037

1

32

5

27

31

5

26

325585.0515

0.0483

1

33

5

28

32

5

27

335833.5696

0.1245

1

34

5

29

33

5

28

346092.3661

0.1448

0

13

6

7

12

6

6

131976.7910

-0.0727

B

0

13

6

8

12

6

7

131976.7910

-0.0727

B

0

14

6

8

13

6

7

142133.5605

-0.1303

B

0

14

6

9

13

6

8

142133.5605

-0.1303

B

0

15

6

9

14

6

8

152291.4721

-0.0939

B

0

15

6

10

14

6

9

152291.4721

-0.0939

B

0

16

6

10

15

6

9

162450.4638

-0.0972

B

0

16

6

11

15

6

10

162450.4638

-0.0972

B

0

17

6

11

16

6

10

172610.6834

-0.0642

B

0

17

6

12

16

6

11

172610.6834

-0.0642

B

0

19

6

13

18

6

12

192934.9108

-0.0690

B

0

19

6

14

18

6

13

192934.9108

-0.0690

B

0

20

6

14

19

6

13

203099.1010

-0.0665

B

0

20

6

15

19

6

14

203099.1010

-0.0665

B

Commentd,e

E


Kolesniková et al.

Page 23


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

21

6

15

20

6

14

213264.7853

-0.0456

B

0

21

6

16

20

6

15

213264.7853

-0.0456

B

0

22

6

16

21

6

15

223431.9164

-0.1248

B

0

22

6

17

21

6

16

223431.9164

-0.1248

B

0

23

6

17

22

6

16

233600.7894

-0.0805

B

0

23

6

18

22

6

17

233600.7894

-0.0805

B

0

24

6

18

23

6

17

243771.3813

-0.0076

B

0

24

6

19

23

6

18

243771.3813

-0.0076

B

0

26

6

20

25

6

19

264117.7914

0.0011

B

0

26

6

21

25

6

20

264117.7914

0.0011

B

0

28

6

22

27

6

21

284472.2785

-0.0749

0

29

6

23

28

6

22

294652.6530

-0.0280

0

32

6

26

31

6

25

325207.3950

-0.0988

B

1

32

6

26

31

6

25

325207.3950

-0.0988

B

0

34

6

28

33

6

27

345590.5825

0.0105

0

28

6

23

27

6

22

284471.1611

-0.1683

0

29

6

24

28

6

23

294651.1227

-0.0535

0

30

6

25

29

6

24

304833.1065

0.0326

0

32

6

27

31

6

26

325203.1428

-0.0735

0

34

6

29

33

6

28

345582.1240

0.0524

1

14

6

8

13

6

7

142136.7086

0.1267

1

15

6

9

14

6

8

152294.7119

0.1326

1

16

6

10

15

6

9

162453.8714

0.1918

1

17

6

11

16

6

10

172614.1035

0.1501

1

19

6

13

18

6

12

192938.4648

0.1624

1

20

6

14

19

6

13

203102.6555

0.1376

1

21

6

15

20

6

14

213268.3164

0.1288

1

23

6

17

22

6

16

233604.4969

0.3254

1

24

6

18

23

6

17

243774.7592

0.1312

1

25

6

19

24

6

18

253946.8615

0.0380

1

26

6

20

25

6

19

264120.8997

0.0682

1

27

6

21

26

6

20

274296.6845

-0.0425

1

28

6

22

27

6

21

284474.5455

-0.0415

1

29

6

23

28

6

22

294654.4868

-0.0049

1

30

6

24

29

6

23

304836.5640

0.0383

1

34

6

28

33

6

27

345588.0455

-0.0561

1

13

6

8

12

6

7

131989.3511

-0.0317

1

14

6

9

13

6

8

142147.0989

-0.0118

1

16

6

11

15

6

10

162465.7058

-0.0309

1

19

6

14

18

6

13

192952.4219

-0.2312

1

20

6

15

19

6

14

203117.5860

-0.0450

1

21

6

16

20

6

15

213284.0272

-0.0335

E

E

E


Kolesniková et al.

Page 24


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

24

6

19

23

6

18

243792.7488

-0.0079

1

25

6

20

24

6

19

253965.7226

0.0307

1

26

6

21

25

6

20

264140.4043

-0.0266

1

27

6

22

26

6

21

274317.0296

-0.0170

1

30

6

25

29

6

24

304858.9263

0.0286

1

31

6

26

30

6

25

315043.7795

0.0150

1

32

6

27

31

6

26

325231.0207

0.1488

1

34

6

29

33

6

28

345612.0035

0.0497

0

13

7

6

12

7

5

131986.7568

-0.0238

B

0

13

7

7

12

7

6

131986.7568

-0.0238

B

0

15

7

8

14

7

7

152296.9456

-0.0751

B

0

15

7

9

14

7

8

152296.9456

-0.0751

B

0

16

7

9

15

7

8

162452.7705

-0.0766

B

0

16

7

10

15

7

9

162452.7705

-0.0766

B

0

17

7

10

16

7

9

172609.1405

-0.0432

B

0

17

7

11

16

7

10

172609.1405

-0.0432

B

0

18

7

11

17

7

10

182765.9097

-0.1494

B

0

18

7

12

17

7

11

182765.9097

-0.1494

B

0

19

7

12

18

7

11

192923.4304

-0.0715

B

0

19

7

13

18

7

12

192923.4304

-0.0715

B

0

20

7

13

19

7

12

203081.4770

-0.0631

B

0

20

7

14

19

7

13

203081.4770

-0.0631

B

0

21

7

14

20

7

13

213240.1386

-0.0626

B

0

21

7

15

20

7

14

213240.1386

-0.0626

B

0

25

7

18

24

7

17

253881.6185

0.0012

B

0

25

7

19

24

7

18

253881.6185

0.0012

B

0

27

7

20

26

7

19

274206.7764

0.0149

B

0

27

7

21

26

7

20

274206.7764

0.0149

B

0

28

7

21

27

7

20

284370.5740

0.0388

B

0

28

7

22

27

7

21

284370.5740

0.0388

B

0

30

7

23

29

7

22

304700.6229

0.0044

B

0

30

7

24

29

7

23

304700.6229

0.0044

B

0

31

7

24

30

7

23

314867.0378

0.0557

B

0

31

7

25

30

7

24

314867.0378

0.0557

B

0

32

7

25

31

7

24

325034.3136

0.0499

B

0

32

7

26

31

7

25

325034.3136

0.0499

B

0

33

7

26

32

7

25

335202.5784

0.0867

B

0

33

7

27

32

7

26

335202.5784

0.0867

B

0

34

7

27

33

7

26

345371.7160

0.0209

B

0

34

7

28

33

7

27

345371.7160

0.0209

B

1

13

7

6

12

7

5

131994.2852

0.1288

1

14

7

7

13

7

6

142149.7232

0.1838

Commentd,e


Kolesniková et al.

Page 25


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

16

7

9

15

7

8

162461.8302

0.1948

1

17

7

10

16

7

9

172618.5506

0.1456

1

19

7

12

18

7

11

192933.6587

0.1326

1

25

7

18

24

7

17

253893.5771

0.1091

1

26

7

19

25

7

18

264055.9913

0.1334

1

27

7

20

26

7

19

274219.0749

0.0729

1

29

7

22

28

7

21

294547.7324

0.0771

1

30

7

23

29

7

22

304713.2396

0.0229

1

32

7

25

31

7

24

325046.9664

0.0240

1

34

7

27

33

7

26

345384.3091

-0.0156

1

15

7

9

14

7

8

152311.8370

-0.0632

1

16

7

10

15

7

9

162468.5576

-0.0947

1

17

7

11

16

7

10

172625.6438

-0.2565

E

1

18

7

12

17

7

11

182783.5162

-0.1555

E

1

19

7

13

18

7

12

192941.8999

-0.0938

1

20

7

14

19

7

13

203100.7950

-0.0979

1

21

7

15

20

7

14

213260.3452

-0.0502

1

24

7

18

23

7

17

243742.7616

-0.0177

1

26

7

20

25

7

19

264067.7973

-0.0526

1

27

7

21

26

7

20

274231.4115

-0.0923

1

28

7

22

27

7

21

284395.8908

-0.0456

1

29

7

23

28

7

22

294561.1087

-0.0636

1

30

7

24

29

7

23

304727.2057

-0.0307

1

31

7

25

30

7

24

314894.0761

-0.0780

1

32

7

26

31

7

25

325061.8882

-0.0628

1

33

7

27

32

7

26

335230.6769

0.0235

1

34

7

28

33

7

27

345400.1850

-0.1033

0

13

8

5

12

8

4

132007.4796

0.0151

B

0

13

8

6

12

8

5

132007.4796

0.0151

B

0

14

8

6

13

8

5

142162.1891

-0.0289

B

0

14

8

7

13

8

6

142162.1891

-0.0289

B

0

15

8

7

14

8

6

152317.0273

-0.0123

B

0

15

8

8

14

8

7

152317.0273

-0.0123

B

0

17

8

9

16

8

8

172626.8108

-0.0878

B

0

17

8

10

16

8

9

172626.8108

-0.0878

B

0

18

8

10

17

8

9

182781.7945

-0.1462

B

0

18

8

11

17

8

10

182781.7945

-0.1462

B

0

19

8

11

18

8

10

192937.0462

-0.0141

B

0

19

8

12

18

8

11

192937.0462

-0.0141

B

0

21

8

13

20

8

12

213247.4500

-0.0873

B

0

21

8

14

20

8

13

213247.4500

-0.0873

B

0

24

8

16

23

8

15

243713.8210

-0.0352

B

Commentd,e


Kolesniková et al.

Page 26


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

24

8

17

23

8

16

243713.8210

-0.0352

B

0

25

8

17

24

8

16

253869.4691

0.0125

B

0

25

8

18

24

8

17

253869.4691

0.0125

B

0

26

8

18

25

8

17

264025.1546

0.0183

B

0

26

8

19

25

8

18

264025.1546

0.0183

B

0

27

8

19

26

8

18

274180.8971

0.0031

B

0

27

8

20

26

8

19

274180.8971

0.0031

B

0

28

8

20

27

8

19

284336.7330

0.0047

B

0

28

8

21

27

8

20

284336.7330

0.0047

B

0

29

8

21

28

8

20

294492.6724

0.0348

B

0

29

8

22

28

8

21

294492.6724

0.0348

B

0

31

8

23

30

8

22

314804.7087

0.0361

B

0

31

8

24

30

8

23

314804.7087

0.0361

B

0

32

8

24

31

8

23

324960.8316

0.0376

B

0

32

8

25

31

8

24

324960.8316

0.0376

B

0

34

8

26

33

8

25

345273.3283

0.0963

B

0

34

8

27

33

8

26

345273.3283

0.0963

B

0

13

9

4

12

9

3

132036.4720

-0.0745

0

13

9

5

12

9

4

132036.4720

-0.0745

0

16

9

7

15

9

6

162503.3703

0.0014

B

0

16

9

8

15

9

7

162503.3703

0.0014

B

0

19

9

10

18

9

9

192968.1451

-0.0243

B

0

19

9

11

18

9

10

192968.1451

-0.0243

B

0

20

9

11

19

9

10

203122.5552

-0.0234

B

0

20

9

12

19

9

11

203122.5552

-0.0234

B

0

21

9

12

20

9

11

213276.7116

0.0138

B

0

21

9

13

20

9

12

213276.7116

0.0138

B

0

24

9

15

23

9

14

243737.1302

-0.0114

B

0

24

9

16

23

9

15

243737.1302

-0.0114

B

0

26

9

17

25

9

16

264042.2806

-0.0492

B

0

26

9

18

25

9

17

264042.2806

-0.0492

B

0

27

9

18

26

9

17

274194.3698

0.0339

B

0

27

9

19

26

9

18

274194.3698

0.0339

B

0

28

9

19

27

9

18

284345.9227

-0.0018

B

0

28

9

20

27

9

19

284345.9227

-0.0018

B

0

29

9

20

28

9

19

294497.1708

0.0948

B

0

29

9

21

28

9

20

294497.1708

0.0948

B

0

31

9

22

30

9

21

314798.0102

0.0220

B

0

31

9

23

30

9

22

314798.0102

0.0220

B

0

33

9

24

32

9

23

335096.9895

0.0798

B

0

33

9

25

32

9

24

335096.9895

0.0798

B

0

34

9

25

33

9

24

345245.5546

-0.0175

B


Kolesniková et al.

Page 27


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

34

9

26

33

9

25

345245.5546

-0.0175

B

1

13

9

5

12

9

4

132049.3133

0.0727

1

14

9

6

13

9

5

142205.9755

0.0359

1

15

9

7

14

9

6

152362.4708

0.0441

1

16

9

8

15

9

7

162518.7123

0.0272

1

17

9

9

16

9

8

172674.7133

0.0152

1

18

9

10

17

9

9

182830.4026

-0.0458

1

19

9

11

18

9

10

192985.9411

0.0226

1

20

9

12

19

9

11

203141.1450

0.0542

1

21

9

13

20

9

12

213295.9293

-0.0177

1

24

9

16

23

9

15

243758.4738

0.0400

1

25

9

17

24

9

16

253911.8513

0.0126

1

26

9

18

25

9

17

264064.9262

0.0939

1

27

9

19

26

9

18

274217.3950

0.0003

1

28

9

20

27

9

19

284369.4188

-0.0867

1

29

9

21

28

9

20

294521.1661

0.0218

1

31

9

23

30

9

22

314822.9464

0.0248

1

32

9

24

31

9

23

324972.9594

-0.0584

1

34

9

26

33

9

25

345271.0843

-0.4326

1

13

9

4

12

9

3

132044.8744

-0.0030

1

14

9

5

13

9

4

142201.2857

-0.0298

1

15

9

6

14

9

5

152357.5301

-0.0272

1

16

9

7

15

9

6

162513.5164

-0.0704

1

17

9

8

16

9

7

172669.3176

-0.0705

1

19

9

10

18

9

9

192980.2035

-0.0354

1

20

9

11

19

9

10

203135.2497

-0.0047

1

21

9

12

20

9

11

213289.8983

-0.0748

1

24

9

15

23

9

14

243752.1369

-0.0288

1

26

9

17

25

9

16

264058.4564

-0.0116

1

27

9

18

26

9

17

274210.9384

-0.0737

1

28

9

19

27

9

18

284363.1330

0.0086

1

29

9

20

28

9

19

294514.7663

-0.0175

1

30

9

21

29

9

20

304665.9167

-0.0525

1

31

9

22

30

9

21

314816.6714

0.0125

1

32

9

23

31

9

22

324966.7687

-0.0622

1

34

9

25

33

9

24

345265.5204

-0.0118

0

13

10

3

12

10

2

132072.6239

-0.0408

B

0

13

10

4

12

10

3

132072.6239

-0.0408

B

0

14

10

4

13

10

3

142230.4220

0.0235

B

0

14

10

5

13

10

4

142230.4220

0.0235

B

0

15

10

5

14

10

4

152387.7782

0.0272

B

0

15

10

6

14

10

5

152387.7782

0.0272

B

E


Kolesniková et al.

Page 28


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

17

10

7

16

10

6

172701.2010

0.0031

B

0

17

10

8

16

10

7

172701.2010

0.0031

B

0

20

10

10

19

10

9

203167.8210

0.0298

B

0

20

10

11

19

10

10

203167.8210

0.0298

B

0

23

10

14

22

10

13

233629.3663

-0.0204

B

0

23

10

13

22

10

12

233629.3663

-0.0204

B

0

24

10

14

23

10

13

243781.9998

-0.0016

B

0

24

10

15

23

10

14

243781.9998

-0.0016

B

0

25

10

15

24

10

14

253933.8677

-0.0723

B

0

25

10

16

24

10

15

253933.8677

-0.0723

B

0

26

10

16

25

10

15

264085.0225

-0.1491

B

0

26

10

17

25

10

16

264085.0225

-0.1491

B

0

27

10

17

26

10

16

274235.5752

-0.0898

B

0

27

10

18

26

10

17

274235.5752

-0.0898

B

0

28

10

18

27

10

17

284385.2999

-0.0887

B

0

28

10

19

27

10

18

284385.2999

-0.0887

B

0

29

10

19

28

10

18

294534.1257

-0.1850

B

0

29

10

20

28

10

19

294534.1257

-0.1850

B

0

30

10

20

29

10

19

304682.3173

-0.0818

B

0

30

10

21

29

10

20

304682.3173

-0.0818

B

0

32

10

22

31

10

21

324975.8269

-0.1183

B

0

32

10

23

31

10

22

324975.8269

-0.1183

B

0

34

10

24

33

10

23

345265.5204

-0.2443

B

0

34

10

25

33

10

24

345265.5204

-0.2443

B

1

13

10

3

12

10

2

132076.5829

-0.0200

1

14

10

4

13

10

3

142234.6973

0.0433

1

15

10

5

14

10

4

152392.3955

0.0693

1

16

10

6

15

10

5

162549.6221

0.0312

1

17

10

7

16

10

6

172706.4787

0.0592

1

18

10

8

17

10

7

182862.8924

0.1096

1

20

10

10

19

10

9

203174.0988

0.1026

1

21

10

11

20

10

10

213328.8713

0.0847

1

23

10

13

22

10

12

233636.6464

0.0626

1

24

10

14

23

10

13

243789.6084

0.0796

1

25

10

15

24

10

14

253941.8729

0.0764

1

26

10

16

25

10

15

264093.5668

0.2115

1

27

10

17

26

10

16

274244.3518

0.1787

1

28

10

18

27

10

17

284394.3695

0.1521

1

29

10

19

28

10

18

294543.6494

0.1937

1

30

10

20

29

10

19

304692.0889

0.2341

1

34

10

24

33

10

23

345276.6710

0.2865

1

13

10

4

12

10

3

132085.2869

-0.0078


Kolesniková et al.

Page 29


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


1

14

10

5

13

10

4

142243.8903

-0.0350

1

15

10

6

14

10

5

152402.1616

0.0037

1

16

10

7

15

10

6

162559.9495

-0.0133

1

17

10

8

16

10

7

172717.2146

-0.0957

1

18

10

9

17

10

8

182874.1539

-0.0166

1

20

10

11

19

10

10

203186.2761

-0.0313

1

21

10

12

20

10

11

213341.3881

-0.1349

1

24

10

15

23

10

14

243803.3572

-0.0284

1

25

10

16

24

10

15

253955.9560

-0.0174

1

26

10

17

25

10

16

264107.8720

0.0473

1

27

10

18

26

10

17

274258.8960

-0.0112

1

28

10

19

27

10

18

284409.2157

0.0273

1

29

10

20

28

10

19

294558.6006

-0.0348

1

30

10

21

29

10

20

304707.1448

-0.0703

1

31

10

22

30

10

21

314854.8581

-0.0359

1

32

10

23

31

10

22

325001.7186

0.0801

1

34

10

25

33

10

24

345292.0845

-0.1040

0

13

11

2

12

11

1

132114.8337

-0.0205

B

0

13

11

3

12

11

2

132114.8337

-0.0205

B

0

14

11

3

13

11

2

142275.2073

0.0098

B

0

14

11

4

13

11

3

142275.2073

0.0098

B

0

15

11

4

14

11

3

152435.0488

0.0299

B

0

15

11

5

14

11

4

152435.0488

0.0299

B

0

16

11

5

15

11

4

162594.2671

-0.0133

B

0

16

11

6

15

11

5

162594.2671

-0.0133

B

0

17

11

6

16

11

5

172752.9012

-0.0424

B

0

17

11

7

16

11

6

172752.9012

-0.0424

B

0

18

11

7

17

11

6

182910.9968

0.0266

B

0

18

11

8

17

11

7

182910.9968

0.0266

B

1

13

11

2

12

11

1

132113.8468

-0.0013

1

14

11

3

13

11

2

142274.2397

0.0879

1

15

11

4

14

11

3

152434.0036

0.0622

1

16

11

5

15

11

4

162593.2578

0.0787

1

17

11

6

16

11

5

172751.9150

0.0882

1

13

11

3

12

11

2

132125.7859

0.2629

1

14

11

4

13

11

3

142286.6079

-0.0234

1

15

11

5

14

11

4

152447.1780

-0.0272

1

16

11

6

15

11

5

162607.2274

0.0218

1

17

11

7

16

11

6

172766.5496

-0.0437

1

18

11

8

17

11

7

182925.2566

-0.0722

1

20

11

10

19

11

9

203240.7092

0.0242

1

22

11

12

21

11

11

223553.0031

0.0481

Commentd,e

E


Kolesniková et al.

Page 30


σα

J′

K a′

K ′c

J″

K a″

K ″c

νobs (MHz)b


Commentd,e

0

14

12

2

13

12

1

142325.7505

-0.0631

B

0

14

12

3

13

12

2

142325.7505

-0.0631

B

0

15

12

3

14

12

2

152488.5825

-0.1031

B

0

15

12

4

14

12

3

152488.5825

-0.1031

B

0

16

12

4

15

12

3

162650.7818

-0.0999

B

0

16

12

5

15

12

4

162650.7818

-0.0999

B

0

17

12

5

16

12

4

172812.2012

-0.1549

B

0

17

12

6

16

12

5

172812.2012

-0.1549

B

1

13

12

1

12

12

0

132156.6548

0.1199

1

14

12

2

13

12

1

142319.8044

0.1513

1

15

12

3

14

12

2

152482.3266

0.1729

1

16

12

4

15

12

3

162644.1767

0.1848

1

17

12

5

16

12

4

172805.2610

0.1385

1

13

12

2

12

12

1

132169.5664

0.1593

1

14

12

3

13

12

2

142333.5442

0.1156

1

15

12

4

14

12

3

152496.9286

0.1152

1

16

12

5

15

12

4

162659.6207

0.1054

1

17

12

6

16

12

5

172821.5582

0.0703

1

18

12

7

17

12

6

182982.6579

-0.0268

0

14

13

1

13

13

0

142381.3361

-0.0879

B

0

14

13

2

13

13

1

142381.3361

-0.0879

B

0

15

13

2

14

13

1

152547.6795

-0.1412

B

0

15

13

3

14

13

2

152547.6795

-0.1412

B

0

16

13

3

15

13

2

162713.2633

-0.1863

B

0

16

13

4

15

13

3

162713.2633

-0.1863

B

0

17

13

4

16

13

3

172878.0754

-0.1837

0

17

13

5

16

13

4

172878.0754

-0.1837

Notes.

(a) The symmetry numbers σ = 0 and 1 label the A and E transitions, respectively. (b)

Observed frequency of the rotational transitions.

(c) Observed minus calculated frequency. (d)

Blended transitions are indicated using the capital letter B. In case of the lines composed from degenerate asymmetric rotor transitions, equal weights were assigned to the components of such blends. Any other transitions blended accidentally, as those corresponding to not related A and E components, were not included in the fit.

(e) The capital letter E indicates the excluded transitions.


Kolesniková et al.

Page 31

Table 4

Predicted rotational transition frequencies of methyl cyanate in the ground torsional state.


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

10

2

8

11

1

11

10037.989

0

24

3

21

24

3

22

1

24

3

21

24

3

22

1

1

0

1

0

0

0

1

0

1

0

0

1

27

2

25

28

1

24

1

24

23

0

22

0

22

1

6

1

5

0

6

1

0

27

2

1

22

0

0

20

0

1

46

0

46

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.606

2.17263

22.863

23.198

10123.728

0.068

11.19290

111.844

112.182

10126.000

0.076

11.15812

111.850

112.188

0

10143.236

0.001

16.56490

0.010

0.348

0

10144.141

0.001

16.56490

-0.019

0.319

0

28

10163.196

0.844

0.11595

134.136

134.475

2

21

10288.690

0.772

1.11353

99.248

99.591

21

2

19

10381.654

0.817

0.18553

83.694

84.040

6

1

6

10513.273

0.063

5.12684

8.067

8.418

5

6

1

6

10527.378

0.061

5.13346

8.041

8.392

25

28

0

28

10607.290

0.868

0.11595

134.113

134.467

22

21

2

19

10710.914

0.781

0.18553

83.708

84.065

20

19

2

17

10812.145

0.798

0.20540

69.546

69.907

5

41

46

5

42

10921.444

0.586

15.65714

394.992

395.356

5

41

46

5

42

10939.920

0.585

15.65549

394.997

395.362

21

0

21

20

2

18

11041.897

0.807

0.19712

76.446

76.814

20

0

20

19

2

17

11112.038

0.756

0.20540

69.561

69.932

1

35

4

31

35

4

32

11151.641

0.215

13.35297

231.788

232.160

0

35

4

31

35

4

32

11162.917

0.215

13.36125

231.791

232.163

1

10

1

9

9

2

7

11201.529

0.447

0.00000

19.810

20.184

1

21

0

21

20

2

18

11355.824

0.769

0.19712

76.459

76.838

1

7

2

6

8

1

7

11588.055

0.569

1.91477

13.611

13.998

0

7

2

6

8

1

7

11883.231

0.522

2.23398

13.587

13.983

1

15

2

13

15

2

14

12190.018

0.090

7.96275

45.060

45.467

0

15

2

13

15

2

14

12196.868

0.079

7.97931

45.043

45.450

0

16

1

16

15

2

13

12503.823

0.673

2.11512

45.450

45.867

1

7

2

5

8

1

7

12545.172

0.460

0.00000

13.612

14.030

1

25

3

22

25

3

23

12622.697

0.086

10.57669

120.323

120.744

0

25

3

22

25

3

23

12628.484

0.081

10.59491

120.317

120.738

1

16

1

16

15

2

13

12742.084

0.628

2.11389

45.467

45.892

0

10

1

9

9

2

8

12913.115

0.509

3.19790

19.729

20.160

0

23

1

23

22

2

20

12924.078

0.788

1.22654

91.291

91.722

1

14

1

14

13

2

12

12953.573

0.585

0.00000

35.280

35.712

1

10

1

9

9

2

8

13118.857

0.505

3.09980

19.746

20.184

1

47

5

42

47

5

43

13192.068

0.723

15.12044

410.957

411.397

0

47

5

42

47

5

43

13215.085

0.722

15.11878

410.962

411.403

1

23

1

23

22

2

20

13266.857

0.756

1.22700

91.304

91.747

1

1

1

1

2

0

2

13300.960

0.279

0.70883

1.024

1.468

0

1

1

1

2

0

2

13427.313

0.214

0.78587

0.996

1.444


Kolesniková et al.

Page 32


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

36

4

32

36

4

33

0

36

4

32

36

4

1

1

1

0

2

0

1

7

1

6

7

0

7

1

6

7

1

5

0

5

4

1

9

2

8

10

1

28

2

26

0

17

1

17

1

17

1

0

28

2

0

22

1

16

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

13621.669

0.261

12.80301

244.011

244.465

33

13638.312

0.263

12.80632

244.014

244.469

2

13923.838

0.224

0.00000

1.025

1.489

1

7

14008.972

0.080

4.44436

10.375

10.842

1

7

14031.459

0.080

4.44768

10.349

10.817

1

3

14130.903

0.212

0.00000

4.607

5.078

1

10

14332.732

0.575

0.00000

19.269

19.747

29

1

29

14702.210

0.836

0.69207

143.649

144.139

16

2

14

14892.676

0.690

2.00780

50.948

51.445

17

16

2

14

15143.195

0.646

2.00734

50.965

51.470

26

29

1

29

15168.800

0.857

0.69161

143.625

144.131

1

22

21

2

19

15182.243

0.773

1.34924

83.695

84.201

2

14

16

2

15

15362.723

0.103

7.37304

50.453

50.965

16

2

14

16

2

15

15378.232

0.094

7.38298

50.435

50.948

22

1

22

21

2

19

15507.178

0.740

1.34971

83.708

84.225

1

12

2

10

13

0

13

15529.924

0.694

0.14908

30.554

31.072

1

26

3

23

26

3

24

15554.302

0.098

10.01845

129.133

129.652

0

26

3

23

26

3

24

15567.628

0.097

10.03005

129.127

129.646

0

12

2

10

13

0

13

15761.764

0.752

0.14908

30.528

31.054

1

48

5

43

48

5

44

15833.956

0.888

14.59202

427.261

427.789

0

48

5

43

48

5

44

15862.396

0.888

14.59036

427.266

427.795

1

28

2

26

29

0

29

16115.128

0.853

0.10602

143.601

144.139

1

9

2

7

10

1

10

16250.059

0.532

1.99058

19.269

19.811

0

9

2

7

10

1

10

16398.256

0.596

2.05546

19.243

19.790

1

37

4

33

37

4

34

16503.098

0.316

12.26465

256.572

257.122

0

18

1

18

17

2

15

16513.120

0.707

1.88418

56.797

57.348

0

37

4

33

37

4

34

16525.399

0.319

12.26631

256.575

257.126

0

28

2

26

29

0

29

16581.103

0.875

0.10602

143.578

144.131

0

21

1

21

20

2

18

16681.992

0.757

1.47948

76.446

77.002

1

18

1

18

17

2

15

16776.626

0.665

1.88418

56.813

57.373

1

21

1

21

20

2

18

16990.065

0.722

1.47994

76.459

77.026

0

19

1

19

18

2

16

17353.248

0.724

1.75117

62.996

63.575

0

20

1

20

19

2

17

17408.662

0.741

1.61463

69.546

70.127

1

19

1

19

18

2

16

17630.626

0.684

1.75133

63.012

63.600

1

20

1

20

19

2

17

17700.883

0.703

1.61494

69.561

70.151

1

8

1

7

8

1

8

17999.947

0.100

3.92422

13.011

13.611

0

8

1

7

8

1

8

18031.204

0.101

3.92588

12.985

13.586

1

27

3

24

27

3

25

18955.388

0.112

9.48837

138.279

138.911

0

27

3

24

27

3

25

18976.127

0.114

9.49334

138.274

138.907

1

17

2

15

17

2

16

19029.859

0.117

6.84296

56.178

56.813

0

17

2

15

17

2

16

19053.901

0.109

6.84793

56.161

56.797

1

15

1

15

14

2

13

19081.942

0.593

0.00000

40.002

40.639


Kolesniková et al.

Page 33


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

5

0

5

4

1

4

19085.202

1

5

0

5

4

1

4

1

2

1

2

1

1

0

0

2

1

2

1

1

1

2

1

2

1

1

1

38

4

34

38

0

38

4

34

38

1

2

0

2

0

2

0

2

1

2

1

0

2

1

1

2

1

1

29

2

1

8

2

0

29

2

1

9

1

0

9

1

1

11

1

29

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.207

3.31368

4.413

5.050

19149.654

0.205

3.30922

4.439

5.078

19202.023

0.203

3.30922

1.488

2.129

1

19786.867

0.003

24.84735

1.444

2.104

1

19824.901

0.087

23.88659

1.468

2.129

4

35

19834.051

0.380

11.74120

269.470

270.132

4

35

19862.493

0.385

11.74120

269.474

270.137

1

0

1

20280.845

0.002

33.12814

0.348

1.024

1

0

1

20282.644

0.002

33.12814

0.319

0.996

1

1

1

0

20748.699

0.087

23.88659

1.489

2.181

1

1

1

0

20790.004

0.004

24.84735

1.461

2.154

1

1

1

1

21371.578

0.203

3.69209

1.468

2.181

27

30

1

30

21478.810

0.847

0.63426

153.426

154.142

7

9

1

9

21831.033

0.586

0.00000

15.976

16.704

27

30

1

30

21967.891

0.866

0.63380

153.402

154.135

8

9

1

9

22482.484

0.122

3.51838

15.976

16.726

8

9

1

9

22523.102

0.124

3.51838

15.950

16.701

2

9

12

0

12

22563.711

0.688

0.12424

26.219

26.972

2

27

30

0

30

22653.426

0.862

0.09773

153.386

154.142

11

2

9

12

0

12

22785.867

0.749

0.12589

26.192

26.952

6

0

6

5

1

4

22854.514

0.217

0.00000

6.340

7.102

1

28

3

25

28

3

26

22856.189

0.129

8.98315

147.762

148.524

0

28

3

25

28

3

26

22884.487

0.134

8.98646

147.757

148.520

1

11

1

10

10

2

8

23034.144

0.445

0.00000

23.218

23.986

0

29

2

27

30

0

30

23141.703

0.882

0.09773

153.363

154.135

1

8

2

6

9

1

9

23156.649

0.521

1.76209

15.976

16.748

1

18

2

16

18

2

17

23207.488

0.132

6.36589

62.238

63.012

0

18

2

16

18

2

17

23240.235

0.124

6.36920

62.221

62.996

0

8

2

6

9

1

9

23271.022

0.587

1.89263

15.950

16.726

1

6

2

5

7

1

6

23593.475

0.605

1.32803

10.842

11.629

1

39

4

35

39

4

36

23650.318

0.454

11.23266

282.707

283.496

0

39

4

35

39

4

36

23685.519

0.461

11.23100

282.711

283.501

0

6

2

5

7

1

6

23954.633

0.528

1.79007

10.817

11.616

1

6

2

4

7

1

6

24361.809

0.475

0.00000

10.842

11.655

1

16

1

16

15

2

14

24932.102

0.601

0.00000

45.060

45.892

0

11

1

10

10

2

9

25621.318

0.502

3.72330

23.108

23.963

1

8

1

8

8

0

8

25787.995

0.186

0.00000

12.151

13.011

1

11

1

10

10

2

9

25800.673

0.485

3.67040

23.125

23.986

1

29

3

26

29

3

27

27281.610

0.148

8.50773

157.580

158.490

0

29

3

26

29

3

27

27317.797

0.156

8.50773

157.575

158.486

1

7

1

7

7

0

7

27433.207

0.191

0.00000

9.460

10.375

1

10

1

9

10

1

10

27451.588

0.146

3.19206

19.268

20.184


Kolesniková et al.

Page 34


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

10

2

9

11

0

11

27469.791

0

10

1

9

10

1

10

1

19

2

17

19

2

18

0

19

2

17

19

2

1

40

4

36

40

4

0

40

4

36

40

1

3

1

3

2

1

30

2

28

1

6

1

6

0

30

2

1

7

2

0

3

1

3

1 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.712

3.19206

22.210

23.126

27502.255

0.147

3.19206

19.243

20.160

27905.431

0.147

5.93852

68.630

69.561

18

27947.239

0.139

5.94017

68.614

69.546

37

27984.206

0.540

10.73902

296.281

297.214

4

37

28026.868

0.548

10.73571

296.284

297.219

1

1

28140.188

0.089

0.00000

2.181

3.120

31

1

31

28753.359

0.858

0.58352

163.524

164.483

6

0

6

28944.423

0.196

0.00000

7.102

8.067

28

31

1

31

29265.132

0.876

0.58290

163.501

164.477

6

8

1

8

29588.002

0.607

0.00000

13.011

13.998

1

3

2

1

2

29676.690

0.005

44.17196

2.104

3.094

1

3

2

1

2

29686.865

0.029

44.01625

2.130

3.120

30

2

28

31

0

31

29728.030

0.871

0.08945

163.491

164.483

3

2

2

2

2

0

29765.947

0.577

0.00000

5.558

6.551

1

10

2

8

11

0

11

30236.320

0.682

0.09939

22.209

23.218

0

30

2

28

31

0

31

30238.875

0.890

0.08945

163.468

164.477

1

5

1

5

5

0

5

30293.181

0.201

0.00000

5.079

6.089

0

6

0

6

5

1

5

30311.420

0.203

4.24009

6.062

7.073

1

6

0

6

5

1

5

30370.199

0.200

4.23763

6.089

7.102

1

3

0

3

2

0

2

30407.209

0.003

49.68973

1.025

2.039

0

3

0

3

2

0

2

30409.877

0.003

49.68973

0.996

2.010

0

3

2

2

2

2

1

30433.532

0.003

27.60872

5.526

6.541

1

3

2

1

2

2

0

30441.895

0.004

27.60044

5.558

6.573

1

3

2

2

2

2

1

30443.563

0.003

27.60044

5.536

6.551

0

10

2

8

11

0

11

30445.614

0.748

0.10105

22.182

23.198

0

3

2

1

2

2

0

30455.745

0.003

27.60872

5.526

6.542

1

7

2

5

8

1

8

30545.119

0.518

1.44288

13.011

14.030

0

7

2

5

8

1

8

30610.613

0.580

1.68690

12.985

14.006

1

3

2

1

2

2

1

31119.510

0.578

0.00000

5.535

6.573

1

3

1

2

2

1

1

31166.191

0.029

44.01625

2.181

3.221

0

3

1

2

2

1

1

31181.260

0.006

44.17196

2.154

3.194

1

7

0

7

6

1

5

31232.400

0.223

0.00000

8.418

9.460

1

4

1

4

4

0

4

31454.256

0.206

0.00000

3.390

4.439

1

30

3

27

30

3

28

32250.550

0.170

8.05717

167.733

168.809

0

30

3

27

30

3

28

32295.066

0.180

8.05717

167.729

168.806

1

3

1

3

3

0

3

32405.516

0.212

0.00000

2.039

3.120

1

3

1

2

2

1

2

32712.867

0.089

3.20082

2.130

3.221

1

41

4

37

41

4

38

32863.483

0.640

10.26196

310.190

311.286

1

11

1

10

11

1

11

32900.617

0.171

2.92536

22.889

23.986

0

41

4

37

41

4

38

32914.342

0.649

10.25864

310.194

311.292

0

11

1

10

11

1

11

32962.065

0.172

2.92702

22.864

23.963


Kolesniková et al.

Page 35


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

2

1

2

2

0

2

33125.861

1

20

2

18

20

2

19

0

20

2

18

20

2

19

1

1

1

1

1

0

1

1

1

0

1

0

0

1

1

0

1

1

2

1

1

2

0

2

1

1

1

12

1

11

1

5

2

4

1

3

1

2

0

3

1

0

5

2

1

5

1

4

1 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.226

0.00000

1.024

2.129

33127.688

0.161

5.55421

75.355

76.460

33179.023

0.153

5.55421

75.338

76.445

1

33581.805

0.279

0.00000

0.348

1.468

1

34204.683

0.225

2.08007

0.348

1.489

0

1

34211.545

0.216

2.30640

0.319

1.460

0

2

34672.537

0.204

3.76020

1.024

2.181

2

0

2

34718.906

0.218

3.81555

0.996

2.154

11

2

9

34772.755

0.442

0.00000

26.972

28.132

6

1

5

35371.487

0.628

0.85429

8.418

9.598

3

0

3

35431.519

0.207

5.26213

2.039

3.221

2

3

0

3

35490.290

0.220

5.28181

2.010

3.194

4

6

1

5

35799.131

0.533

1.36923

8.392

9.586

2

3

6

1

5

36067.519

0.488

0.00000

8.418

9.621

1

3

4

0

4

36473.007

0.212

6.67933

3.390

4.607

31

2

29

32

1

32

36479.621

0.869

0.53908

173.943

175.160

4

1

3

4

0

4

36538.021

0.224

6.68825

3.361

4.580

1

4

1

4

3

1

2

36539.473

0.053

6.68825

3.220

4.439

1

9

2

8

10

0

10

36555.339

0.723

6.68825

18.528

19.747

0

31

2

29

32

1

32

37014.141

0.887

0.53862

173.920

175.155

1

31

2

29

32

0

32

37286.991

0.881

0.08282

173.916

175.160

1

6

2

5

7

1

7

37602.447

0.629

0.00000

10.375

11.629

1

31

3

28

31

3

29

37775.557

0.194

7.63642

178.221

179.481

1

5

1

4

5

0

5

37808.866

0.217

8.01320

5.078

6.339

0

31

2

29

32

0

32

37820.514

0.899

0.08282

173.893

175.155

0

31

3

28

31

3

29

37828.898

0.207

7.63476

178.217

179.479

0

5

1

4

5

0

5

37878.349

0.228

8.01797

5.050

6.313

1

42

4

38

42

4

39

38310.500

0.754

9.80145

324.435

325.713

0

42

4

38

42

4

39

38370.289

0.765

9.79814

324.440

325.720

1

6

2

4

7

1

7

38370.782

0.521

1.06725

10.375

11.655

0

6

2

4

7

1

7

38373.733

0.573

1.44288

10.349

11.629

1

9

2

7

10

0

10

38472.667

0.676

0.07620

18.528

19.811

0

12

1

11

11

2

10

38522.572

0.495

4.28222

26.823

28.108

0

9

2

7

10

0

10

38663.009

0.747

0.07951

18.500

19.790

1

12

1

11

11

2

10

38682.062

0.471

4.25269

26.842

28.132

1

12

1

11

12

1

12

38820.928

0.196

2.70670

26.837

28.132

1

21

2

19

21

2

20

38873.028

0.175

5.20966

82.411

83.708

0

12

1

11

12

1

12

38893.901

0.198

2.70670

26.811

28.108

0

21

2

19

21

2

20

38934.409

0.167

5.20966

82.395

83.694

1

6

1

5

6

0

6

39457.696

0.223

9.25159

7.102

8.418

0

6

1

5

6

0

6

39531.205

0.233

9.25466

7.073

8.392

0

4

1

4

3

1

3

39562.238

0.006

62.11672

3.093

4.413


Kolesniková et al.

Page 36


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

4

1

4

3

1

3

1

4

2

3

3

2

1

4

0

4

3

0

0

4

0

4

3

0

4

2

3

3

1

4

3

1

0

4

3

2

0

4

3

1

4

3

1

4

1

4

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

39565.476

0.014

62.07862

3.119

4.439

1

39921.807

0.573

2.13557

6.573

7.905

3

40516.736

0.004

66.24635

2.039

3.390

0

3

40520.237

0.004

66.24635

2.010

3.362

2

2

40573.340

0.004

49.69470

6.542

7.895

3

3

0

40587.964

0.005

28.98858

12.226

13.580

3

3

1

40591.142

0.004

28.98858

12.201

13.555

1

3

3

0

40591.373

0.004

28.98858

12.201

13.555

2

3

3

1

40591.761

0.004

28.98858

12.197

13.551

2

3

3

2

2

40597.754

0.005

49.61022

6.551

7.905

2

2

3

2

1

40599.294

0.006

49.61022

6.573

7.927

4

2

2

3

2

1

40628.835

0.004

49.69470

6.543

7.898

4

2

2

3

2

2

41275.241

0.574

0.00000

6.550

7.927

1

7

1

6

7

0

7

41442.179

0.229

10.38065

9.460

10.842

0

7

1

6

7

0

7

41519.810

0.240

10.38264

9.432

10.817

1

4

1

3

3

1

2

41558.224

0.013

62.07862

3.221

4.607

0

4

1

3

3

1

2

41567.968

0.008

62.11672

3.193

4.580

0

7

0

7

6

1

6

41691.940

0.199

5.22092

8.041

9.432

1

7

0

7

6

1

6

41745.672

0.196

5..21938

8.068

9.460

1

1

1

1

0

0

0

43725.041

0.279

1.38676

0.009

1.468

1

8

1

7

8

0

8

43787.942

0.237

11.38685

12.150

13.611

0

1

1

1

0

0

0

43854.098

0.215

1.53760

-0.019

1.444

1

32

3

29

32

3

30

43862.806

0.221

7.24217

189.043

190.506

0

8

1

7

8

0

8

43870.060

0.247

11.38839

12.123

13.586

0

32

3

29

32

3

30

43925.482

0.237

7.24052

189.040

190.505

1

43

4

39

43

4

40

44341.568

0.887

9.36248

339.016

340.495

1

1

1

0

0

0

0

44347.919

0.225

0.00000

0.010

1.489

0

43

4

39

43

4

40

44410.977

0.899

9.35917

339.022

340.503

1

5

1

5

4

1

3

44424.083

0.047

8.13806

4.607

6.089

1

4

1

3

3

1

3

44584.227

0.054

8.11791

3.120

4.607

1

32

2

30

33

1

33

44608.934

0.882

0.50018

184.685

186.173

1

22

2

20

22

2

21

45135.620

0.188

4.90155

89.798

91.304

0

32

2

30

33

1

33

45166.107

0.899

0.49972

184.662

186.169

1

13

1

12

13

1

13

45201.523

0.222

2.52283

31.111

32.619

0

22

2

20

22

2

21

45207.583

0.179

4.90155

89.783

91.291

1

32

2

30

33

0

33

45276.665

0.892

0.07620

184.663

186.173

0

13

1

12

13

1

13

45286.756

0.224

2.52283

31.085

32.596

0

32

2

30

33

0

33

45832.814

0.909

0.07620

184.640

186.169

1

8

2

7

9

0

9

45871.077

0.741

0.07620

15.174

16.704

1

5

2

4

6

1

6

45884.760

0.640

0.00000

8.067

9.598

1

13

1

12

12

2

10

46363.264

0.438

0.00000

31.072

32.619

0

5

2

3

6

1

6

46520.616

0.567

1.16704

8.041

9.593


Kolesniková et al.

Page 37


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

9

1

8

9

0

9

1

5

2

3

6

1

0

9

1

8

9

0

1

4

2

3

5

1

8

2

6

9

0

8

2

6

0

4

2

3

1

4

2

0

5

1

1

5

1

1

10

1

0

10

1

5

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

46522.529

0.246

12.25928

15.174

16.726

6

46580.792

0.524

0.72513

8.067

9.621

9

46609.668

0.256

12.26051

15.146

16.701

1

4

46931.660

0.639

0.52309

6.340

7.905

0

9

47196.694

0.672

0.05466

15.174

16.748

9

0

9

47357.588

0.747

0.05798

15.146

16.726

5

1

4

47411.259

0.538

0.97146

6.314

7.895

2

5

1

4

47609.146

0.495

0.00000

6.339

7.927

5

4

1

4

49442.176

0.008

79.50821

4.413

6.062

5

4

1

4

49442.835

0.010

79.49496

4.440

6.089

9

10

0

10

49674.196

0.257

12.99026

18.527

20.184

1

9

10

0

10

49767.007

0.267

12.99118

18.500

20.160

2

4

4

2

2

50074.550

0.560

0.42572

7.928

9.598

33

3

30

33

3

31

50512.355

0.252

6.87609

200.197

201.882

33

3

30

33

3

31

50584.852

0.271

6.87609

200.195

201.882

1

5

0

5

4

0

4

50603.910

0.005

82.79800

3.390

5.078

0

5

0

5

4

0

4

50608.197

0.005

82.79800

3.362

5.050

0

5

2

4

4

2

3

50709.122

0.004

69.57092

7.895

9.586

1

5

4

1

4

4

0

50738.843

0.005

29.81682

21.487

23.179

1

5

3

2

4

3

1

50739.523

0.006

53.00768

13.581

15.273

0

5

4

2

4

4

1

50741.477

0.005

29.81682

21.471

23.164

0

5

4

1

4

4

0

50741.479

0.005

29.81682

21.471

23.164

0

5

3

3

4

3

2

50743.258

0.005

53.00768

13.555

15.248

1

5

4

2

4

4

1

50743.995

0.005

29.81682

21.456

23.149

0

5

3

2

4

3

1

50744.065

0.005

53.00768

13.555

15.248

1

5

3

3

4

3

2

50744.286

0.005

53.00768

13.551

15.244

1

5

2

4

4

2

3

50752.037

0.012

69.13195

7.905

9.598

1

5

2

3

4

2

2

50770.582

0.012

69.13195

7.927

9.621

0

5

2

3

4

2

2

50819.965

0.005

69.57092

7.898

9.593

1

5

2

3

4

2

3

51448.069

0.560

1.57742

7.905

9.621

0

13

1

12

12

2

11

51604.489

0.488

4.87834

30.875

32.596

1

13

1

12

12

2

11

51747.915

0.459

4.86143

30.893

32.619

1

6

1

6

5

1

4

51798.937

0.055

4.86143

6.339

8.067

1

23

2

21

23

2

22

51905.611

0.200

4.62658

97.517

99.248

1

5

1

4

4

1

3

51939.768

0.010

79.49496

4.606

6.339

0

5

1

4

4

1

3

51948.524

0.010

79.50655

4.580

6.313

0

23

2

21

23

2

22

51988.685

0.191

4.62658

97.502

99.236

1

14

1

13

14

1

14

52028.705

0.247

2.36878

35.713

37.448

0

14

1

13

14

1

14

52126.908

0.249

2.36878

35.687

37.426

1

33

2

31

34

1

34

53090.556

0.897

0.46635

195.747

197.518

0

8

0

8

7

1

7

53197.398

0.194

6.26203

10.349

12.123

1

8

0

8

7

1

7

53246.292

0.191

6.26111

10.375

12.151


Kolesniková et al.

Page 38


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

11

1

10

11

0

11

0

11

1

10

11

0

1

2

1

2

1

0

0

2

1

2

1

1

33

2

31

34

0

33

2

31

0

33

2

31

1

4

2

1

20

2

1

2

1

0

4

2

1

4

1

7

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

53270.465

0.269

13.57624

22.209

23.986

11

53369.691

0.279

13.57701

22.183

23.963

1

53406.706

0.226

2.27288

0.348

2.129

0

1

53496.823

0.213

2.30640

0.320

2.104

0

34

53642.001

0.905

0.07123

195.729

197.518

34

1

34

53670.136

0.913

0.46589

195.724

197.514

34

0

34

54220.560

0.922

0.07123

195.705

197.514

3

5

1

5

54447.345

0.640

0.00000

6.089

7.905

19

20

1

19

54798.211

0.386

0.00000

73.527

75.355

1

1

0

1

54953.382

0.205

0.00000

0.348

2.181

2

5

1

5

55015.898

0.563

0.86767

6.063

7.898

2

2

5

1

5

55124.831

0.524

0.46497

6.088

7.927

2

6

8

0

8

55375.997

0.767

0.00000

12.151

13.998

7

2

5

8

0

8

56333.114

0.671

0.03479

12.151

14.030

7

2

5

8

0

8

56449.469

0.747

0.03976

12.123

14.006

1

5

1

4

4

1

4

56958.519

0.048

0.00000

4.439

6.339

1

12

1

11

12

0

12

57336.466

0.283

14.01845

26.219

28.132

0

12

1

11

12

0

12

57442.920

0.292

14.01907

26.192

28.108

1

34

3

31

34

3

32

57718.584

0.287

6.53817

211.685

213.610

1

14

1

13

13

2

11

57750.170

0.433

0.00000

35.522

37.448

0

34

3

31

34

3

32

57801.342

0.308

6.53817

211.683

213.611

1

3

2

2

4

1

3

58273.674

0.647

0.29076

4.607

6.551

1

19

2

18

19

1

18

58638.423

0.397

0.00000

66.674

68.630

1

7

1

7

6

1

5

58665.607

0.071

0.00000

8.418

10.375

0

3

2

2

4

1

3

58786.443

0.542

0.59936

4.580

6.541

1

3

2

1

4

1

3

58949.621

0.499

0.00000

4.607

6.573

1

24

2

22

24

2

23

59169.607

0.211

4.38307

105.564

107.538

0

24

2

22

24

2

23

59264.283

0.202

4.38307

105.550

107.527

1

15

1

14

15

1

15

59285.759

0.273

2.23957

40.639

42.617

1

6

1

6

5

1

5

59314.622

0.010

96.61644

6.088

8.067

0

6

1

6

5

1

5

59315.247

0.009

96.62141

6.062

8.041

0

15

1

14

15

1

15

59397.599

0.275

2.23957

40.614

42.595

1

6

2

5

5

2

3

60200.535

0.520

2.42695

9.621

11.629

1

6

0

6

5

0

5

60663.380

0.006

99.34302

5.078

7.102

0

6

0

6

5

0

5

60668.394

0.006

99.34302

5.049

7.073

0

6

2

5

5

2

4

60839.874

0.005

88.34227

9.587

11.616

1

6

4

2

5

4

1

60889.761

0.006

55.21744

23.180

25.211

0

6

4

3

5

4

2

60892.936

0.006

55.21744

23.164

25.195

0

6

4

2

5

4

1

60892.944

0.006

55.21744

23.164

25.195

1

6

3

3

5

3

2

60894.129

0.008

74.54205

15.273

17.304

1

6

5

1

5

5

0

60894.426

0.006

30.37009

33.336

35.367

0

6

5

2

5

5

1

60895.362

0.006

30.37009

33.332

35.363


Kolesniková et al.

Page 39


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

6

5

1

5

5

0

1

6

4

3

5

4

1

6

2

5

5

2

0

6

3

4

5

1

6

3

4

5

1

6

5

2

0

6

3

3

1

6

2

0

6

2

1

6

2

1

34

2

1

13

1

0

13

1

1

6

0

6

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

60895.362

0.006

30.37009

33.332

35.363

2

60895.949

0.006

55.21744

23.149

25.180

4

60896.567

0.030

87.01542

9.598

11.629

3

3

60898.049

0.005

74.54205

15.248

17.279

3

3

60899.865

0.005

74.54205

15.244

17.275

5

5

1

60900.185

0.006

30.37009

33.308

35.339

5

3

2

60900.200

0.005

74.54205

15.248

17.279

4

5

2

3

60968.870

0.030

87.01542

9.621

11.655

4

5

2

3

61033.407

0.006

88.34227

9.593

11.629

4

5

2

4

61664.902

0.521

7.47919

9.598

11.655

32

35

1

35

61872.144

0.915

0.43668

207.130

209.194

12

13

0

13

61893.188

0.298

14.32351

30.554

32.619

12

13

0

13

62007.737

0.307

14.32397

30.528

32.596

1

5

5

1

4

62312.210

0.011

96.61478

6.339

8.418

1

5

5

1

4

62321.250

0.011

96.61975

6.313

8.392

34

2

32

35

0

35

62326.948

0.922

0.06792

207.115

209.194

18

2

17

18

1

17

62431.151

0.408

0.00000

60.156

62.238

0

34

2

32

35

1

35

62473.728

0.931

0.43637

207.107

209.191

1

3

1

3

2

0

2

62812.725

0.212

3.07505

1.025

3.120

0

3

1

3

2

0

2

62890.870

0.211

3.08658

0.996

3.094

0

34

2

32

35

0

35

62927.538

0.939

0.06792

207.092

209.191

1

3

2

2

4

1

4

63292.425

0.634

0.00000

4.440

6.551

0

3

2

1

4

1

4

63829.238

0.559

0.55615

4.413

6.542

1

3

2

1

4

1

4

63968.372

0.524

0.26846

4.439

6.573

0

9

0

9

8

1

8

64795.648

0.189

7.36818

12.985

15.146

1

9

0

9

8

1

8

64839.767

0.185

7.36756

13.011

15.174

0

14

1

13

13

2

12

64852.699

0.480

5.51614

35.263

37.426

1

14

1

13

13

2

12

64982.279

0.449

5.50599

35.280

37.448

1

6

2

5

7

0

7

65035.654

0.792

3.01108

9.460

11.629

1

35

3

32

35

3

33

65470.752

0.327

6.22840

223.504

225.688

0

35

3

32

35

3

33

65564.140

0.349

6.22675

223.502

225.689

1

6

2

4

7

0

7

65803.989

0.674

0.01988

9.460

11.655

1

3

1

2

2

0

2

65838.728

0.208

0.00000

1.025

3.221

0

6

2

4

7

0

7

65862.084

0.747

0.02650

9.432

11.629

1

17

2

16

17

1

16

66148.199

0.418

0.00000

53.972

56.178

1

25

2

23

25

2

24

66911.005

0.222

4.16607

113.942

116.174

1

16

1

15

16

1

16

66952.662

0.297

2.13025

45.892

48.125

1

14

1

13

14

0

14

66955.770

0.314

14.50310

35.215

37.448

0

25

2

23

25

2

24

67017.730

0.213

4.16607

113.928

116.163

0

16

1

15

16

1

16

67078.759

0.299

2.13025

45.866

48.104

0

14

1

13

14

0

14

67079.314

0.323

14.50326

35.188

37.426

1

15

1

14

14

2

12

68878.388

0.427

0.00000

40.319

42.617


Kolesniková et al.

Page 40


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

7

1

7

6

1

6

0

7

1

7

6

1

1

2

2

1

3

1

1

16

2

15

16

1

6

1

5

5

0

2

2

1

1

2

2

0

1

7

2

1

7

0

0

7

0

1

35

2

0

7

2

1

7

2

1

7

1

7

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

69178.880

0.011

113.57392

8.067

10.375

6

69180.290

0.011

113.57558

8.041

10.349

2

69388.336

0.658

0.11701

3.220

5.535

1

15

69763.740

0.427

0.00000

48.125

50.452

1

5

69827.895

0.057

0.00000

6.089

8.418

3

1

2

69920.880

0.546

0.26339

3.194

5.526

3

1

2

70065.951

0.501

0.00000

3.221

5.558

6

6

2

4

70251.508

0.440

9.85115

11.655

13.998

7

6

0

6

70690.096

0.007

115.87976

7.102

9.460

7

6

0

6

70695.767

0.007

115.87976

7.074

9.432

33

36

1

36

70900.386

0.938

0.41085

218.834

221.199

6

6

2

5

70964.597

0.006

106.48249

11.616

13.983

6

6

2

5

71019.842

0.052

104.33568

11.629

13.998

4

3

6

4

2

71042.395

0.007

78.09191

25.210

27.580

5

2

6

5

1

71045.739

0.006

56.79442

35.367

37.737

7

4

4

6

4

3

71046.113

0.007

78.09191

25.195

27.565

7

4

3

6

4

2

71046.139

0.007

78.09191

25.195

27.565

0

7

5

3

6

5

2

71046.848

0.006

56.79442

35.363

37.733

0

7

5

2

6

5

1

71046.848

0.006

56.79442

35.363

37.733

1

7

4

4

6

4

3

71049.622

0.006

78.09191

25.180

27.550

1

7

3

4

6

3

3

71052.402

0.009

94.65681

17.304

19.674

1

7

5

3

6

5

2

71052.460

0.007

56.79442

35.340

37.710

0

7

6

1

6

6

0

71053.831

0.006

30.76433

47.775

50.145

0

7

6

2

6

6

1

71053.831

0.006

30.76433

47.775

50.145

1

7

6

1

6

6

0

71055.478

0.007

30.76433

47.769

50.139

0

7

3

5

6

3

4

71055.842

0.006

94.65681

17.279

19.649

1

7

3

5

6

3

4

71059.101

0.006

94.65681

17.275

19.645

0

7

3

4

6

3

3

71060.677

0.006

94.65681

17.279

19.649

1

7

6

2

6

6

1

71060.705

0.007

30.76433

47.748

50.118

1

7

2

5

6

2

4

71208.624

0.052

104.33734

11.655

14.030

0

7

2

5

6

2

4

71273.135

0.007

106.48249

11.629

14.006

1

35

2

33

36

0

36

71275.026

0.944

0.06295

218.822

221.199

0

35

2

33

36

1

36

71523.418

0.955

0.41054

218.811

221.197

0

35

2

33

36

0

36

71897.107

0.961

0.06295

218.799

221.197

1

4

1

4

3

0

3

71970.992

0.206

3.88136

2.038

4.439

1

7

2

5

6

2

5

71976.959

0.441

3.88136

11.629

14.030

0

4

1

4

3

0

3

72043.231

0.208

3.88644

2.010

4.413

1

2

2

1

3

1

3

72414.339

0.624

0.00000

3.120

5.535

1

15

1

14

15

0

15

72532.022

0.332

14.57260

40.198

42.617

0

15

1

14

15

0

15

72665.476

0.340

14.57245

40.171

42.595

1

7

1

6

6

1

5

72674.579

0.012

113.57227

8.418

10.842

0

7

1

6

6

1

5

72684.372

0.012

113.57392

8.393

10.817


Kolesniková et al.

Page 41


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

2

2

0

3

1

3

72935.731

1

2

2

0

3

1

3

1

15

2

14

15

1

14

1

36

3

33

36

3

0

36

3

33

36

3

1

5

2

4

6

1

17

1

16

17

1

26

2

24

0

17

1

16

0

26

2

0

5

2

1

5

0

10

1 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.556

0.25201

3.093

5.526

73091.954

0.526

0.11132

3.120

5.558

73254.461

0.436

0.00000

42.616

45.060

34

73753.563

0.372

5.94514

235.655

238.115

34

73857.863

0.396

5.94514

235.653

238.117

0

6

74829.183

0.807

0.13086

7.102

9.598

1

17

75005.877

0.321

2.03748

51.470

53.972

26

2

25

75110.215

0.233

3.97558

122.648

125.153

17

1

17

75146.787

0.323

2.03748

51.445

53.952

24

26

2

25

75229.370

0.223

3.97558

122.635

125.144

3

6

0

6

75524.443

0.747

0.01491

7.074

9.593

2

3

6

0

6

75525.215

0.679

0.00994

7.102

9.621

0

10

9

1

9

76452.627

0.183

8.54229

15.950

18.500

10

0

10

9

1

9

76492.010

0.180

8.54168

15.976

18.527

14

2

13

14

1

13

76599.570

0.445

0.00000

37.448

40.003

1

4

1

3

3

0

3

76989.743

0.212

0.00000

2.039

4.607

0

15

1

14

14

2

13

78250.654

0.473

6.19991

39.985

42.595

1

15

1

14

14

2

13

78367.701

0.439

6.19376

40.003

42.617

1

16

1

15

16

0

16

78621.325

0.350

14.55077

45.502

48.125

0

16

1

15

16

0

16

78765.595

0.357

14.55062

45.477

48.104

1

8

1

8

7

1

7

79034.287

0.012

130.42871

10.375

13.011

0

8

1

8

7

1

7

79036.254

0.012

130.43037

10.349

12.985

1

16

1

15

15

2

13

79694.746

0.420

0.00000

45.467

48.125

1

13

2

12

13

1

12

79780.676

0.455

0.00000

32.619

35.280

1

36

2

34

37

1

37

80121.782

0.969

0.38840

230.858

233.531

1

8

2

7

7

2

5

80165.726

0.333

0.38840

14.030

16.704

1

8

3

6

7

3

4

80371.619

0.371

5.22969

19.674

22.355

1

36

2

34

37

0

37

80430.039

0.974

0.05963

230.848

233.531

1

8

0

8

7

0

7

80679.499

0.008

132.40987

9.460

12.151

0

8

0

8

7

0

7

80685.749

0.008

132.40987

9.432

12.123

0

36

2

34

37

1

37

80765.558

0.987

0.38809

230.837

233.531

1

5

1

5

4

0

4

80897.091

0.201

4.71182

3.391

6.089

0

5

1

5

4

0

4

80965.170

0.204

4.71459

3.361

6.062

0

36

2

34

37

0

37

81072.920

0.992

0.05963

230.827

233.531

0

8

2

7

7

2

6

81082.300

0.007

124.22681

13.982

16.687

1

8

2

7

7

2

6

81122.843

0.057

122.37982

13.998

16.704

1

8

4

4

7

4

3

81197.029

0.008

99.39106

27.581

30.289

1

8

5

3

7

5

2

81198.084

0.007

80.75554

37.738

40.446

0

8

5

4

7

5

3

81199.375

0.007

80.75554

37.732

40.441

0

8

5

3

7

5

2

81199.376

0.007

80.75554

37.732

40.441

0

8

4

5

7

4

4

81201.287

0.007

99.39106

27.565

30.274

0

8

4

4

7

4

3

81201.360

0.007

99.39106

27.565

30.274


Kolesniková et al.

Page 42


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

8

4

5

7

4

4

1

8

5

4

7

5

0

8

6

2

7

6

0

8

6

3

7

1

8

6

2

7

1

8

6

3

1

8

3

5

0

8

3

0

8

7

0

8

1

8

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

81205.299

0.007

99.39106

27.550

30.259

3

81205.769

0.008

80.75554

37.709

40.418

1

81205.903

0.007

57.97715

50.145

52.854

6

2

81205.903

0.007

57.97715

50.145

52.854

6

1

81207.762

0.008

57.97715

50.139

52.848

7

6

2

81213.741

0.008

57.97715

50.118

52.827

7

3

4

81214.989

0.010

113.88037

19.674

22.383

6

7

3

5

81216.855

0.007

113.88369

19.649

22.358

2

7

7

1

81218.008

0.008

31.05919

64.793

67.502

7

1

7

7

0

81218.008

0.008

31.05919

64.793

67.502

3

6

7

3

5

81222.578

0.007

113.88037

19.646

22.355

8

7

1

7

7

0

81222.723

0.009

31.05919

64.779

67.488

8

7

2

7

7

1

81226.107

0.007

31.05919

64.767

67.476

0

8

3

5

7

3

4

81226.514

0.007

113.88369

19.650

22.359

1

8

2

6

7

2

5

81491.342

0.056

122.38148

14.030

16.748

0

8

2

6

7

2

5

81542.623

0.008

124.22847

14.006

16.726

1

8

3

5

7

3

5

82065.949

0.371

0.00000

19.646

22.383

1

8

2

6

7

2

6

82448.459

0.334

7.96938

13.998

16.748

1

37

3

34

37

3

35

82547.707

0.425

5.68839

248.136

250.889

0

37

3

34

37

3

35

82663.106

0.449

5.68673

248.135

250.892

1

12

2

11

12

1

11

82781.559

0.465

0.00000

28.132

30.893

1

8

1

7

7

1

6

83025.262

0.013

130.42540

10.842

13.611

0

8

1

7

7

1

6

83035.999

0.014

130.42705

10.816

13.586

1

7

1

6

6

1

6

83187.852

0.072

0.00000

8.067

10.842

1

18

1

17

18

1

18

83418.223

0.343

1.95963

57.372

60.155

0

18

1

17

18

1

18

83574.431

0.345

1.95963

57.348

60.136

1

27

2

25

27

2

26

83744.759

0.243

3.80827

131.682

134.475

0

27

2

25

27

2

26

83876.654

0.234

3.80827

131.669

134.467

1

4

2

3

5

0

5

84740.525

0.813

0.60296

5.078

7.905

1

16

2

14

16

1

15

85126.463

0.421

19.68666

48.125

50.965

1

17

2

15

17

1

16

85178.058

0.415

21.27131

53.972

56.813

1

17

1

16

17

0

17

85214.024

0.368

14.45790

51.130

53.972

0

16

2

14

16

1

15

85255.152

0.465

19.69358

48.104

50.948

0

17

2

15

17

1

16

85305.035

0.457

21.27654

53.952

56.797

0

17

1

16

17

0

17

85369.984

0.375

14.45744

51.104

53.952

0

4

2

2

5

0

5

85372.872

0.748

0.00828

5.050

7.898

1

4

2

2

5

0

5

85418.012

0.682

0.00497

5.078

7.927

1

15

2

13

15

1

14

85444.479

0.428

18.05681

42.617

45.467

0

15

2

13

15

1

14

85575.031

0.472

18.06665

42.596

45.450

1

11

2

10

11

1

10

85587.822

0.476

0.00000

23.986

26.841

1

18

2

16

18

1

17

85638.639

0.409

22.78047

60.155

63.012

0

18

2

16

18

1

17

85764.282

0.450

22.78477

60.135

62.996


Kolesniková et al.

Page 43


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

14

2

12

14

1

13

0

14

2

12

14

1

1

19

2

17

19

1

0

19

2

17

19

1

13

2

11

13

0

13

2

11

1

20

2

18

0

20

2

0

11

0

1

12

1

11

1

10

0

12

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

86088.883

0.434

16.41188

37.447

40.319

13

86221.135

0.480

16.42649

37.426

40.302

18

86543.855

0.403

24.18537

66.674

69.561

1

18

86668.712

0.443

24.18891

66.655

69.546

1

12

87012.785

0.440

14.77910

32.619

35.521

13

1

12

87146.122

0.488

14.80232

32.596

35.503

20

1

19

87925.900

0.397

25.46020

73.527

76.460

18

20

1

19

88050.650

0.437

25.46327

73.508

76.445

11

10

1

10

88133.484

0.177

9.78483

19.242

22.182

2

10

12

1

11

88166.209

0.445

13.18061

28.131

31.072

0

11

10

1

10

88168.191

0.174

9.78436

19.268

22.209

2

9

10

1

9

88186.394

0.491

0.00000

20.184

23.126

2

10

12

1

11

88299.340

0.495

13.21952

28.109

31.054

5

1

4

4

0

4

88412.776

0.217

0.00000

3.390

6.339

9

1

9

8

1

8

88879.812

0.014

147.21724

13.011

15.976

0

9

1

9

8

1

8

88882.214

0.013

147.21724

12.985

15.950

1

11

2

9

11

1

10

89497.129

0.449

11.63041

23.987

26.972

1

6

1

6

5

0

5

89607.803

0.196

5.57718

5.078

8.067

0

11

2

9

11

1

10

89627.697

0.503

11.69868

23.962

26.952

0

6

1

6

5

0

5

89672.221

0.200

5.57887

5.050

8.041

1

21

2

19

21

1

20

89813.780

0.393

26.58372

80.712

83.708

1

9

2

8

8

2

6

89890.700

0.232

26.58372

16.749

19.747

0

21

2

19

21

1

20

89939.201

0.431

26.58633

80.694

83.694

1

17

1

16

16

2

14

90149.072

0.413

0.00000

50.965

53.972

1

9

3

7

8

3

5

90547.441

0.368

11.77386

22.383

25.403

1

9

2

8

9

1

8

90564.865

0.510

0.00000

16.726

19.747

1

9

0

9

8

0

8

90627.763

0.009

148.93005

12.151

15.174

0

9

0

9

8

0

8

90634.504

0.009

148.93005

12.123

15.146

1

10

2

8

10

1

9

90952.923

0.451

10.12940

20.184

23.218

0

10

2

8

10

1

9

91076.843

0.510

10.25472

20.160

23.198

0

9

2

8

8

2

7

91191.998

0.007

141.70609

16.687

19.729

1

9

2

8

8

2

7

91216.317

0.045

140.66913

16.704

19.747

1

9

5

4

8

5

3

91351.606

0.007

103.07178

40.446

43.493

0

9

5

5

8

5

4

91353.090

0.008

103.07178

40.442

43.489

0

9

5

4

8

5

3

91353.091

0.008

103.07178

40.442

43.489

1

9

4

5

8

4

4

91353.947

0.009

119.63668

30.289

33.336

0

9

6

3

8

6

2

91358.583

0.007

82.82616

52.854

55.901

0

9

6

4

8

6

3

91358.583

0.007

82.82616

52.854

55.901

0

9

4

6

8

4

5

91358.730

0.008

119.63668

30.274

33.321

0

9

4

5

8

4

4

91358.904

0.008

119.63668

30.274

33.321

1

9

5

5

8

5

4

91360.256

0.008

103.07178

40.419

43.466

1

9

6

3

8

6

2

91360.644

0.009

82.82616

52.848

55.895


Kolesniková et al.

Page 44


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

9

4

6

8

4

5

1

9

6

4

8

6

0

9

7

2

8

7

0

9

7

3

8

1

9

7

2

8

1

9

7

3

0

9

3

7

1

9

3

0

9

8

0

9

1

9

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

91363.265

0.007

119.63668

30.258

33.306

3

91367.377

0.008

82.82616

52.827

55.875

1

91371.106

0.009

58.89816

67.502

70.550

7

2

91371.106

0.009

58.89816

67.502

70.550

7

1

91376.379

0.010

58.89816

67.488

70.536

8

7

2

91380.199

0.008

58.89816

67.476

70.524

8

3

6

91381.184

0.007

132.51920

22.358

25.406

6

8

3

5

91382.619

0.011

132.50429

22.383

25.431

1

8

8

1

91389.063

0.010

132.50429

84.378

87.426

8

2

8

8

0

91389.063

0.010

132.50429

84.378

87.426

3

7

8

3

6

91390.812

0.007

132.50429

22.355

25.403

9

8

1

8

8

0

91396.753

0.010

31.28944

84.357

87.406

9

8

2

8

8

1

91397.094

0.009

31.28944

84.356

87.405

0

9

3

6

8

3

5

91398.862

0.007

132.51920

22.358

25.407

0

16

1

15

15

2

14

91779.450

0.465

6.93442

45.043

48.104

1

9

2

7

8

2

6

91808.028

0.044

140.67244

16.749

19.811

1

38

3

35

38

3

36

91830.314

0.487

5.45648

260.947

264.010

0

9

2

7

8

2

6

91844.614

0.009

141.70941

16.726

19.790

1

16

1

15

15

2

14

91884.764

0.429

6.93058

45.060

48.125

0

38

3

35

38

3

36

91956.890

0.510

5.45648

260.947

264.014

1

19

1

18

19

1

19

92158.887

0.364

1.89668

63.600

66.674

1

9

3

6

8

3

6

92225.989

0.368

9.94135

22.355

25.431

1

22

2

20

22

1

21

92233.430

0.389

27.53980

88.227

91.304

1

18

1

17

18

0

18

92291.359

0.386

14.31398

57.076

60.155

0

19

1

18

19

1

19

92330.796

0.367

1.89668

63.575

66.655

0

22

2

20

22

1

21

92360.380

0.425

27.54211

88.210

91.291

0

18

1

17

18

0

18

92459.825

0.392

14.31336

57.052

60.136

1

9

2

7

9

1

8

92482.193

0.454

8.65700

16.726

19.811

0

9

2

7

9

1

8

92592.534

0.516

8.89609

16.701

19.790

1

8

2

7

8

1

7

92710.898

0.537

0.00000

13.611

16.704

1

28

2

26

28

2

27

92789.300

0.255

3.66084

141.044

144.139

0

28

2

26

28

2

27

92934.160

0.247

3.66084

141.031

144.131

1

9

2

7

8

2

7

93133.644

0.234

0.00000

16.704

19.811

1

9

1

8

8

1

7

93362.349

0.013

147.21061

13.612

16.726

0

9

1

8

8

1

7

93374.111

0.014

147.21227

13.586

16.701

1

8

2

6

8

1

7

94036.514

0.457

7.16537

13..611

16.748

0

8

2

6

8

1

7

94122.032

0.522

7.62588

13.586

16.726

1

7

2

6

7

1

6

94613.317

0.573

0.00000

10.842

13.998

1

3

2

2

4

0

4

94746.681

0.814

0.05135

3.391

6.551

1

23

2

21

23

1

22

95207.581

0.385

28.31844

96.072

99.248

0

23

2

21

23

1

22

95336.978

0.420

28.32029

96.056

99.236

0

3

2

1

4

0

4

95352.233

0.748

0.00331

3.361

6.542


Kolesniková et al.

Page 45


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

3

2

1

4

0

4

95422.629

1

7

2

5

7

1

6

0

7

2

5

7

1

6

1

6

2

5

6

1

0

6

2

4

6

1

1

6

2

4

6

1

5

2

4

5

1

7

1

7

0

7

1

7

0

5

2

1

5

2

1

10

0

10

1 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.683

0.00166

3.390

6.573

95570.434

0.466

5.60963

10.842

14.030

95615.408

0.528

6.44147

10.817

14.006

5

96268.054

0.609

0.00000

8.418

11.629

5

97026.645

0.534

5.33547

8.393

11.629

1

5

97036.389

0.480

4.08387

8.418

11.655

1

4

97683.697

0.633

0.00000

6.340

9.598

6

0

6

98123.303

0.192

6.48590

7.102

10.375

6

0

6

98184.118

0.196

6.48698

7.074

10.349

3

5

1

4

98314.488

0.538

4.29559

6.314

9.593

3

5

1

4

98379.729

0.492

2.83964

6.339

9.621

1

10

9

1

9

98714.618

0.015

163.95607

15.976

19.269

1

10

9

1

9

98717.379

0.014

163.95772

15.950

19.243

24

2

22

24

1

23

98755.337

0.383

28.91626

104.244

107.538

4

2

3

4

1

3

98871.428

0.646

0.00000

4.607

7.905

0

24

2

22

24

1

23

98888.140

0.415

28.91749

104.228

107.527

1

10

2

9

9

2

7

99387.923

0.159

0.05301

19.811

23.126

0

4

2

2

4

1

3

99443.047

0.542

3.30353

4.581

7.898

1

4

2

2

4

1

3

99548.915

0.498

1.96920

4.606

7.927

0

12

0

12

11

1

11

99803.895

0.170

11.09409

22.863

26.192

1

19

1

18

19

0

19

99825.901

0.403

14.13777

63.344

66.674

1

3

2

2

3

1

2

99831.898

0.657

0.00000

3.221

6.551

1

12

0

12

11

1

11

99834.034

0.167

11.09378

22.889

26.219

0

19

1

18

19

0

19

100007.610

0.409

14.13685

63.319

66.655

1

6

1

5

5

0

5

100121.076

0.223

0.00000

5.078

8.418

1

18

1

17

17

2

15

100194.849

0.407

0.00000

56.813

60.155

0

3

2

1

3

1

2

100382.180

0.546

2.32946

3.194

6.542

1

3

2

1

3

1

2

100507.846

0.500

1.35063

3.220

6.573

1

10

0

10

9

0

9

100532.055

0.010

165.44360

15.174

18.527

0

10

0

10

9

0

9

100539.193

0.010

165.44360

15.146

18.500

1

2

2

1

2

1

1

100554.527

0.679

0.00000

2.181

5.535

1

10

3

8

9

3

6

100728.969

0.365

0.00000

25.431

28.791

0

2

2

0

2

1

1

101107.695

0.549

1.30988

2.153

5.526

1

20

1

19

20

1

20

101193.589

0.383

1.84367

70.152

73.527

1

2

2

0

2

1

1

101232.142

0.498

0.81477

2.181

5.558

0

10

2

9

9

2

8

101292.716

0.007

159.00151

19.729

23.108

1

10

2

9

9

2

8

101305.251

0.031

158.51284

19.747

23.126

0

20

1

19

20

1

20

101381.510

0.386

1.84367

70.126

73.508

1

10

5

5

9

5

4

101506.453

0.008

124.23841

43.493

46.879

0

10

5

6

9

5

5

101508.138

0.008

124.23841

43.489

46.875

0

10

5

5

9

5

4

101508.141

0.008

124.23841

43.489

46.875

0

10

6

5

9

6

4

101511.945

0.008

106.01702

55.901

59.287


Kolesniková et al.

Page 46


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

10

6

4

9

6

3

1

10

4

6

9

4

1

10

6

4

9

6

1

10

5

6

9

0

10

4

7

9

0

10

4

6

1

10

6

5

1

10

4

0

10

7

0

10

1

10

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

101511.945

0.008

106.01702

55.901

59.287

5

101513.435

0.009

139.14682

33.336

36.722

3

101514.198

0.009

106.01702

55.895

59.281

5

5

101516.069

0.009

124.23841

43.466

46.852

4

6

101518.705

0.008

139.14682

33.321

36.707

9

4

5

101519.083

0.008

139.14682

33.321

36.707

9

6

4

101521.687

0.009

106.01702

55.875

59.261

7

9

4

6

101523.803

0.008

139.14682

33.307

36.693

3

9

7

2

101524.501

0.009

84.48265

70.551

73.937

7

4

9

7

3

101524.501

0.009

84.48265

70.551

73.937

7

3

9

7

2

101530.319

0.011

84.48265

70.535

73.922

10

7

4

9

7

3

101534.581

0.008

84.48265

70.524

73.911

10

8

2

9

8

1

101543.579

0.011

59.63364

87.426

90.813

0

10

8

3

9

8

2

101543.579

0.011

59.63364

87.426

90.813

0

10

3

8

9

3

7

101548.787

0.008

150.73893

25.407

28.794

1

10

8

2

9

8

1

101552.082

0.011

59.63364

87.407

90.794

1

10

8

3

9

8

2

101552.488

0.009

59.63364

87.406

90.793

1

10

3

7

9

3

6

101556.208

0.011

150.68758

25.431

28.819

1

10

3

8

9

3

7

101564.147

0.008

150.68758

25.403

28.791

0

10

9

1

9

9

1

101568.116

0.011

150.68758

106.519

109.907

0

10

9

2

9

9

0

101568.116

0.011

150.68758

106.519

109.907

1

10

9

1

9

9

0

101574.538

0.011

31.47331

106.506

109.894

1

39

3

36

39

3

37

101575..317

0.561

5.24942

274.087

277.475

1

10

9

2

9

9

1

101578.034

0.010

31.47331

106.497

109.885

0

10

3

7

9

3

6

101579.029

0.008

150.73893

25.408

28.796

0

39

3

36

39

3

37

101713.033

0.581

5.24776

274.087

277.480

1

2

2

1

2

1

2

102101.203

0.605

0.80094

2.129

5.535

1

10

2

8

9

2

7

102154.452

0.031

158.52112

19.810

23.218

0

10

2

8

9

2

7

102180.842

0.010

159.00813

19.790

23.198

1

29

2

27

29

2

28

102215.633

0.268

3.53495

150.732

154.142

0

29

2

27

29

2

28

102373.588

0.261

3.53329

150.720

154.135

1

10

3

7

9

3

7

102391.386

0.365

3.53329

25.404

28.819

0

2

2

1

2

1

2

102606.866

0.554

1.28128

2.103

5.526

1

2

2

0

2

1

2

102778.818

0.533

0.00000

2.130

5.558

1

3

2

2

3

1

3

102857.901

0.624

1.29927

3.120

6.551

1

25

2

23

25

1

24

102891.483

0.381

29.33602

112.742

116.174

0

25

2

23

25

1

24

103028.674

0.411

29.33649

112.726

116.163

0

3

2

2

3

1

3

103363.707

0.556

2.22998

3.093

6.541

1

3

2

1

3

1

3

103533.848

0.525

0.00000

3.119

6.573

1

10

1

9

9

1

8

103683.722

0.014

163.94613

16.725

20.184

0

10

1

9

9

1

8

103696.532

0.015

163.94778

16.701

20.160

1

4

2

3

4

1

4

103890.179

0.633

1.84081

4.440

7.905


Kolesniková et al.

Page 47


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

10

2

8

9

2

8

104071.780

0

4

2

3

4

1

4

1

4

2

2

4

1

4

1

5

2

4

5

1

0

17

1

16

16

2

1

17

1

16

16

2

0

5

2

4

5

1

1

5

2

3

5

1

8

1

8

7

0

8

1

8

1

6

2

5

0

6

2

1

6

2

1

26

0

26

1 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.162

1.84081

19.747

23.218

104374.810

0.559

3.07382

4.413

7.895

104567.666

0.522

0.00000

4.439

7.927

5

105199.382

0.634

2.56210

6.089

9.598

15

105417.695

0.456

7.72429

50.436

53.952

15

105511.795

0.420

7.72183

50.453

53.972

5

105641.756

0.562

3.86061

6.062

9.586

1

5

105895.414

0.521

0.00000

6.089

9.621

0

7

106467.494

0.187

7.44506

9.460

13.011

7

0

7

106524.605

0.191

7.44583

9.432

12.985

6

1

6

106781.327

0.623

3.53556

8.067

11.629

5

6

1

6

107166.382

0.567

4.60496

8.041

11.616

4

6

1

6

107549.661

0.516

0.00000

8.068

11.655

2

24

26

1

25

107625.592

0.380

29.58665

121.563

125.153

2

24

26

1

25

107768.155

0.407

29.58635

121.549

125.144

20

1

19

20

0

20

107782.433

0.420

13.94542

69.932

73.527

20

1

19

20

0

20

107978.026

0.425

13.94449

69.906

73.508

1

11

1

11

10

1

10

108538.039

0.016

180.66177

19.269

22.889

0

11

1

11

10

1

10

108541.109

0.015

180.66177

19.242

22.863

1

11

2

10

10

2

8

108621.966

0.112

0.00000

23.218

26.841

1

7

2

6

7

1

7

108622.289

0.601

4.63586

10.375

13.998

0

7

2

6

7

1

7

108950.689

0.572

5.31225

10.349

13.983

1

7

2

5

7

1

7

109579.406

0.511

0.00000

10.375

14.030

1

19

1

18

18

2

16

109789.513

0.400

0.00000

63.012

66.674

1

11

0

11

10

0

10

110390.799

0.011

181.94886

18.527

22.209

0

11

0

11

10

0

10

110398.237

0.012

181.94886

18.500

22.182

1

21

1

20

21

1

21

110484.938

0.402

1.80060

77.027

80.712

0

21

1

20

21

1

21

110689.085

0.405

1.80060

77.002

80.694

1

8

2

7

8

1

8

110710.845

0.579

5.62992

13.011

16.704

1

11

3

9

10

3

7

110915.291

0.361

12.96089

28.818

32.518

0

8

2

7

8

1

8

110996.735

0.578

5.98342

12.985

16.687

0

11

2

10

10

2

9

111383.496

0.008

176.16109

23.108

26.823

1

11

2

10

10

2

9

111388.495

0.021

175.93912

23.125

26.841

0

13

0

13

12

1

12

111431.477

0.162

12.46625

26.811

30.528

1

13

0

13

12

1

12

111457.213

0.159

12.46594

26.836

30.554

1

11

5

6

10

5

5

111662.768

0.008

144.56851

46.878

50.603

0

11

5

7

10

5

6

111664.666

0.008

144.56851

46.874

50.599

0

11

5

6

10

5

5

111664.672

0.008

144.56851

46.874

50.599

0

11

6

5

10

6

4

111666.064

0.008

128.00361

59.287

63.012

0

11

6

6

10

6

5

111666.064

0.008

128.00361

59.287

63.012

1

11

6

5

10

6

4

111668.497

0.010

128.00361

59.281

63.006

1

11

5

7

10

5

6

111673.350

0.009

144.56851

46.852

50.577


Kolesniková et al.

Page 48


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

11

4

7

10

4

6

1

11

6

6

10

6

0

11

7

5

10

7

0

11

7

4

10

0

11

4

8

10

0

11

4

7

1

11

7

4

1

11

4

1

11

7

0

11

0

11

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

111675.779

0.010

158.12025

36.722

40.447

5

111676.742

0.009

128.00361

59.261

62.986

4

111678.224

0.010

108.42555

73.937

77.662

7

3

111678.224

0.010

108.42555

73.937

77.662

4

7

111681.463

0.009

158.12025

36.708

40.433

10

4

6

111682.217

0.009

158.12025

36.708

40.433

10

7

3

111684.576

0.011

108.42555

73.923

77.648

8

10

4

7

111687.200

0.008

158.12025

36.693

40.418

5

10

7

4

111689.283

0.009

108.42555

73.911

77.637

8

4

10

8

3

111698.149

0.011

85.83766

90.813

94.539

8

3

10

8

2

111698.149

0.011

85.83766

90.813

94.539

11

8

3

10

8

2

111707.450

0.011

85.83766

90.794

94.520

11

8

4

10

8

3

111707.932

0.010

85.83766

90.793

94.519

0

11

3

9

10

3

8

111719.482

0.008

168.65884

28.793

32.520

0

11

9

2

10

9

2

111724.414

0.011

168.65884

109.906

113.633

0

11

9

3

10

9

1

111724.414

0.011

168.65884

109.906

113.633

1

11

9

2

10

9

1

111731.474

0.012

60.23660

109.893

113.620

1

11

9

3

10

9

2

111735.272

0.011

60.23660

109.885

113.612

1

11

3

8

10

3

7

111737.100

0.012

168.50479

28.819

32.546

1

11

3

9

10

3

8

111742.530

0.009

168.50479

28.791

32.518

1

40

3

37

40

3

38

111753.716

0.648

5.06555

287.554

291.282

0

11

10

1

10

10

0

111756.165

0.011

31.62405

131.206

134.934

0

11

10

2

10

10

1

111756.165

0.011

31.62405

131.206

134.934

1

11

10

1

10

10

0

111759.476

0.012

31.62405

131.201

134.929

1

11

10

2

10

10

1

111766.957

0.011

31.62405

131.186

134.914

0

11

3

8

10

3

7

111768.491

0.008

168.65884

28.796

32.524

0

40

3

37

40

3

38

111902.416

0.665

5.06389

287.555

291.288

1

30

2

28

30

2

29

111992.674

0.284

3.42562

160.747

164.483

1

8

2

6

8

1

8

112036.461

0.514

0.00000

13.011

16.748

0

30

2

28

30

2

29

112163.754

0.277

3.42562

160.736

164.477

1

11

2

9

10

2

8

112531.273

0.021

175.95237

23.218

26.972

0

11

2

9

10

2

8

112551.773

0.012

176.17434

23.198

26.952

1

11

3

8

10

3

8

112564.339

0.361

176.17434

28.791

32.546

1

27

2

25

27

1

26

112961.055

0.380

29.68291

130.707

134.475

1

9

2

8

9

1

9

113047.349

0.567

6.44670

15.976

19.747

0

27

2

25

27

1

26

113109.953

0.404

29.68183

130.694

134.467

0

9

2

8

9

1

9

113306.520

0.585

6.61875

15.950

19.729

1

11

1

10

10

1

9

113987.068

0.014

180.64520

20.184

23.986

0

11

1

10

10

1

9

114000.920

0.016

180.64520

20.160

23.963

1

9

1

9

8

0

8

114667.807

0.182

8.46111

12.151

15.976

0

9

1

9

8

0

8

114721.070

0.186

8.46157

12.123

15.950

1

9

2

7

9

1

9

114964.677

0.524

0.00000

15.976

19.811


Kolesniková et al.

Page 49


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

11

2

9

10

2

9

115297.802

1

10

2

9

10

1

10

0

10

2

9

10

1

10

1

21

1

20

21

0

0

21

1

20

21

0

1

12

2

11

11

1

12

1

12

11

0

12

1

12

1

10

2

8

1

11

2

0

11

2

1

28

0

28

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.116

0.26504

23.126

26.972

115637.982

0.563

7.13354

19.269

23.126

115881.856

0.592

7.21765

19.243

23.108

21

116119.178

0.436

13.75060

76.839

80.712

21

116329.180

0.441

13.74953

76.814

80.694

2

9

117554.314

0.085

1.33371

26.972

30.893

1

11

118349.573

0.016

197.33931

22.889

26.837

11

1

11

118352.914

0.016

197.33931

22.863

26.811

10

1

10

118404.511

0.537

0.00000

19.268

23.218

10

11

1

11

118488.439

0.564

7.73674

22.889

26.841

10

11

1

11

118724.243

0.599

7.77918

22.863

26.823

2

26

28

1

27

118894.165

0.381

29.64401

140.173

144.139

2

26

28

1

27

119050.315

0.402

29.64201

140.160

144.131

18

1

17

17

2

16

119141.452

0.448

8.57412

56.162

60.136

18

1

17

17

2

16

119224.708

0.410

8.57258

56.178

60.155

1

22

1

21

22

1

22

119993.009

0.419

1.76582

84.224

88.227

1

12

0

12

11

0

11

120203.882

0.013

198.44916

22.209

26.219

0

12

0

12

11

0

11

120211.521

0.013

198.44916

22.182

26.192

0

22

1

21

22

1

22

120213.492

0.423

1.76582

84.201

88.211

1

12

3

10

11

3

8

121103.301

0.354

12.62047

32.545

36.585

1

2

2

1

1

1

0

121303.226

0.745

0.47635

1.489

5.535

0

12

2

11

11

2

10

121463.397

0.008

193.21796

26.823

30.875

1

12

2

11

11

2

10

121463.621

0.015

193.11360

26.841

30.893

1

12

2

11

12

1

12

121602.487

0.568

8.28074

26.837

30.893

1

12

5

7

11

5

6

121820.696

0.009

164.27080

50.603

54.667

0

12

6

6

11

6

5

121821.012

0.008

149.08576

63.012

67.076

0

12

6

7

11

6

6

121821.012

0.008

149.08576

63.012

67.076

0

12

5

8

11

5

7

121822.818

0.009

164.27080

50.599

54.663

0

12

5

7

11

5

6

121822.832

0.009

164.27080

50.599

54.663

1

12

6

6

11

6

5

121823.612

0.010

149.08576

63.006

67.070

1

12

5

8

11

5

7

121832.246

0.010

164.27080

50.577

54.641

0

12

7

5

11

7

4

121832.307

0.010

131.14100

77.662

81.726

0

12

7

6

11

7

5

121832.307

0.010

131.14100

77.662

81.726

1

12

6

7

11

6

6

121832.617

0.010

149.08576

62.986

67.050

0

12

2

11

12

1

12

121834.725

0.608

8.30289

26.811

30.875

1

12

7

5

11

7

4

121839.178

0.012

131.14100

77.648

81.712

1

12

4

8

11

4

7

121841.265

0.010

176.69282

40.447

44.511

1

12

7

6

11

7

5

121844.337

0.009

131.14100

77.637

81.701

0

12

4

9

11

4

8

121847.237

0.009

176.69282

40.433

44.497

0

12

4

8

11

4

7

121848.649

0.009

176.69282

40.433

44.497

0

12

8

4

11

8

4

121852.776

0.012

176.69282

94.538

98.603

0

12

8

5

11

8

3

121852.776

0.012

176.69282

94.538

98.603


Kolesniková et al.

Page 50


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

12

4

9

11

4

8

1

12

8

4

11

8

1

12

8

5

11

8

0

12

9

3

11

0

12

9

4

11

1

12

9

3

0

2

2

1

1

12

9

0

12

3

0

12

10

0

12

10

1

12

1

12

u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

121853.740

0.009

176.69282

40.418

44.483

3

121862.862

0.012

110.43488

94.520

98.585

4

121863.427

0.010

110.43488

94.519

98.584

9

2

121880.562

0.012

86.96738

113.634

117.699

9

3

121880.562

0.012

86.96738

113.634

117.699

11

9

2

121888.258

0.012

86.96738

113.620

117.686

1

1

0

121892.144

0.550

2.30640

1.460

5.526

4

11

9

3

121892.346

0.011

86.96738

113.612

117.678

10

11

3

9

121892.934

0.008

186.35181

32.520

36.586

3

11

10

1

121914.578

0.011

186.35181

134.934

139.001

2

11

10

2

121914.578

0.011

186.35181

134.934

139.001

10

2

11

10

1

121918.201

0.013

60.73852

134.928

138.995

3

10

11

3

9

121925.109

0.010

185.94597

32.518

36.585


1

2

2

1

1

1

1

121926.104

0.554

0.00000

1.468

5.535

1

12

10

3

11

10

2

121926.295

0.012

60.73852

134.914

138.981

1

12

3

9

11

3

8

121927.470

0.013

185.94597

32.546

36.613

1

12

11

1

11

11

0

121953.068

0.013

31.74994

158.429

162.497

0

12

11

2

11

11

0

121954.027

0.013

31.74994

158.429

162.497

0

12

11

1

11

11

1

121954.027

0.013

31.74994

158.429

162.497

1

12

11

2

11

11

1

121963.919

0.013

31.74994

158.413

162.481

0

12

3

9

11

3

8

121968.907

0.009

186.35181

32.524

36.592

1

2

2

0

1

1

0

121980.841

0.494

0.00000

1.489

5.558

1

31

2

29

31

2

30

122086.498

0.302

3.33286

171.088

175.160

0

31

2

29

31

2

30

122270.622

0.296

3.33120

171.076

175.155

1

41

3

38

41

3

39

122333.772

0.751

4.90155

301.350

305.431

1

11

2

9

11

1

11

122397.746

0.551

0.00000

22.889

26.972

0

2

2

0

1

1

1

122399.288

0.552

2.28933

1.443

5.526

0

41

3

38

41

3

39

122493.173

0.765

4.89990

301.352

305.438

1

2

2

0

1

1

1

122603.719

0.569

0.46943

1.468

5.558

1

12

3

9

11

3

9

122749.278

0.355

0.77126

32.519

36.613

1

10

1

10

9

0

9

122754.662

0.177

9.53835

15.174

19.269

0

10

1

10

9

0

9

122803.945

0.180

9.53881

15.147

19.243

1

12

2

10

11

2

9

122938.964

0.017

193.13845

26.971

31.072

0

12

2

10

11

2

9

122956.393

0.013

193.24115

26.953

31.054

0

14

0

14

13

1

13

122987.154

0.154

13.89514

31.086

35.188

1

14

0

14

13

1

13

123008.707

0.152

13.89483

31.111

35.214

1

12

1

11

11

1

10

124269.883

0.015

197.31446

23.987

28.132

0

12

1

11

11

1

10

124284.750

0.016

197.31446

23.962

28.108

1

22

1

21

22

0

22

124789.274

0.451

13.56363

84.064

88.227

1

13

2

12

13

1

13

124982.199

0.575

8.77662

31.111

35.280

0

22

1

21

22

0

22

125014.081

0.456

13.56240

84.041

88.211

0

13

2

12

13

1

13

125213.770

0.616

8.78877

31.085

35.262


Kolesniková et al.

Page 51


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

29

2

27

29

1

28

0

29

2

27

29

1

1

13

2

12

12

2

1

12

2

10

11

1

12

2

10

12

1

13

1

13

0

13

1

13

1

14

2

0

14

2

1

31

1

23

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

125413.405

0.384

29.49255

149.959

154.142

28

125577.649

0.402

29.48978

149.946

154.135

10

126143.941

0.073

0.25013

31.072

35.280

2

10

126848.271

0.092

0.05301

26.841

31.072

1

12

126987.137

0.566

0.00000

26.836

31.072

12

1

12

128148.879

0.017

213.99697

26.836

31.111

12

1

12

128152.458

0.017

213.99697

26.811

31.086

13

14

1

14

128628.276

0.582

9.22975

35.712

40.003

13

14

1

14

128861.135

0.625

9.23667

35.687

39.985

3

28

31

2

29

129527.145

0.984

37.87017

175.160

179.481

1

22

23

1

23

129676.138

0.435

1.73931

91.746

96.072

32

3

29

32

2

30

129903.083

0.964

39.41668

186.173

190.506

23

1

22

23

1

23

129912.957

0.439

1.73931

91.723

96.056

1

13

0

13

12

0

12

129972.752

0.014

214.94614

26.219

30.554

0

13

0

13

12

0

12

129980.496

0.014

214.94614

26.192

30.528

1

11

1

11

10

0

10

130760.647

0.172

10.68017

18.527

22.889

0

11

1

11

10

0

10

130805.862

0.175

10.68048

18.500

22.863

1

33

3

30

33

2

31

130852.599

0.944

40.80806

197.517

201.882

1

3

2

2

2

1

1

130998.089

0.679

1.02927

2.181

6.551

1

13

3

11

12

3

9

131285.534

0.342

0.00000

36.613

40.992

1

13

2

12

12

2

11

131528.591

0.012

210.14563

30.893

35.280

0

13

2

12

12

2

11

131531.502

0.008

210.19699

30.875

35.262

0

3

2

2

2

1

1

131535.671

0.549

2.56272

2.153

6.541

1

3

2

1

2

1

1

131674.037

0.498

0.00000

2.181

6.573

0

13

6

8

12

6

7

131976.864

0.009

169.47384

67.076

71.478

0

13

6

7

12

6

6

131976.864

0.009

169.47384

67.076

71.478

1

13

6

7

12

6

6

131979.617

0.011

169.47384

67.070

71.472

1

13

5

8

12

5

7

131980.383

0.009

183.48940

54.667

59.069

0

13

5

9

12

5

8

131982.739

0.009

183.48940

54.663

59.065

0

13

5

8

12

5

7

131982.766

0.009

183.48940

54.663

59.065

0

13

7

6

12

7

5

131986.781

0.011

152.90894

81.725

86.128

0

13

7

7

12

7

6

131986.781

0.011

152.90894

81.725

86.128

1

13

6

8

12

6

7

131989.383

0.010

169.47384

67.050

71.453

1

13

5

9

12

5

8

131992.900

0.010

183.48940

54.641

59.044

1

13

7

6

12

7

5

131994.156

0.012

152.90894

81.712

86.115

1

13

7

7

12

7

6

131999.771

0.010

152.90894

81.701

86.104

0

13

8

5

12

8

5

132007.465

0.012

152.90894

98.604

103.007

0

13

8

6

12

8

4

132007.465

0.012

152.90894

98.604

103.007

1

13

4

9

12

4

8

132010.184

0.011

194.95562

44.512

48.915

0

13

4

10

12

4

9

132016.241

0.009

194.95728

44.497

48.901

1

13

8

5

12

8

4

132018.319

0.012

133.79470

98.584

102.988

0

13

4

9

12

4

8

132018.745

0.009

194.95728

44.497

48.901


Kolesniková et al.

Page 52


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

13

8

6

12

8

5

1

13

4

10

12

4

0

13

9

4

12

9

0

13

9

5

12

1

13

9

4

12

1

13

9

5

12

0

13

3

11

12

0

13

10

4

0

13

10

3

1

13

10

1

13

10

1

13

1

13

0

13

0

13

1

13

1

13

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

132018.977

0.011

133.79470

98.583

102.987

9

132023.710

0.009

194.95562

44.483

48.887

4

132036.547

0.012

194.95562

117.699

122.103

9

3

132036.547

0.012

194.95562

117.699

122.103

9

3

132044.877

0.013

112.13278

117.686

122.091

9

4

132049.241

0.011

112.13278

117.678

122.083

3

10

132068.660

0.009

203.87085

36.586

40.991

12

10

2

132072.665

0.012

203.87085

139.001

143.406

12

10

3

132072.665

0.012

203.87085

139.001

143.406

3

12

10

2

132076.603

0.013

87.92318

138.995

143.401

4

12

10

3

132085.295

0.012

87.92318

138.981

143.387

3

11

12

3

10

132109.703

0.012

202.95150

36.585

40.992

11

2

12

11

1

132113.848

0.014

61.16424

162.497

166.904

11

2

12

11

1

132114.854

0.014

61.16424

162.496

166.903

11

3

12

11

2

132114.854

0.014

61.16424

162.496

166.903

11

3

12

11

2

132125.523

0.014

61.16424

162.481

166.888

3

10

12

3

9

132130.858

0.015

202.95150

36.613

41.020

13

12

1

12

12

0

132156.535

0.018

31.85596

188.177

192.585

13

12

2

12

12

0

132162.311

0.017

31.85596

188.173

192.581

0

13

12

1

12

12

1

132162.311

0.017

31.85596

188.173

192.581

1

13

12

2

12

12

1

132169.407

0.016

31.85596

188.162

192.571

0

13

3

10

12

3

9

132182.127

0.009

203.87085

36.593

41.002

1

13

2

11

13

1

13

132214.307

0.581

0.00000

31.111

35.521

1

34

3

31

34

2

32

132405.647

0.925

42.02199

209.193

213.610

1

32

2

30

32

2

31

132460.457

0.324

3.25500

181.755

186.173

1

30

2

28

30

1

29

132499.038

0.389

29.25284

160.063

164.483

1

15

2

14

15

1

15

132540.220

0.590

9.64290

40.639

45.060

1

3

2

2

2

1

2

132544.766

0.604

0.00000

2.130

6.551

0

32

2

30

32

2

31

132657.427

0.319

3.25335

181.744

186.169

0

30

2

28

30

1

29

132672.115

0.405

29.24930

160.052

164.477

0

15

2

14

15

1

15

132775.762

0.634

9.64721

40.614

45.043

0

19

1

18

18

2

17

132924.279

0.438

9.48822

62.221

66.655

1

13

3

10

12

3

10

132955.027

0.343

0.62058

36.585

41.020

1

19

1

18

18

2

17

132997.002

0.400

9.48730

62.238

66.674

0

3

2

1

2

1

2

133068.166

0.554

2.50567

2.103

6.542

1

3

2

1

2

1

2

133220.713

0.532

1.00052

2.129

6.573

1

42

3

39

42

3

40

133281.149

0.873

4.75910

315.474

319.920

1

13

2

11

12

2

10

133376.049

0.015

210.18373

31.072

35.521

0

13

2

11

12

2

10

133392.095

0.014

210.23508

31.054

35.503

0

42

3

39

42

3

40

133450.838

0.883

4.75744

315.476

319.927

1

23

1

22

23

0

23

133742.417

0.465

13.39173

91.611

96.072

0

23

1

22

23

0

23

133982.294

0.470

13.39050

91.587

96.056


Kolesniková et al.

Page 53


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

14

2

13

13

2

11

134349.740

0

15

0

15

14

1

14

1

15

0

15

14

1

14

1

13

1

12

12

1

0

13

1

12

12

1

1

35

3

32

35

0

35

3

32

35

1

2

2

1

1

3

2

2

1

4

2

1

5

2

1

6

0

2

0 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.072

1.31834

35.522

40.003

134446.313

0.146

15.37277

35.686

40.171

134463.954

0.143

15.37262

35.713

40.198

11

134529.474

0.015

213.96053

28.132

32.619

11

134545.313

0.016

213.96053

28.108

32.596

2

33

134587.406

0.907

43.04142

221.199

225.688

2

33

134671.446

0.989

43.04542

221.197

225.689

2

0

2

135227.064

0.814

0.00166

1.024

5.535

3

0

3

135263.417

0.814

0.00331

2.039

6.551

3

4

0

4

135344.435

0.813

0.00994

3.390

7.905

4

5

0

5

135492.563

0.807

0.02153

5.078

9.598

2

5

6

0

6

135725.750

0.792

0.04473

7.102

11.629

2

1

2

0

2

135821.046

0.749

0.00166

0.995

5.526

3

2

2

3

0

3

135844.701

0.749

0.00828

2.010

6.541

4

2

3

4

0

4

135897.805

0.748

0.01822

3.362

7.895

1

2

2

0

2

0

2

135904.679

0.684

0.01822

1.025

5.558

1

3

2

1

3

0

3

135939.365

0.683

0.00000

2.039

6.573

0

5

2

4

5

0

5

135998.730

0.748

0.03479

5.050

9.586

1

4

2

2

4

0

4

136021.922

0.682

0.03479

3.390

7.927

1

7

2

6

7

0

7

136055.497

0.767

0.07786

9.460

13.998

0

6

2

5

6

0

6

136170.210

0.747

0.05798

7.074

11.616

1

5

2

3

5

0

5

136188.595

0.679

0.05798

5.078

9.621

0

7

2

6

7

0

7

136439.040

0.746

0.08945

9.432

13.983

1

6

2

4

6

0

6

136494.085

0.675

0.08945

7.102

11.655

1

8

2

7

8

0

8

136498.840

0.741

0.12258

12.151

16.704

1

16

2

15

16

1

16

136716.402

0.599

10.01839

45.892

50.452

0

8

2

7

8

0

8

136835.591

0.746

0.13086

12.123

16.687

0

16

2

15

16

1

16

136955.679

0.643

10.02115

45.867

50.435

1

7

2

5

7

0

7

137012.613

0.670

10.02115

9.460

14.030

1

9

2

8

9

0

9

137087.394

0.723

0.17724

15.174

19.747

0

9

2

8

9

0

9

137393.086

0.745

0.18221

15.146

19.729

1

36

3

33

36

2

34

137418.228

0.891

43.85635

233.531

238.115

0

36

3

33

36

2

34

137503.534

0.968

43.85896

233.530

238.117

1

8

2

6

8

0

8

137824.456

0.671

0.00000

12.151

16.748

1

10

2

9

10

0

10

133281.149

0.712

0.24019

18.527

23.126

1

14

1

14

13

1

13

137935.772

0.017

230.63642

31.111

35.712

0

14

1

14

13

1

13

137939.561

0.017

230.63807

31.086

35.687

1

14

2

12

14

1

14

138117.589

0.598

0.00000

35.712

40.319

0

10

2

9

10

0

10

138146.609

0.744

0.24185

18.500

23.108

1

12

1

12

11

0

11

138719.420

0.166

11.88734

22.210

26.837

0

12

1

12

11

0

11

138760.539

0.168

11.88765

22.182

26.811

1

13

2

11

12

2

11

138760.699

0.082

11.88765

30.892

35.521


Kolesniková et al.

Page 54


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

11

2

10

11

0

11

138858.286

1

9

2

7

9

0

9

0

11

2

10

11

0

11

1

24

1

23

24

1

1

14

0

14

13

0

0

14

0

14

13

0

24

1

23

24

1

12

2

11

1

31

2

29

0

31

2

0

12

2

1

4

2

1

10

2

1

37

0

4

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.705

0.31142

22.209

26.841

139004.721

0.676

0.31142

15.174

19.811

139131.868

0.744

0.31308

22.182

26.823

24

139491.913

0.450

1.71944

99.591

104.244

13

139700.373

0.016

231.44313

30.554

35.214

0

13

139708.135

0.015

231.44313

30.528

35.188

1

24

139744.962

0.455

1.71944

99.567

104.228

12

0

12

140118.025

0.701

0.39093

26.219

30.893

31

1

30

140123.080

0.397

28.94963

170.486

175.160

29

31

1

30

140305.603

0.410

28.94517

170.475

175.155

11

12

0

12

140383.744

0.743

0.39093

26.192

30.875

3

3

1

2

140429.653

0.656

1.44919

3.221

7.905

8

10

0

10

140627.119

0.682

0.09608

18.527

23.218

3

34

37

2

35

140913.399

0.880

44.46370

246.189

250.889

2

3

3

1

2

140927.751

0.546

2.88838

3.194

7.895

37

3

34

37

2

35

141001.179

0.950

44.46432

246.189

250.892

4

2

2

3

1

2

141107.139

0.499

0.00000

3.220

7.927

1

17

2

16

17

1

17

141154.076

0.608

10.35773

51.470

56.178

1

14

4

11

13

4

9

141353.698

0.322

1.23223

48.915

53.630

0

17

2

16

17

1

17

141397.921

0.652

10.35958

51.444

56.161

1

14

3

12

13

3

10

141447.330

0.320

12.82774

41.020

45.738

1

14

2

13

13

2

12

141581.849

0.010

227.08656

35.280

40.003

0

14

2

13

13

2

12

141586.926

0.008

227.11306

35.262

39.985

1

13

2

12

13

0

13

141673.865

0.698

0.47707

30.554

35.280

0

13

2

12

13

0

13

141934.750

0.743

0.47707

30.528

35.262

1

15

2

14

14

2

12

142132.849

0.079

23.51067

40.319

45.060

0

14

6

9

13

6

8

142133.691

0.009

189.31527

71.478

76.219

0

14

6

8

13

6

7

142133.691

0.009

189.31527

71.478

76.219

1

14

6

8

13

6

7

142136.582

0.011

189.31527

71.472

76.213

0

14

7

8

13

7

7

142141.675

0.011

173.93311

86.129

90.870

0

14

7

7

13

7

6

142141.675

0.011

173.93311

86.129

90.870

1

14

5

9

13

5

8

142141.972

0.009

202.33031

59.070

63.811

0

14

5

10

13

5

9

142144.570

0.009

202.33031

59.066

63.807

0

14

5

9

13

5

8

142144.625

0.009

202.33031

59.066

63.807

1

14

6

9

13

6

8

142147.111

0.010

189.31527

71.452

76.194

1

14

7

7

13

7

6

142149.539

0.013

173.93311

86.114

90.856

1

14

5

10

13

5

9

142155.456

0.010

202.33031

59.043

63.785

1

14

7

8

13

7

7

142155.616

0.010

173.93311

86.104

90.846

0

14

8

6

13

8

5

142162.218

0.013

156.18547

103.007

107.749

0

14

8

7

13

8

6

142162.218

0.013

156.18547

103.007

107.749

1

14

8

6

13

8

5

142173.823

0.013

156.18547

102.989

107.731

1

14

8

7

13

8

6

142174.586

0.011

156.18547

102.988

107.730


Kolesniková et al.

Page 55


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

14

4

10

13

4

9

0

14

4

11

13

4

0

14

9

5

13

9

0

14

9

6

13

0

14

4

10

13

1

14

4

11

1

14

9

5

1

14

9

6

0

14

10

5

0

14

10

1

14

10

1

14

0

14

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

142182.834

0.011

212.97658

48.914

53.657

10

142188.661

0.009

212.97823

48.900

53.643

4

142192.353

0.012

136.07071

122.103

126.846

9

5

142192.353

0.012

136.07071

122.103

126.846

4

9

142192.907

0.009

212.97823

48.901

53.644

13

4

10

142197.396

0.009

212.97658

48.887

53.630

13

9

4

142201.316

0.013

136.07071

122.091

126.834

13

9

5

142205.940

0.012

136.07071

122.083

126.826

13

10

3

142230.399

0.012

136.07071

143.406

148.150

4

13

10

4

142230.399

0.012

136.07071

143.406

148.150

4

13

10

3

142234.654

0.014

113.58883

143.401

148.145

10

5

13

10

4

142243.925

0.012

113.58883

143.387

148.132

3

12

13

3

11

142246.024

0.009

221.25240

40.991

45.736

14

11

3

13

11

2

142274.152

0.014

88.74148

166.904

171.650

14

11

3

13

11

3

142275.197

0.014

88.74148

166.903

171.649

0

14

11

4

13

11

2

142275.197

0.014

88.74148

166.903

171.649

1

14

11

4

13

11

3

142286.631

0.014

88.74148

166.888

171.634

1

14

3

12

13

3

11

142292.654

0.017

219.55118

40.992

45.738

1

14

12

2

13

12

1

142319.653

0.019

61.52701

192.585

197.332

0

14

12

2

13

12

1

142325.814

0.017

61.52701

192.581

197.328

0

14

12

3

13

12

2

142325.814

0.017

61.52701

192.581

197.328

1

14

12

3

13

12

2

142333.429

0.017

61.52701

192.570

197.318

1

14

3

11

13

3

10

142352.319

0.019

219.55118

41.021

45.769

1

14

13

1

13

13

0

142371.076

0.028

31.94707

220.428

225.177

0

14

13

2

13

13

0

142381.424

0.022

31.94707

220.423

225.172

0

14

13

1

13

13

1

142381.424

0.022

31.94707

220.423

225.172

1

14

13

2

13

13

1

142384.063

0.024

31.94707

220.419

225.168

0

14

3

11

13

3

10

142410.186

0.009

221.25240

41.002

45.752

1

11

2

9

11

0

11

142767.593

0.687

0.00000

22.210

26.972

1

24

1

23

24

0

24

142926.598

0.478

13.23920

99.476

104.244

1

14

4

10

13

4

10

143026.533

0.323

13.23920

48.886

53.657

1

33

2

31

33

2

32

143075.421

0.351

3.19040

192.746

197.518

0

24

1

23

24

0

24

143181.671

0.483

13.23797

99.452

104.228

1

14

3

11

13

3

11

143197.642

0.321

13.23797

40.992

45.769

0

33

2

31

33

2

32

143284.916

0.347

3.19040

192.735

197.514

1

4

2

3

3

1

3

143455.655

0.623

0.00000

3.120

7.905

1

14

2

13

14

0

14

143555.340

0.697

0.56818

35.215

40.003

0

14

2

13

14

0

14

143813.541

0.742

0.56983

35.188

39.985

1

14

2

12

13

2

11

143839.053

0.015

227.14453

35.521

40.319

0

14

2

12

13

2

11

143854.725

0.015

227.17104

35.504

40.302

0

4

2

2

3

1

3

144020.312

0.556

2.76030

3.094

7.898

1

4

2

2

3

1

3

144133.142

0.523

1.37784

3.119

7.927


Kolesniková et al.

Page 56


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

15

2

13

15

1

15

144730.238

1

14

1

13

13

1

12

0

14

1

13

13

1

12

1

38

3

35

38

2

0

38

3

35

38

2

1

12

2

10

12

1

15

2

14

15

0

16

0

16

1

16

0

16

1

18

2

0

15

2

0

18

1

13

0 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.615

0.00000

40.639

45.467

144762.955

0.015

230.58506

32.619

37.448

144779.712

0.016

230.58506

32.597

37.426

36

145082.722

0.875

44.86686

259.171

264.010

36

145174.141

0.938

44.86548

259.172

264.014

0

12

145502.676

0.692

0.11430

26.219

31.072

0

15

145786.483

0.696

0.66425

40.197

45.060

15

1

15

145789.618

0.137

16.89100

40.614

45.477

15

1

15

145803.660

0.134

16.89069

40.640

45.503

17

18

1

18

145849.374

0.616

10.66295

57.373

62.238

14

15

0

15

146043.639

0.742

0.66425

40.172

45.043

2

17

18

1

18

146098.478

0.661

10.66433

57.348

62.221

1

13

12

0

12

146664.417

0.160

13.15863

26.219

31.111

13

1

13

12

0

12

146701.477

0.162

13.15878

26.193

31.086

20

1

19

19

2

18

146737.411

0.428

10.47059

68.613

73.508

1

20

1

19

19

2

18

146799.903

0.388

10.46998

68.630

73.527

1

15

1

15

14

1

14

147710.217

0.018

247.26426

35.712

40.639

0

15

1

15

14

1

14

147714.190

0.017

247.26426

35.687

40.614

1

32

2

30

32

1

31

148249.687

0.409

28.60613

181.228

186.173

1

16

2

15

16

0

16

148385.064

0.695

0.76033

45.502

50.452

0

32

2

30

32

1

31

148442.117

0.420

28.60105

181.218

186.169

0

16

2

15

16

0

16

148642.515

0.742

0.76033

45.477

50.435

1

15

0

15

14

0

14

149391.019

0.017

247.94177

35.215

40.198

1

25

1

24

25

1

25

149398.334

0.465

1.70453

107.759

112.742

0

15

0

15

14

0

14

149398.719

0.016

247.94177

35.188

40.171

1

16

2

15

15

2

13

149458.486

0.090

247.94177

45.467

50.452

1

5

2

4

4

1

3

149623.465

0.639

1.96444

4.607

9.598

0

25

1

24

25

1

25

149667.402

0.470

1.70453

107.735

112.727

1

39

3

36

39

2

37

149929.955

0.879

45.07659

272.474

277.475

0

39

3

36

39

2

37

150026.106

0.933

45.07290

272.476

277.480

0

5

2

4

4

1

3

150068.905

0.542

3.24710

4.580

9.586

1

5

2

3

4

1

3

150319.497

0.494

0.00000

4.607

9.621

1

19

2

18

19

1

19

150797.311

0.625

10.93572

63.600

68.630

0

19

2

18

19

1

19

151052.269

0.669

10.93680

63.575

68.614

1

14

2

12

13

2

12

151071.162

0.083

10.93680

35.280

40.319

1

17

2

16

17

0

17

151362.223

0.695

0.85641

51.129

56.178

1

15

4

12

14

4

10

151545.943

0.320

0.85641

53.657

58.712

1

15

3

13

14

3

11

151565.189

0.284

0.85641

45.768

50.824

0

17

2

16

17

0

17

151621.117

0.742

0.85641

51.103

56.161

1

15

2

14

14

2

13

151622.162

0.010

243.96453

40.002

45.060

0

15

2

14

14

2

13

151628.817

0.009

243.97779

39.985

45.043

1

16

2

14

16

1

16

152079.126

0.634

0.00000

45.892

50.965


Kolesniková et al.

Page 57


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

25

1

24

25

0

25

0

15

6

10

14

6

0

15

6

9

14

6

1

15

6

9

14

0

15

7

8

14

0

15

7

9

1

15

7

8

1

15

5

1

15

6

0

15

0

15

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

152289.850

0.491

13.10866

107.662

112.742

9

152291.565

0.009

208.71940

76.219

81.299

8

152291.566

0.009

208.71940

76.219

81.299

6

8

152294.579

0.011

208.71940

76.213

81.293

7

7

152297.021

0.011

194.36425

90.870

95.950

14

7

8

152297.021

0.011

194.36425

90.870

95.950

14

7

7

152305.356

0.013

194.36425

90.857

95.937

10

14

5

9

152305.607

0.009

220.86644

63.811

68.891

10

14

6

9

152305.872

0.010

208.71940

76.195

81.275

5

11

14

5

10

152308.452

0.009

220.86644

63.807

68.887

5

10

14

5

9

152308.557

0.009

220.86644

63.807

68.887

15

7

9

14

7

8

152311.900

0.010

194.36425

90.845

95.926

15

8

8

14

8

7

152317.040

0.013

177.79935

107.748

112.829

0

15

8

7

14

8

6

152317.040

0.013

177.79935

107.748

112.829

1

15

5

11

14

5

10

152320.058

0.010

220.86644

63.785

68.866

1

15

8

7

14

8

6

152329.378

0.013

177.79935

107.731

112.812

1

15

8

8

14

8

7

152330.255

0.011

177.79935

107.730

112.811

0

15

9

7

14

9

6

152347.965

0.013

159.02470

126.846

131.928

0

15

9

6

14

9

5

152347.965

0.013

159.02470

126.846

131.928

1

15

9

6

14

9

5

152357.557

0.013

159.02470

126.834

131.916

1

15

4

11

14

4

10

152359.528

0.011

230.80041

53.658

58.740

1

15

9

7

14

9

6

152362.427

0.012

159.02470

126.827

131.909

0

15

4

12

14

4

11

152364.647

0.009

230.80372

53.644

58.726

0

15

4

11

14

4

10

152371.577

0.009

230.80372

53.643

58.726

1

15

4

12

14

4

11

152375.079

0.009

230.80041

53.629

58.712

0

15

10

5

14

10

5

152387.751

0.012

230.80041

148.151

153.234

0

15

10

6

14

10

4

152387.751

0.012

230.80041

148.151

153.234

1

15

10

5

14

10

4

152392.326

0.014

138.04194

148.146

153.229

1

15

10

6

14

10

5

152402.158

0.013

138.04194

148.131

153.215

0

15

3

13

14

3

12

152424.246

0.009

238.52462

45.737

50.821

1

15

11

4

14

11

3

152433.941

0.015

114.85108

171.649

176.734

0

15

11

5

14

11

4

152435.019

0.014

114.85108

171.649

176.734

0

15

11

4

14

11

3

152435.019

0.014

114.85108

171.649

176.734

1

15

11

5

14

11

4

152447.205

0.015

114.85108

171.634

176.719

1

15

3

13

14

3

12

152470.177

0.024

236.13762

45.738

50.824

1

15

12

3

14

12

2

152482.154

0.020

89.45212

197.332

202.418

0

15

12

3

14

12

3

152488.686

0.018

89.45212

197.329

202.415

0

15

12

4

14

12

2

152488.686

0.018

89.45212

197.329

202.415

1

15

12

4

14

12

3

152496.813

0.018

89.45212

197.318

202.405

1

15

13

2

14

13

1

152536.825

0.029

61.84340

225.177

230.265

0

15

13

2

14

13

1

152547.821

0.023

61.84340

225.172

230.260

0

15

13

3

14

13

2

152547.821

0.023

61.84340

225.172

230.260


Kolesniková et al.

Page 58


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

15

13

3

14

13

2

0

25

1

24

25

0

1

15

3

12

14

3

1

15

14

1

14

1

15

14

2

14

0

15

14

2

0

15

14

1

0

15

3

1

15

4

1

15

1

34

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

152550.658

0.025

61.84340

225.168

230.257

25

152560.114

0.497

13.10742

107.638

112.727

11

152597.060

0.024

236.13762

45.769

50.859

14

0

152597.784

0.040

32.02658

255.168

260.258

14

1

152608.724

0.037

32.02658

255.165

260.255

14

14

0

152611.610

0.033

32.02658

255.162

260.253

14

14

1

152611.610

0.033

32.02658

255.162

260.253

12

14

3

11

152655.291

0.009

238.52628

45.752

50.844

11

14

4

11

153188.664

0.321

0.00000

53.630

58.740

3

12

14

3

12

153502.049

0.286

0.80837

45.739

50.859

2

32

34

2

33

153890.165

0.384

3.13739

204.061

209.194

34

2

32

34

2

33

154111.740

0.381

3.13739

204.050

209.191

15

2

13

14

2

12

154322.867

0.015

244.04902

40.319

45.467

0

15

2

13

14

2

12

154338.777

0.016

244.06227

40.302

45.450

1

14

1

14

13

0

13

154627.438

0.153

14.49065

30.554

35.712

1

5

2

4

4

1

4

154642.216

0.627

0.00000

4.440

9.598

0

14

1

14

13

0

13

154660.541

0.154

14.49080

30.528

35.687

1

18

2

17

18

0

18

154722.510

0.696

0.94917

57.077

62.238

1

15

1

14

14

1

13

154967.271

0.014

247.18972

37.448

42.617

0

18

2

17

18

0

18

154983.872

0.743

0.94917

57.051

62.221

0

15

1

14

14

1

13

154984.881

0.016

247.18972

37.425

42.595

0

5

2

3

4

1

4

155278.039

0.559

3.00816

4.413

9.593

1

5

2

3

4

1

4

155338.248

0.518

1.81237

4.439

9.621

1

40

3

37

40

2

38

155452.174

0.896

45.10903

286.097

291.282

0

40

3

37

40

2

38

155554.052

0.940

45.10319

286.099

291.288

1

20

2

19

20

1

20

155991.800

0.633

11.17820

70.152

75.355

0

2

2

0

1

0

1

156109.244

0.749

0.00166

0.319

5.526

0

20

2

19

20

1

20

156253.137

0.677

11.17927

70.127

75.339

1

17

2

16

16

2

14

156297.271

0.104

0.09939

50.964

56.178

1

33

2

31

33

1

32

156835.928

0.425

28.24371

192.287

197.518

0

17

0

17

16

1

16

157003.391

0.128

18.44074

45.867

51.104

1

17

0

17

16

1

16

157014.173

0.125

18.44044

45.893

51.130

0

33

2

31

33

1

32

157038.557

0.435

28.23818

192.276

197.514

1

16

1

16

15

1

15

157472.322

0.018

263.88051

40.639

45.892

0

16

1

16

15

1

15

157476.454

0.017

263.88051

40.614

45.867

1

19

2

18

19

0

19

158464.324

0.697

1.03696

63.344

68.630

1

6

2

5

5

1

4

158580.264

0.614

2.65497

6.339

11.629

0

19

2

18

19

0

19

158729.083

0.743

1.03696

63.319

68.614

0

6

2

5

5

1

4

158960.254

0.538

3.62843

6.314

11.616

1

16

0

16

15

0

15

159049.923

0.018

264.44372

40.198

45.503

0

16

0

16

15

0

15

159057.495

0.017

264.44372

40.171

45.477

1

6

2

4

5

1

4

159348.599

0.484

0.00000

6.340

11.655


Kolesniková et al.

Page 59


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

26

1

25

26

1

26

159355.046

0

26

1

25

26

1

26

1

17

2

15

17

1

17

0

21

1

20

20

2

1

21

1

20

20

2

1

21

2

20

21

1

16

3

14

15

1

41

3

38

1

16

2

15

0

16

2

0

21

2

1

16

0

41

1 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.479

1.69625

116.247

121.563

159639.828

0.485

1.69625

116.224

121.549

160183.935

0.653

0.00000

51.470

56.813

19

160550.099

0.417

11.52400

75.339

80.694

19

160602.691

0.377

11.52370

75.355

80.712

1

21

161425.689

0.641

11.39269

77.026

82.411

3

12

161609.275

0.237

11.39269

50.858

56.249

41

2

39

161639.181

0.930

44.98572

300.039

305.431

15

2

14

161648.504

0.009

260.79447

45.060

50.452

15

15

2

14

161656.370

0.009

260.80110

45.043

50.435

20

21

1

21

161693.877

0.685

11.39346

77.001

82.395

4

13

15

4

11

161743.439

0.320

12.78099

58.740

64.135

3

38

41

2

39

161747.649

0.964

44.97757

300.043

305.438

26

1

25

26

0

26

161781.943

0.504

13.00010

116.167

121.563

26

1

25

26

0

26

162067.267

0.510

12.99902

116.143

121.549

0

16

6

11

15

6

10

162450.560

0.009

227.76903

81.299

86.718

0

16

6

10

15

6

9

162450.562

0.009

227.76903

81.299

86.718

0

16

7

9

15

7

8

162452.847

0.011

214.31171

95.949

101.368

0

16

7

10

15

7

9

162452.847

0.011

214.31171

95.949

101.368

1

16

6

10

15

6

9

162453.680

0.011

227.76903

81.293

86.712

1

16

7

9

15

7

8

162461.635

0.013

214.31171

95.937

101.356

1

16

6

11

15

6

10

162465.737

0.010

227.76903

81.275

86.694

1

16

7

10

15

7

9

162468.652

0.010

214.31171

95.927

101.346

1

16

5

11

15

5

10

162471.435

0.009

239.15740

68.892

74.311

0

16

8

8

15

8

7

162471.932

0.013

198.78046

112.830

118.249

0

16

8

9

15

8

8

162471.932

0.013

198.78046

112.830

118.249

0

16

5

12

15

5

11

162474.525

0.009

239.15740

68.887

74.307

0

16

5

11

15

5

10

162474.715

0.009

239.15740

68.887

74.307

1

16

8

8

15

8

7

162484.984

0.013

198.78046

112.812

118.232

1

16

8

9

15

8

8

162485.986

0.011

198.78211

112.811

118.231

1

16

5

12

15

5

11

162486.850

0.010

239.15740

68.866

74.286

0

16

9

7

15

9

7

162503.369

0.013

239.15740

131.927

137.348

0

16

9

8

15

9

6

162503.369

0.013

239.15740

131.927

137.348

1

16

9

7

15

9

6

162513.587

0.013

181.18025

131.916

137.337

1

16

9

8

15

9

7

162518.685

0.012

181.18025

131.909

137.330

1

16

4

12

15

4

11

162540.601

0.012

248.46025

58.739

64.161

0

16

4

13

15

4

12

162544.313

0.009

248.47350

58.726

64.148

0

16

10

7

15

10

6

162544.694

0.013

161.50943

153.233

158.655

0

16

10

6

15

10

5

162544.694

0.013

161.50943

153.233

158.655

1

16

10

6

15

10

5

162549.591

0.014

161.50943

153.229

158.651

0

16

4

12

15

4

11

162555.249

0.009

248.47350

58.727

64.149

1

16

4

13

15

4

12

162557.024

0.009

248.46025

58.713

64.135


Kolesniková et al.

Page 60


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

16

10

7

15

10

6

1

20

2

19

20

0

1

16

11

5

15

11

0

16

11

5

15

0

16

11

6

15

0

16

3

14

1

16

11

6

1

18

2

1

15

1

1

16

1

16

0

16

0

16

1

16

0

15

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

162559.963

0.013

161.50943

153.216

158.638

20

162580.645

0.698

1.11979

69.932

75.355

4

162593.179

0.015

139.76800

176.734

182.158

11

4

162594.280

0.015

139.76800

176.733

182.157

11

5

162594.280

0.015

139.76800

176.733

182.157

15

3

13

162602.412

0.009

255.70905

50.820

56.244

15

11

5

162607.206

0.015

139.76800

176.719

182.143

17

17

2

15

162626.000

0.119

0.13749

56.813

62.238

15

14

0

14

162637.282

0.145

15.87803

35.214

40.639

3

14

15

3

13

162641.146

0.028

253.27401

50.824

56.249

12

4

15

12

3

162643.992

0.021

115.95596

202.418

207.843

12

4

15

12

3

162650.882

0.018

115.95596

202.415

207.840

12

5

15

12

4

162650.882

0.018

115.95596

202.415

207.840

12

5

15

12

4

162659.515

0.019

115.95596

202.405

207.831

1

15

14

0

14

162666.596

0.146

15.87818

35.188

40.614

16

13

3

15

13

2

162701.823

0.031

90.07330

230.265

235.692

16

13

3

15

13

3

162713.450

0.024

90.07330

230.260

235.688

0

16

13

4

15

13

2

162713.450

0.024

90.07330

230.260

235.688

1

16

13

4

15

13

3

162716.485

0.026

90.07330

230.256

235.684

1

16

14

2

15

14

1

162766.454

0.042

62.12003

260.258

265.687

1

16

14

3

15

14

2

162778.059

0.039

62.12003

260.255

265.685

0

16

14

3

15

14

1

162781.082

0.035

62.12003

260.253

265.683

0

16

14

2

15

14

2

162781.082

0.035

62.12003

260.253

265.683

1

16

15

2

15

15

0

162837.568

0.056

62.12003

292.380

297.812

1

16

15

1

15

15

1

162844.410

0.057

62.12003

292.380

297.812

0

20

2

19

20

0

20

162849.653

0.744

1.11979

69.907

75.339

0

16

15

1

15

15

1

162853.029

0.053

1.11979

292.375

297.807

0

16

15

2

15

15

0

162853.029

0.053

1.11979

292.375

297.807

1

16

3

13

15

3

12

162867.639

0.027

253.27401

50.858

56.291

0

16

3

13

15

3

12

162919.790

0.009

255.70905

50.844

56.278

1

16

4

12

15

4

12

163354.186

0.321

14.36580

58.712

64.161

1

15

2

13

14

2

13

163812.180

0.091

13.22597

40.003

45.467

1

16

3

13

15

3

13

163899.510

0.240

13.22597

50.824

56.291

1

16

2

14

15

2

13

164821.209

0.016

260.91043

45.467

50.965

0

16

2

14

15

2

13

164837.734

0.016

260.91871

45.450

50.948

1

35

2

33

35

2

34

164861.930

0.423

3.09764

215.700

221.199

0

35

2

33

35

2

34

165095.013

0.420

3.09764

215.690

221.197

1

16

1

15

15

1

14

165139.225

0.014

263.77947

42.617

48.125

0

16

1

15

15

1

14

165157.613

0.015

263.77947

42.595

48.104

1

3

2

2

2

0

2

165670.626

0.814

0.34381

1.025

6.551

1

34

2

32

34

1

33

165832.901

0.447

27.88022

203.662

209.194

0

34

2

32

34

1

33

166045.840

0.455

27.87438

203.652

209.191


Kolesniková et al.

Page 61


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

6

2

5

5

1

5

166095.949

0

3

2

1

2

0

2

1

3

2

1

2

0

2

1

6

2

4

5

1

0

6

2

4

5

1

1

21

2

20

21

1

22

2

21

22

1

17

1

17

0

17

1

17

1

7

2

0

21

2

0

22

2

0

7

2

0

18

1

18

1

7

2

1

19

2

1

42

3

1

17

0

0

17

1

27

0 1

u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.617

0.00000

6.089

11.629

166282.346

0.749

0.00497

0.995

6.542

166346.574

0.684

0.00166

1.024

6.573

5

166864.284

0.512

2.35653

6.089

11.655

5

166869.270

0.563

3.23050

6.063

11.629

0

21

167059.930

0.699

1.19599

76.838

82.411

1

22

167090.820

0.649

11.58120

84.224

89.798

16

1

16

167222.320

0.018

280.48848

45.892

51.470

16

1

16

167226.588

0.017

280.48848

45.867

51.445

6

6

1

5

167287.896

0.578

3.43254

8.418

13.998

20

21

0

21

167333.972

0.745

1.19599

76.813

82.395

21

22

1

22

167366.289

0.692

11.58197

84.200

89.783

6

6

1

5

167603.602

0.533

4.02897

8.392

13.983

0

18

17

1

17

168079.548

0.118

20.01356

51.444

57.051

0

18

17

1

17

168087.425

0.116

20.01325

51.470

57.077

5

6

1

5

168245.013

0.471

0.00000

8.418

14.030

18

18

2

16

168427.937

0.134

7.05774

63.012

68.630

39

42

2

40

168473.044

0.985

44.73155

314.300

319.920

17

16

0

16

168682.835

0.018

280.95230

45.503

51.130

0

17

16

0

16

168690.227

0.017

280.95230

45.477

51.104

1

26

27

1

27

169324.558

0.494

1.69128

125.059

130.707

27

1

26

27

1

27

169624.661

0.500

1.68962

125.036

130.694

16

1

16

15

0

15

170718.585

0.137

17.31399

40.197

45.892

0

16

1

16

15

0

15

170744.331

0.138

17.31414

40.172

45.867

1

27

1

26

27

0

27

171355.919

0.517

12.91276

124.991

130.707

1

17

3

15

16

3

13

171549.365

0.187

0.00000

56.292

62.014

0

27

1

26

27

0

27

171656.060

0.523

12.91169

124.968

130.694

1

17

2

16

16

2

15

171659.994

0.009

277.58631

50.452

56.178

0

17

2

16

16

2

15

171668.829

0.009

277.59128

50.435

56.161

1

22

2

21

22

0

22

171887.084

0.701

1.26390

84.064

89.798

1

17

4

14

16

4

12

171946.295

0.320

56.21220

64.161

69.897

0

22

2

21

22

0

22

172166.878

0.746

1.26556

84.040

89.783

0

17

7

10

16

7

9

172609.184

0.011

233.85995

101.368

107.126

0

17

7

11

16

7

10

172609.184

0.011

233.85995

101.368

107.126

0

17

6

12

16

6

11

172610.746

0.009

246.52712

86.717

92.475

0

17

6

11

16

6

10

172610.750

0.009

246.52712

86.717

92.475

1

17

6

11

16

6

10

172613.953

0.011

246.52712

86.712

92.470

1

17

7

10

16

7

9

172618.405

0.013

233.85995

101.356

107.114

1

17

7

11

16

7

10

172625.900

0.010

233.85995

101.346

107.104

1

17

6

12

16

6

11

172626.775

0.010

246.52712

86.694

92.452

0

17

8

9

16

8

8

172626.899

0.013

219.24473

118.249

124.007

0

17

8

10

16

8

9

172626.899

0.013

219.24473

118.249

124.007


Kolesniková et al.

Page 62


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

17

5

12

16

5

11

1

17

8

9

16

8

1

17

8

10

16

8

0

17

5

13

16

0

17

5

12

16

1

17

5

13

0

17

9

8

0

17

9

1

17

9

1

17

0

17

0

17

1

17

1

17

1

17

0 1 0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

172639.600

0.009

257.24461

74.310

80.069

8

172640.642

0.013

219.24473

118.231

123.990

9

172641.782

0.011

219.24473

118.231

123.990

5

12

172642.924

0.009

257.24461

74.307

80.066

5

11

172643.257

0.009

257.24461

74.307

80.066

16

5

12

172655.977

0.010

257.24461

74.286

80.045

16

9

7

172658.548

0.013

202.67818

137.349

143.108

9

16

9

8

172658.548

0.013

202.67818

137.349

143.108

8

16

9

7

172669.388

0.013

202.67983

137.337

143.097

9

9

16

9

8

172674.698

0.012

202.67818

137.329

143.089

10

7

16

10

6

172701.198

0.013

184.16525

158.655

164.416

10

8

16

10

7

172701.198

0.013

184.16525

158.655

164.416

10

7

16

10

6

172706.419

0.014

184.16525

158.651

164.412

10

8

16

10

7

172717.310

0.013

184.16525

158.638

164.399

4

13

16

4

12

172726.448

0.012

265.97929

64.161

69.923

17

4

14

16

4

13

172727.721

0.009

266.01242

64.147

69.909

17

4

14

16

4

13

172743.458

0.009

265.97929

64.135

69.897

17

4

13

16

4

12

172744.482

0.009

266.01242

64.149

69.911

17

11

6

16

11

5

172751.827

0.015

163.70262

182.158

187.920

0

17

11

6

16

11

5

172752.944

0.015

163.70262

182.158

187.920

0

17

11

7

16

11

6

172752.944

0.015

163.70262

182.158

187.920

1

17

11

7

16

11

6

172766.593

0.015

163.70262

182.143

187.906

0

17

3

15

16

3

14

172779.485

0.008

272.81728

56.245

62.008

1

17

12

5

16

12

4

172805.122

0.022

141.29031

207.843

213.607

1

17

3

15

16

3

14

172807.729

0.027

270.95538

56.250

62.014

0

17

12

5

16

12

4

172812.356

0.019

141.29031

207.841

213.605

0

17

12

6

16

12

5

172812.356

0.019

141.29031

207.841

213.605

1

17

12

6

16

12

5

172821.488

0.019

141.29031

207.831

213.596

1

17

13

4

16

13

3

172866.021

0.032

116.92997

235.692

241.458

0

17

13

5

16

13

4

172878.259

0.025

116.92997

235.687

241.454

0

17

13

4

16

13

3

172878.259

0.025

116.92997

235.687

241.454

1

17

13

5

16

13

4

172881.494

0.028

116.92997

235.684

241.451

1

17

14

3

16

14

2

172934.248

0.045

90.62160

265.688

271.456

1

17

14

4

16

14

3

172946.505

0.042

90.62160

265.685

271.454

0

17

14

4

16

14

3

172949.656

0.037

90.62160

265.683

271.452

0

17

14

3

16

14

2

172949.656

0.037

90.62160

265.683

271.452

1

23

2

22

23

1

23

172978.107

0.656

11.74603

91.746

97.516

1

17

15

3

16

15

2

173009.437

0.060

62.36354

297.812

303.583

1

17

15

2

16

15

1

173016.673

0.061

62.36354

297.812

303.583

0

17

15

2

16

15

1

173025.724

0.057

62.36354

297.807

303.579

0

17

15

3

16

15

2

173025.724

0.057

62.36354

297.807

303.579

1

17

16

1

16

16

0

173091.104

0.081

32.15578

332.045

337.819


Kolesniková et al.

Page 63


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

17

16

2

16

16

1

0

17

16

2

16

16

0

17

16

1

16

16

1

17

3

14

16

0

17

3

14

16

0

23

2

22

1

17

4

13

0

22

1

1

22

1

1

17

1

35

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

173092.281

0.086

32.15578

332.044

337.818

1

173105.847

0.082

32.15578

332.042

337.816

0

173105.847

0.082

32.15578

332.042

337.816

3

13

173163.279

0.026

270.95704

56.291

62.067

3

13

173206.118

0.010

272.82059

56.278

62.056

23

1

23

173261.250

0.699

11.74680

91.723

97.502

16

4

13

173523.611

0.321

10.26840

64.135

69.923

21

21

2

20

174330.144

0.406

12.65060

82.396

88.211

21

21

2

20

174373.216

0.364

12.65030

82.411

88.227

3

14

16

3

14

174421.643

0.190

12.65030

56.249

62.067

2

33

35

1

34

175187.115

0.476

27.53042

215.355

221.199

17

1

16

16

1

15

175275.535

0.014

280.35265

48.125

53.972

17

1

16

16

1

15

175294.615

0.015

280.35265

48.105

53.952

1

17

2

15

16

2

14

175327.129

0.016

277.74037

50.965

56.813

0

17

2

15

16

2

14

175344.498

0.016

277.74533

50.948

56.797

0

35

2

33

35

1

34

175410.287

0.483

27.52427

215.346

221.197

1

8

2

7

7

1

6

175736.160

0.542

4.13630

10.842

16.704

1

4

2

3

3

0

3

175861.171

0.813

0.18718

2.039

7.905

1

36

2

34

36

2

35

175947.145

0.469

3.06616

227.662

233.531

0

8

2

7

7

1

6

176001.531

0.527

4.44889

10.816

16.687

0

36

2

34

36

2

35

176191.046

0.467

3.06616

227.654

233.531

0

4

2

2

3

0

3

176501.305

0.749

0.00994

2.011

7.898

1

4

2

2

3

0

3

176538.658

0.682

0.00497

2.038

7.927

1

18

1

18

17

1

17

176960.561

0.018

297.08651

51.470

57.373

0

18

1

18

17

1

17

176964.941

0.017

297.08817

51.445

57.348

1

16

2

14

15

2

14

177011.228

0.102

297.08817

45.061

50.965

1

23

2

22

23

0

23

177044.387

0.702

1.32685

91.610

97.516

1

8

2

6

7

1

6

177061.776

0.463

0.00000

10.842

16.748

0

23

2

22

23

0

23

177330.587

0.747

1.32685

91.587

97.502

1

7

2

6

6

1

6

177801.169

0.595

0.00000

8.067

13.998

1

18

0

18

17

0

17

178295.572

0.018

297.46585

51.130

57.077

0

18

0

18

17

0

17

178302.745

0.018

297.46585

51.103

57.051

1

7

2

5

6

1

6

178758.286

0.506

2.90468

8.067

14.030

0

7

2

5

6

1

6

178827.158

0.568

3.41670

8.041

14.006

1

17

1

17

16

0

16

178890.982

0.128

18.79086

45.503

51.470

0

17

1

17

16

0

16

178913.423

0.129

18.79101

45.477

51.445

0

19

0

19

18

1

18

179015.146

0.109

21.60220

57.348

63.319

1

19

0

19

18

1

18

179020.474

0.107

21.60190

57.373

63.344

1

24

2

23

24

1

24

179077.643

0.662

11.88965

99.591

105.564

1

28

1

27

28

1

28

179273.322

0.509

1.68796

134.193

140.173

0

24

2

23

24

1

24

179368.819

0.706

11.89041

99.567

105.550

0

28

1

27

28

1

28

179588.286

0.516

1.68796

134.170

140.160


Kolesniková et al.

Page 64


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

28

1

27

28

0

28

0

28

1

27

28

0

1

18

3

16

17

3

1

18

2

17

17

0

18

2

17

17

1

18

4

15

1

24

2

23

0

18

7

0

18

7

0

18

0

18

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

180969.389

0.530

12.84450

134.137

140.173

28

181284.013

0.537

12.84357

134.113

140.160

14

181358.468

0.143

0.04307

62.068

68.117

2

16

181655.859

0.009

294.34833

56.179

62.238

2

16

181665.499

0.009

294.35165

56.161

62.221

17

4

13

182154.369

0.321

0.25524

69.923

75.999

24

0

24

182512.328

0.704

1.38317

99.476

105.564

12

17

7

11

182766.059

0.011

253.07854

107.127

113.223

11

17

7

10

182766.059

0.011

253.07854

107.127

113.223

6

13

17

6

12

182772.193

0.008

265.04171

92.475

98.572

6

12

17

6

11

182772.201

0.008

265.04171

92.475

98.572

18

6

12

17

6

11

182775.471

0.011

265.04171

92.470

98.567

18

7

11

17

7

10

182775.693

0.013

253.07689

107.114

113.211

0

18

8

11

17

8

10

182781.941

0.013

239.27335

124.007

130.104

0

18

8

10

17

8

9

182781.941

0.013

239.27335

124.007

130.104

1

18

7

12

17

7

11

182783.672

0.010

253.07854

107.104

113.201

1

18

6

13

17

6

12

182789.058

0.010

265.04171

92.452

98.549

1

18

8

10

17

8

9

182796.354

0.013

239.27335

123.991

130.088

1

18

8

11

17

8

10

182797.643

0.011

239.27335

123.990

130.087

0

24

2

23

24

0

24

182805.528

0.749

1.38317

99.452

105.550

1

18

5

13

17

5

12

182810.249

0.009

275.16287

80.069

86.167

0

18

9

10

17

9

9

182813.487

0.013

223.62946

143.108

149.206

0

18

9

9

17

9

8

182813.487

0.013

223.62946

143.108

149.206

0

18

5

14

17

5

13

182813.782

0.009

275.16287

80.066

86.164

0

18

5

13

17

5

12

182814.343

0.009

275.16287

80.066

86.164

1

18

9

9

17

9

8

182824.944

0.013

223.62946

143.097

149.195

1

18

5

14

17

5

13

182827.584

0.010

275.16287

80.046

86.144

1

18

9

10

17

9

9

182830.448

0.012

223.62946

143.089

149.188

0

18

10

9

17

10

8

182857.235

0.013

206.14355

164.417

170.516

0

18

10

8

17

10

7

182857.235

0.013

206.14355

164.417

170.516

1

18

10

8

17

10

7

182862.783

0.014

206.14355

164.411

170.511

1

18

10

9

17

10

8

182874.170

0.013

206.14355

164.399

170.499

1

18

11

7

17

11

6

182909.847

0.016

186.81729

187.920

194.021

0

18

11

8

17

11

7

182910.970

0.015

186.81729

187.920

194.021

0

18

11

7

17

11

6

182910.970

0.015

186.81729

187.920

194.021

0

18

4

15

17

4

14

182914.879

0.009

283.44200

69.910

76.011

1

18

4

14

17

4

13

182917.565

0.012

283.35918

69.923

76.024

1

18

11

8

17

11

7

182925.329

0.015

186.81729

187.906

194.008

1

18

4

15

17

4

14

182934.522

0.010

283.35918

69.897

75.999

0

18

4

14

17

4

13

182939.911

0.009

283.44200

69.911

76.013

0

18

3

16

17

3

15

182954.321

0.008

289.86587

62.007

68.110

1

18

12

6

17

12

5

182965.500

0.023

165.65066

213.608

219.711


Kolesniková et al.

Page 65


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

18

3

16

17

3

15

0

18

12

6

17

12

0

18

12

7

17

12

1

18

12

7

17

1

18

13

5

17

0

18

13

5

0

18

13

6

1

18

13

1

18

14

1

18

0

18

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

182972.382

0.023

288.69639

62.014

68.117

5

182973.063

0.019

165.65066

213.605

219.708

6

182973.063

0.019

165.65066

213.605

219.708

12

6

182982.685

0.020

165.65066

213.595

219.699

13

4

183029.369

0.034

142.64367

241.458

247.563

17

13

5

183042.197

0.026

0.27062

241.454

247.560

17

13

4

183042.197

0.026

0.27062

241.454

247.560

6

17

13

5

183045.632

0.029

142.64367

241.451

247.557

4

17

14

3

183101.111

0.048

117.79632

271.455

277.563

14

5

17

14

4

183114.007

0.044

117.79632

271.454

277.562

14

4

17

14

4

183117.275

0.039

117.79632

271.452

277.560

18

14

5

17

14

3

183117.275

0.039

117.79632

271.452

277.560

18

15

4

17

15

3

183180.309

0.064

91.10861

303.583

309.693

1

18

15

3

17

15

2

183187.932

0.064

91.10861

303.583

309.693

0

18

15

4

17

15

3

183197.398

0.060

91.10861

303.579

309.690

0

18

15

3

17

15

2

183197.398

0.060

91.10861

303.579

309.690

1

18

16

2

17

16

1

183266.425

0.086

62.57888

337.820

343.933

1

18

16

3

17

16

2

183267.681

0.091

62.57888

337.818

343.931

0

18

16

2

17

16

1

183281.895

0.088

62.57888

337.816

343.930

0

18

16

3

17

16

2

183281.895

0.088

62.57888

337.816

343.930

1

18

17

2

17

17

1

183353.548

0.126

32.21045

374.138

380.254

1

18

17

1

17

17

0

183358.810

0.116

32.21045

374.144

380.260

0

18

17

2

17

17

1

183370.342

0.121

32.21045

374.141

380.258

0

18

17

1

17

17

0

183370.342

0.121

32.21045

374.141

380.258

1

18

3

15

17

3

14

183482.815

0.021

288.70136

62.068

68.188

0

18

3

15

17

3

14

183516.712

0.010

289.86919

62.056

68.177

1

18

4

14

17

4

14

183697.718

0.322

0.04141

69.897

76.024

1

9

2

8

8

1

7

183927.214

0.515

4.73319

13.612

19.747

0

9

2

8

8

1

7

184157.529

0.521

4.88941

13.586

19.729

1

36

2

34

36

1

35

184842.064

0.512

27.20491

227.365

233.531

0

36

2

34

36

1

35

185075.205

0.518

27.19876

227.358

233.531

1

18

3

15

17

3

15

185096.729

0.147

5.21923

62.014

68.188

1

18

1

17

17

1

16

185372.907

0.014

296.90927

53.972

60.155

1

25

2

24

25

1

25

185378.812

0.669

12.01404

107.758

113.942

0

18

1

17

17

1

16

185392.585

0.015

296.91092

53.952

60.136

0

25

2

24

25

1

25

185678.347

0.712

12.01481

107.734

113.928

1

18

2

16

17

2

15

185833.488

0.016

294.54380

56.813

63.012

1

9

2

7

8

1

7

185844.542

0.460

0.00000

13.612

19.811

0

18

2

16

17

2

15

185851.833

0.016

294.54711

56.797

62.996

1

5

2

4

4

0

4

186096.473

0.807

18.36386

3.390

9.598

1

19

1

19

18

1

18

186687.488

0.017

313.68123

57.373

63.600

0

19

1

19

18

1

18

186691.961

0.017

313.68123

57.348

63.575


Kolesniková et al.

Page 66


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

5

2

3

4

0

4

186792.505

0

5

2

3

4

0

4

1

37

2

35

37

2

36

1

18

1

18

17

0

0

18

1

18

17

0

0

37

2

35

37

1

19

0

19

18

0

19

0

19

0

23

1

22

1

23

1

1

25

2

0

25

1

29

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.679

0.01160

3.390

9.621

186801.033

0.748

0.01822

3.362

9.593

187102.319

0.524

3.04629

239.948

246.189

17

187168.708

0.119

20.30047

51.130

57.373

17

187188.138

0.120

20.30063

51.104

57.348

2

36

187356.233

0.523

3.04463

239.939

246.189

0

18

187893.611

0.018

313.98768

57.077

63.344

18

0

18

187900.540

0.018

313.98768

57.051

63.319

22

2

21

188044.619

0.393

13.85055

89.784

96.056

22

22

2

21

188078.615

0.350

13.85039

89.798

96.072

24

25

0

25

188270.328

0.706

1.43286

107.662

113.942

2

24

25

0

25

188571.058

0.750

1.43286

107.638

113.928

1

28

29

1

29

189172.591

0.525

1.68962

143.648

149.958

29

1

28

29

1

29

189501.904

0.532

1.68962

143.625

149.946

8

2

7

7

1

7

189745.132

0.572

0.00000

10.375

16.704

0

20

0

20

19

1

19

189811.654

0.100

23.20039

63.576

69.907

1

20

0

20

19

1

19

189814.780

0.098

23.19992

63.600

69.932

1

29

1

28

29

0

29

190585.509

0.544

12.79314

143.601

149.958

1

17

2

15

16

2

15

190689.853

0.116

0.20342

50.452

56.813

0

29

1

28

29

0

29

190914.208

0.551

12.79222

143.578

149.946

1

19

3

17

18

3

15

191011.224

0.108

6.77313

68.188

74.559

1

8

2

6

7

1

7

191070.748

0.508

3.30446

10.375

16.748

0

8

2

6

7

1

7

191189.490

0.574

3.55924

10.349

16.726

1

19

2

18

18

2

17

191635.425

0.009

311.08385

62.238

68.630

0

19

2

18

18

2

17

191645.752

0.009

311.08551

62.221

68.614

1

10

2

9

9

1

8

191870.116

0.496

5.27289

16.726

23.126

1

26

2

25

26

1

26

191870.424

0.675

12.12152

116.248

122.648

0

10

2

9

9

1

8

192076.134

0.515

5.35239

16.701

23.108

0

26

2

25

26

1

26

192178.613

0.718

12.12213

116.224

122.634

1

19

4

16

18

4

14

192366.990

0.322

12.12213

76.024

82.441

0

19

7

13

18

7

12

192923.502

0.011

272.01554

113.223

119.658

0

19

7

12

18

7

11

192923.502

0.011

272.01554

113.223

119.658

1

19

7

12

18

7

11

192933.526

0.013

272.01554

113.210

119.646

0

19

6

14

18

6

13

192934.973

0.008

283.34924

98.572

105.008

0

19

6

13

18

6

12

192934.987

0.008

283.34924

98.572

105.008

0

19

8

12

18

8

11

192937.060

0.013

258.93920

130.104

136.540

0

19

8

11

18

8

10

192937.060

0.013

258.93920

130.104

136.540

1

19

6

13

18

6

12

192938.302

0.011

283.34924

98.566

105.002

1

19

7

13

18

7

12

192941.994

0.010

272.01554

113.201

119.637

1

19

8

11

18

8

10

192952.120

0.013

258.93920

130.088

136.524

1

19

6

14

18

6

13

192952.653

0.010

283.34924

98.549

104.985

1

19

8

12

18

8

11

192953.570

0.011

258.93920

130.087

136.523


Kolesniková et al.

Page 67


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

19

9

10

18

9

9

0

19

9

11

18

9

1

19

9

10

18

9

1

19

5

14

18

1

19

9

11

18

0

19

5

15

0

19

5

14

1

19

5

15

0

19

10

9

0

19

10

1

19

10

1

19

1

19

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

192968.169

0.013

244.11693

149.205

155.642

10

192968.169

0.013

244.11693

149.205

155.642

9

192980.239

0.013

244.11693

149.195

155.632

5

13

192983.530

0.010

292.93866

86.167

92.604

9

10

192985.919

0.012

244.11693

149.188

155.625

18

5

14

192987.226

0.008

292.93866

86.164

92.601

18

5

13

192988.144

0.008

292.93866

86.164

92.601

18

5

14

193001.818

0.010

292.93866

86.144

92.582

18

10

9

193012.776

0.013

292.93866

170.516

176.954

10

18

10

8

193012.776

0.013

292.93866

170.516

176.954

9

18

10

8

193018.652

0.014

227.55203

170.512

176.950

10

10

18

10

9

193030.513

0.013

227.55203

170.499

176.938

11

8

18

11

7

193067.200

0.016

209.24285

194.021

200.461

19

11

9

18

11

8

193068.321

0.015

209.24285

194.021

200.461

19

11

8

18

11

7

193068.321

0.015

209.24285

194.021

200.461

1

19

11

9

18

11

8

193083.373

0.016

209.24285

194.007

200.448

0

19

4

16

18

4

15

193105.728

0.009

300.78048

76.011

82.452

1

19

4

15

18

4

14

193114.647

0.012

300.58502

76.024

82.466

1

19

12

7

18

12

6

193125.080

0.024

189.19104

219.711

226.153

0

19

3

17

18

3

16

193125.688

0.008

306.86146

68.110

74.552

1

19

4

16

18

4

15

193130.185

0.010

300.58502

75.999

82.441

0

19

12

8

18

12

7

193132.956

0.020

189.19104

219.708

226.150

0

19

12

7

18

12

6

193132.956

0.020

189.19104

219.708

226.150

1

19

3

17

18

3

16

193135.571

0.019

306.20218

68.117

74.559

0

19

4

15

18

4

14

193142.260

0.009

300.78048

76.012

82.455

1

19

12

8

18

12

7

193143.059

0.021

189.19104

219.699

226.142

1

19

13

6

18

13

5

193191.814

0.036

167.39494

247.563

254.007

0

19

13

7

18

13

6

193205.213

0.027

167.39494

247.560

254.005

0

19

13

6

18

13

5

193205.213

0.027

167.39494

247.560

254.005

1

19

13

7

18

13

6

193208.848

0.031

167.39494

247.557

254.002

1

19

14

5

18

14

4

193266.988

0.050

143.85456

277.563

284.010

1

19

14

6

18

14

5

193280.508

0.046

143.85456

277.562

284.009

0

19

14

5

18

14

4

193283.883

0.042

143.85456

277.560

284.007

0

19

14

6

18

14

5

193283.883

0.042

143.85456

277.560

284.007

1

19

15

5

18

15

4

193350.124

0.068

118.57155

309.693

316.142

1

19

15

4

18

15

3

193358.127

0.068

118.57155

309.693

316.143

0

19

15

5

18

15

4

193367.990

0.064

118.57155

309.690

316.140

0

19

15

4

18

15

3

193367.990

0.064

118.57155

309.690

316.140

1

19

16

3

18

16

2

193440.630

0.092

91.54426

343.933

350.385

1

19

16

4

18

16

3

193441.964

0.097

91.54426

343.931

350.384

0

19

16

4

18

16

3

193456.803

0.093

91.54426

343.930

350.383

0

19

16

3

18

16

2

193456.803

0.093

91.54426

343.930

350.383


Kolesniková et al.

Page 68


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

19

17

3

18

17

2

1

19

17

2

18

17

0

19

17

2

18

17

0

19

17

3

18

1

19

18

2

18

1

19

18

1

0

19

18

1

0

19

18

1

19

3

0

19

3

1

19

4

1

26

0

26

1

10

2

1

37

2

0

37

2

1

19

1

0

19

1

19

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

193532.311

0.133

62.77269

380.254

386.710

1

193537.803

0.124

62.77269

380.260

386.716

1

193549.860

0.129

62.77269

380.258

386.714

17

2

193549.860

0.129

62.77269

380.258

386.714

18

1

193629.377

0.178

32.25849

418.640

425.099

18

18

0

193640.860

0.165

32.25849

418.653

425.112

18

18

0

193646.980

0.172

32.25849

418.651

425.110

2

18

18

1

193646.980

0.172

32.25849

418.651

425.110

16

18

3

15

193826.880

0.017

306.20880

68.188

74.653

16

18

3

15

193853.905

0.010

306.86809

68.178

74.644

15

18

4

15

193877.842

0.323

0.03147

75.999

82.466

2

25

26

0

26

194297.320

0.708

1.47593

116.167

122.648

2

25

26

0

26

194606.052

0.752

1.47593

116.143

122.634

8

9

1

8

194636.645

0.458

0.00000

16.726

23.218

35

37

1

36

194739.906

0.557

26.91108

239.693

246.189

35

37

1

36

194982.575

0.563

26.90477

239.685

246.189

18

18

1

17

195428.152

0.014

313.45263

60.155

66.674

1

18

18

1

17

195448.326

0.015

313.45263

60.136

66.655

1

19

18

0

18

195560.624

0.110

21.83530

57.077

63.600

19

1

19

18

0

18

195577.354

0.111

21.83546

57.051

63.575

19

3

16

18

3

16

195951.227

0.114

21.83546

68.117

74.653

1

19

2

17

18

2

16

196333.368

0.016

311.32404

63.012

69.561

0

19

2

17

18

2

16

196352.756

0.016

311.32570

62.996

69.546

1

6

2

5

5

0

5

196389.130

0.792

311.32570

5.078

11.629

1

20

1

20

19

1

19

196403.625

0.017

330.26932

63.600

70.151

0

20

1

20

19

1

19

196408.170

0.017

330.26932

63.576

70.127

1

6

2

4

5

0

5

197157.464

0.675

0.02319

5.079

11.655

0

6

2

4

5

0

5

197226.244

0.748

0.03147

5.050

11.629

1

20

0

20

19

0

19

197481.794

0.018

330.51614

63.345

69.932

0

20

0

20

19

0

19

197488.468

0.017

330.51614

63.319

69.907

1

38

2

36

38

2

37

198285.036

0.588

3.03138

252.556

259.170

1

27

2

26

27

1

27

198540.853

0.681

12.21393

125.059

131.682

0

38

2

36

38

2

37

198548.058

0.587

3.03138

252.548

259.171

0

27

2

26

27

1

27

198857.960

0.723

12.21454

125.036

131.669

1

30

1

29

30

1

30

198998.959

0.541

1.69293

153.425

160.063

0

30

1

29

30

1

30

199342.076

0.548

1.69293

153.403

160.052

1

11

2

10

10

1

9

199574.889

0.482

5.79829

20.184

26.841

0

11

2

10

10

1

9

199763.097

0.508

5.84057

20.160

26.823

1

30

1

29

30

0

30

200173.575

0.558

12.75578

153.386

160.063

0

21

0

21

20

1

20

200474.057

0.092

24.80303

70.127

76.814

1

21

0

21

20

1

20

200475.313

0.090

24.80272

70.151

76.838

1

20

3

18

19

3

16

200480.471

0.084

24.80272

74.653

81.340


Kolesniková et al.

Page 69


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

30

1

29

30

0

30

1

27

2

26

27

0

0

27

2

26

27

0

1

20

2

19

19

0

20

2

19

19

0

24

1

23

1

24

1

23

1

9

2

1

20

4

0

20

7

0

20

7

1

20

0

20

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

200515.888

0.565

12.75501

153.364

160.052

27

200572.214

0.710

1.51569

124.992

131.682

27

200889.359

0.753

1.51569

124.968

131.669

2

18

201598.114

0.009

327.79784

68.630

75.355

2

18

201609.038

0.009

327.79949

68.614

75.339

23

2

22

201660.780

0.380

15.12306

97.501

104.228

23

2

22

201686.214

0.336

15.12260

97.516

104.244

8

8

1

8

201927.161

0.560

0.00000

13.011

19.747

17

19

4

15

202582.429

0.323

15.57374

82.466

89.223

14

19

7

13

203081.540

0.010

290.71731

119.658

126.432

13

19

7

12

203081.540

0.010

290.71731

119.658

126.432

7

13

19

7

12

203091.932

0.013

290.71731

119.647

126.421

8

13

19

8

12

203092.259

0.012

278.29363

136.540

143.314

20

8

12

19

8

11

203092.259

0.012

278.29363

136.540

143.314

20

6

15

19

6

14

203099.155

0.008

301.48449

105.007

111.782

0

20

6

14

19

6

13

203099.180

0.008

301.48449

105.007

111.782

1

20

7

14

19

7

13

203100.893

0.010

290.71731

119.637

126.412

1

20

6

14

19

6

13

203102.518

0.011

301.48449

105.002

111.777

1

20

8

12

19

8

11

203107.940

0.013

278.29363

136.524

143.299

1

20

8

13

19

8

12

203109.563

0.011

278.29363

136.523

143.298

1

20

6

15

19

6

14

203117.631

0.010

301.48449

104.986

111.761

0

20

9

12

19

9

11

203122.579

0.013

264.21347

155.643

162.418

0

20

9

11

19

9

10

203122.579

0.013

264.21347

155.643

162.418

1

20

9

11

19

9

10

203135.254

0.013

264.21347

155.632

162.408

1

20

9

12

19

9

11

203141.091

0.012

264.21347

155.625

162.401

1

20

5

15

19

5

14

203159.594

0.010

310.59188

92.604

99.381

0

20

5

16

19

5

15

203163.377

0.008

310.59353

92.601

99.378

0

20

5

15

19

5

14

203164.840

0.008

310.59353

92.601

99.378

0

20

10

10

19

10

9

203167.791

0.013

248.47681

176.954

183.731

0

20

10

11

19

10

10

203167.791

0.013

248.47681

176.954

183.731

1

20

10

10

19

10

9

203173.996

0.014

248.47681

176.950

183.727

1

20

5

16

19

5

15

203178.826

0.010

310.59353

92.582

99.359

1

20

10

11

19

10

10

203186.307

0.012

248.47681

176.937

183.715

1

20

11

9

19

11

8

203223.848

0.016

231.08367

200.461

207.240

0

20

11

10

19

11

8

203224.959

0.015

231.08367

200.461

207.240

0

20

11

9

19

11

9

203224.959

0.015

231.08367

200.461

207.240

1

20

11

10

19

11

9

203240.685

0.016

231.08367

200.449

207.228

1

20

12

8

19

12

7

203283.816

0.025

212.03403

226.152

232.933

0

20

12

9

19

12

7

203291.990

0.020

212.03403

226.150

232.931

0

20

12

8

19

12

8

203291.990

0.020

212.03403

226.150

232.931

0

20

3

18

19

3

17

203292.287

0.008

323.81232

74.552

81.333

1

20

3

18

19

3

17

203296.126

0.015

323.45618

74.559

81.340


Kolesniková et al.

Page 70


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

20

4

17

19

4

16

1

20

12

9

19

12

1

20

4

16

19

4

1

20

4

17

19

4

0

20

4

16

19

4

1

20

13

7

19

0

20

13

8

19

0

20

13

7

1

20

13

8

1

20

14

1

20

14

0

20

0

20

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

203300.138

0.009

318.04277

82.452

89.233

8

203302.564

0.022

212.03403

226.142

232.923

15

203318.749

0.013

317.60380

82.466

89.248

16

203330.086

0.010

317.60380

82.441

89.223

15

203352.356

0.009

318.04277

82.456

89.239

13

6

203353.306

0.038

191.32791

254.008

260.791

13

6

203367.253

0.029

191.32791

254.004

260.788

19

13

7

203367.253

0.029

191.32791

254.004

260.788

19

13

7

203371.089

0.033

191.32791

254.001

260.785

6

19

14

5

203431.823

0.053

168.96364

284.010

290.796

7

19

14

6

203445.951

0.049

168.96364

284.009

290.795

14

6

19

14

5

203449.423

0.044

168.96364

284.008

290.794

14

7

19

14

6

203449.423

0.044

168.96364

284.008

290.794

11

2

9

10

1

9

203484.196

0.455

0.00000

20.184

26.972

20

15

6

19

15

5

203518.824

0.072

144.94453

316.142

322.931

1

20

15

5

19

15

4

203527.198

0.072

144.94453

316.143

322.932

0

20

15

5

19

15

4

203537.439

0.068

144.94453

316.140

322.929

0

20

15

6

19

15

5

203537.439

0.068

144.94453

316.140

322.929

1

20

16

4

19

16

3

203613.656

0.098

119.26894

350.385

357.177

1

20

16

5

19

16

4

203615.069

0.102

119.26894

350.384

357.176

0

20

16

5

19

16

4

203630.507

0.099

119.26894

350.383

357.175

0

20

16

4

19

16

3

203630.507

0.099

119.26894

350.383

357.175

1

20

17

4

19

17

3

203709.849

0.141

91.93685

386.710

393.505

1

20

17

3

19

17

2

203715.561

0.131

91.93685

386.716

393.511

0

20

17

4

19

17

3

203728.126

0.137

91.93685

386.714

393.510

0

20

17

3

19

17

2

203728.126

0.137

91.93685

386.714

393.510

1

20

18

3

19

18

2

203811.742

0.188

62.94828

425.100

431.898

1

20

18

2

19

18

1

203823.704

0.175

62.94828

425.112

431.911

0

20

18

2

19

18

2

203830.087

0.182

62.94828

425.111

431.910

0

20

18

3

19

18

1

203830.087

0.182

62.94828

425.111

431.910

1

9

2

7

8

1

8

203844.489

0.516

3.53356

13.011

19.811

1

20

19

2

19

19

1

203920.788

0.242

32.30156

465.531

472.333

0

20

19

2

19

19

1

203936.456

0.237

32.30156

465.546

472.349

0

20

19

1

19

19

0

203936.456

0.237

32.30156

465.546

472.349

1

20

19

1

19

19

0

203937.234

0.230

32.30156

465.548

472.351

0

9

2

7

8

1

8

203997.849

0.581

3.65349

12.985

19.790

1

20

4

16

19

4

16

204066.406

0.324

3.65349

82.441

89.248

1

20

1

20

19

0

19

204070.639

0.101

23.38843

63.344

70.151

0

20

1

20

19

0

19

204084.984

0.102

23.38874

63.319

70.127

1

20

3

17

19

3

16

204197.420

0.014

323.46612

74.653

81.464

0

20

3

17

19

3

16

204219.776

0.011

323.82226

74.644

81.456

1

38

2

36

38

1

37

204823.159

0.612

26.65276

252.338

259.170


Kolesniková et al.

Page 71


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

18

2

16

17

2

16

0

38

2

36

38

1

1

28

2

27

28

1

1

20

1

19

19

0

20

1

19

19

0

28

2

27

1

21

1

21

0

21

1

1

7

2

1

20

0

20

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

204863.347

0.130

26.65276

56.178

63.012

37

205074.755

0.618

26.64676

252.330

259.171

28

205378.186

0.687

12.29311

134.193

141.044

1

18

205438.326

0.014

329.98275

66.674

73.527

1

18

205458.884

0.015

329.98275

66.655

73.508

28

1

28

205704.441

0.728

12.29388

134.169

141.031

20

1

20

206109.553

0.017

346.85244

70.151

77.026

21

20

1

20

206114.151

0.017

346.85244

70.127

77.002

6

6

0

6

206745.592

0.767

0.00000

7.102

13.998

2

18

19

2

17

206820.371

0.015

328.08275

69.561

76.460

2

18

19

2

17

206840.821

0.016

328.08275

69.546

76.445

20

3

17

19

3

17

207013.076

0.091

0.00000

74.559

81.464

12

2

11

11

1

10

207051.442

0.471

6.33368

23.987

30.893

1

21

0

21

20

0

20

207064.157

0.018

347.05122

69.931

76.838

0

21

0

21

20

0

20

207070.573

0.017

347.05122

69.907

76.814

1

28

2

27

28

0

28

207074.253

0.713

1.54882

134.137

141.044

0

12

2

11

11

1

10

207225.574

0.501

6.35721

23.963

30.875

0

28

2

27

28

0

28

207400.168

0.755

1.54882

134.113

141.031

1

7

2

5

6

0

6

207702.709

0.671

0.04141

7.102

14.030

0

7

2

5

6

0

6

207830.985

0.748

0.04804

7.074

14.006

1

31

1

30

31

1

31

208734.548

0.558

1.69625

163.523

170.486

0

31

1

30

31

1

31

209090.911

0.566

1.69625

163.500

170.475

1

39

2

37

39

2

38

209455.015

0.662

3.02641

265.487

272.474

1

31

1

30

31

0

31

209709.219

0.574

12.72994

163.491

170.486

0

39

2

37

39

2

38

209726.161

0.662

3.02641

265.479

272.475

1

21

3

19

20

3

17

209735.305

0.070

3.02641

81.464

88.460

0

31

1

30

31

0

31

210064.654

0.581

12.72933

163.468

170.475

1

22

0

22

21

1

21

211009.631

0.082

26.40628

77.026

84.065

0

22

0

22

21

1

21

211009.940

0.084

26.40659

77.001

84.040

1

21

2

20

20

2

19

211543.442

0.009

344.49360

75.355

82.411

0

21

2

20

20

2

19

211554.892

0.009

344.49526

75.338

82.395

1

29

2

28

29

1

29

212370.364

0.693

12.36107

143.648

150.732

1

12

2

10

11

1

10

212436.093

0.452

0.00000

23.986

31.072

1

21

1

21

20

0

20

212698.398

0.092

24.95417

69.931

77.026

1

21

5

17

20

5

15

212703.379

0.448

24.95417

99.381

106.476

0

29

2

28

29

1

29

212705.965

0.734

12.36169

143.625

150.720

0

21

1

21

20

0

20

212710.668

0.093

24.95433

69.907

77.002

1

21

4

18

20

4

16

212797.004

0.321

72.98664

89.248

96.346

0

21

7

14

20

7

13

213240.201

0.010

309.21533

126.432

133.545

0

21

7

15

20

7

14

213240.201

0.010

309.21533

126.432

133.545

0

21

8

13

20

8

12

213247.537

0.012

297.38302

143.314

150.427

0

21

8

14

20

8

13

213247.537

0.012

297.38302

143.314

150.427


Kolesniková et al.

Page 72


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

21

7

14

20

7

13

1

21

7

15

20

7

1

21

8

13

20

8

0

21

6

16

20

0

21

6

15

20

1

21

8

14

1

21

6

15

0

21

9

0

21

9

1

21

1

21

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

213250.936

0.013

309.21533

126.421

133.534

14

213260.395

0.010

309.21533

126.411

133.525

12

213263.815

0.013

297.38302

143.299

150.413

6

15

213264.810

0.008

319.46900

111.782

118.896

6

14

213264.852

0.008

319.46900

111.782

118.896

20

8

13

213265.623

0.011

297.38302

143.298

150.412

20

6

14

213268.188

0.011

319.46900

111.777

118.891

12

20

9

11

213276.698

0.013

283.97374

162.418

169.532

13

20

9

12

213276.698

0.013

283.97374

162.418

169.532

6

16

20

6

15

213284.061

0.010

319.46900

111.761

118.875

9

12

20

9

11

213289.973

0.013

283.97374

162.408

169.523

21

9

13

20

9

12

213295.947

0.012

283.97374

162.401

169.516

21

10

12

20

10

10

213322.251

0.013

283.97374

183.730

190.846

0

21

10

11

20

10

11

213322.251

0.013

283.97374

183.730

190.846

1

21

10

11

20

10

10

213328.787

0.013

268.98582

183.727

190.843

1

21

5

16

20

5

15

213338.595

0.010

328.14239

99.381

106.497

1

21

10

12

20

10

11

213341.523

0.012

268.98582

183.716

190.832

0

21

5

17

20

5

16

213342.347

0.008

328.14404

99.378

106.494

0

21

5

16

20

5

15

213344.624

0.008

328.14404

99.378

106.494

1

21

5

17

20

5

16

213358.758

0.010

328.14239

99.359

106.476

1

21

11

10

20

11

9

213379.751

0.016

252.42092

207.240

214.358

0

21

11

10

20

11

9

213380.843

0.016

252.42092

207.240

214.358

0

21

11

11

20

11

10

213380.843

0.016

252.42092

207.240

214.358

1

21

11

11

20

11

10

213397.226

0.016

252.42092

207.228

214.346

1

21

12

9

20

12

8

213441.663

0.026

234.27738

232.933

240.053

0

21

12

9

20

12

8

213450.118

0.021

234.27738

232.931

240.051

0

21

12

10

20

12

9

213450.118

0.021

234.27738

232.931

240.051

1

21

3

19

20

3

18

213452.255

0.012

340.53293

81.340

88.460

0

21

3

19

20

3

18

213452.771

0.009

340.72343

81.333

88.453

1

21

12

10

20

12

9

213461.153

0.023

234.27738

232.924

240.044

0

21

4

18

20

4

17

213497.895

0.008

335.23713

89.233

96.355

1

21

13

8

20

13

7

213513.795

0.040

214.55852

260.791

267.913

0

21

13

8

20

13

8

213528.267

0.030

214.55852

260.788

267.911

0

21

13

9

20

13

7

213528.267

0.030

214.55852

260.788

267.911

1

21

4

17

20

4

16

213531.500

0.013

334.33269

89.248

96.371

1

21

13

9

20

13

8

213532.303

0.034

214.55852

260.785

267.908

1

21

4

18

20

4

17

213533.324

0.011

334.33269

89.223

96.346

0

21

4

17

20

4

16

213571.142

0.008

335.23713

89.239

96.363

1

21

14

7

20

14

6

213595.562

0.056

193.25938

290.795

297.920

1

21

14

8

20

14

7

213610.281

0.052

193.25938

290.795

297.920

0

21

14

8

20

14

7

213613.840

0.047

193.25938

290.794

297.919

0

21

14

7

20

14

6

213613.840

0.047

193.25938

290.794

297.919


Kolesniková et al.

Page 73


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

21

15

7

20

15

6

1

21

15

6

20

15

0

21

15

7

20

15

0

21

15

6

20

1

29

2

28

29

1

21

16

5

1

21

16

6

0

21

16

0

21

16

1

21

1

21

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

213686.349

0.077

170.38490

322.931

330.059

5

213695.085

0.076

170.38490

322.932

330.060

5

213705.685

0.073

170.38490

322.930

330.058

15

6

213705.685

0.073

170.38490

322.930

330.058

0

29

213783.281

0.716

1.57863

143.601

150.732

20

16

4

213785.441

0.104

145.93014

357.177

364.308

20

16

5

213786.933

0.108

145.93014

357.176

364.307

5

20

16

5

213802.945

0.105

145.93014

357.175

364.307

6

20

16

4

213802.945

0.105

145.93014

357.175

364.307

17

5

20

17

4

213886.097

0.149

119.90006

393.505

400.639

17

4

20

17

3

213892.020

0.139

119.90006

393.511

400.646

21

17

4

20

17

3

213905.074

0.145

119.90006

393.510

400.645

21

17

5

20

17

4

213905.074

0.145

119.90006

393.510

400.645

1

21

18

4

20

18

3

213992.775

0.199

92.29134

431.898

439.036

1

21

5

16

20

5

16

213993.974

0.447

92.29134

99.359

106.497

1

21

18

3

20

18

2

214005.197

0.185

92.29134

431.911

439.049

0

21

18

3

20

18

2

214011.835

0.192

92.29134

431.909

439.048

0

21

18

4

20

18

3

214011.835

0.192

92.29134

431.909

439.048

1

21

19

3

20

19

2

214106.995

0.256

63.10564

472.333

479.475

0

29

2

28

29

0

29

214118.268

0.758

1.57863

143.578

150.720

0

21

19

3

20

19

2

214123.280

0.250

63.10564

472.349

479.491

0

21

19

2

20

19

1

214123.280

0.250

63.10564

472.349

479.491

1

21

19

2

20

19

1

214124.074

0.243

63.10564

472.351

479.493

1

21

20

2

20

20

1

214228.575

0.322

32.34131

514.786

521.932

0

21

20

1

20

20

0

214239.685

0.321

32.34131

514.800

521.946

0

21

20

2

20

20

1

214239.685

0.321

32.34131

514.800

521.946

1

21

20

1

20

20

0

214247.806

0.314

32.34131

514.804

521.951

1

21

4

17

20

4

17

214267.821

0.323

32.34131

89.224

96.371

1

13

2

12

12

1

11

214310.150

0.461

6.89183

28.131

35.280

1

10

2

9

9

1

9

214352.600

0.555

0.00000

15.976

23.126

0

13

2

12

12

1

11

214472.326

0.494

6.90552

28.108

35.262

1

21

3

18

20

3

17

214596.531

0.012

340.55115

81.465

88.623

0

21

3

18

20

3

17

214615.977

0.011

340.74165

81.455

88.614

1

39

2

37

39

1

38

215036.346

0.678

26.43165

265.301

272.474

0

25

1

24

24

2

23

215147.110

0.365

16.46493

105.550

112.727

1

25

1

24

24

2

23

215164.565

0.320

16.46447

105.565

112.742

0

39

2

37

39

1

38

215296.128

0.685

26.42581

265.293

272.475

1

21

1

20

20

1

19

215400.902

0.015

346.49795

73.527

80.712

0

21

1

20

20

1

19

215421.726

0.015

346.49795

73.508

80.694

1

22

1

22

21

1

21

215805.896

0.017

363.43225

77.026

84.225

0

22

1

22

21

1

21

215810.530

0.017

363.43225

77.002

84.201

1

22

0

22

21

0

21

216643.872

0.017

363.59127

76.839

84.065


Kolesniková et al.

Page 74


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

22

0

22

21

0

21

1

10

2

8

9

1

1

8

2

7

7

0

1

21

2

19

20

0

10

2

8

9

0

21

2

19

1

21

3

18

1

32

1

1

8

2

0

8

2

0

32

1

1

22

3

1

32

1

1

30

1

19

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

216650.035

0.017

363.59127

76.813

84.040

9

217119.129

0.528

3.63996

15.976

23.218

7

217178.339

0.741

3.63996

9.460

16.704

2

18

217288.782

0.015

344.81993

76.460

83.708

1

9

217296.478

0.589

3.69701

15.950

23.198

20

2

18

217310.278

0.015

344.82158

76.445

83.694

20

3

18

218313.481

0.078

0.11761

81.341

88.623

31

32

1

32

218366.875

0.576

1.70287

173.944

181.228

6

7

0

7

218503.955

0.671

0.06295

9.459

16.748

6

7

0

7

218677.841

0.748

0.06792

9.432

16.726

31

32

1

32

218735.926

0.584

1.70287

173.921

181.217

20

21

3

18

218740.869

0.063

1.70287

88.623

95.919

31

32

0

32

219174.245

0.590

12.71318

173.917

181.228

2

29

30

1

30

219505.322

0.700

12.41904

153.425

160.747

2

17

18

2

17

219540.856

0.145

0.00000

62.238

69.561

32

1

31

32

0

32

219542.299

0.598

12.71272

173.894

181.217

30

2

29

30

1

30

219850.436

0.739

12.41966

153.403

160.736

1

40

2

38

40

2

39

220575.149

0.747

3.02475

278.739

286.097

1

30

2

29

30

0

30

220679.939

0.720

1.60514

153.386

160.747

0

40

2

38

40

2

39

220853.373

0.748

3.02475

278.733

286.100

0

30

2

29

30

0

30

221024.248

0.760

1.60514

153.363

160.736

1

14

2

13

13

1

12

221362.525

0.451

7.48104

32.619

40.003

1

23

0

23

22

1

22

221427.018

0.074

28.00815

84.225

91.611

0

23

0

23

22

1

22

221428.613

0.076

28.00846

84.201

91.587

1

22

1

22

21

0

21

221440.136

0.083

26.52760

76.839

84.225

0

22

1

22

21

0

21

221450.624

0.085

26.52775

76.814

84.201

1

22

2

21

21

2

20

221471.026

0.010

361.17280

82.411

89.798

0

22

2

21

21

2

20

221482.941

0.010

361.17280

82.395

89.783

0

14

2

13

13

1

12

221513.939

0.486

7.48919

32.596

39.985

1

13

2

11

12

1

11

221542.258

0.447

0.00000

28.131

35.521

1

22

5

18

21

5

16

222906.546

0.444

0.03313

106.498

113.933

1

22

4

19

21

4

17

223003.792

0.315

11.82245

96.370

103.809

0

22

7

16

21

7

15

223399.512

0.010

327.53611

133.545

140.997

0

22

7

15

21

7

14

223399.513

0.010

327.53611

133.545

140.997

0

22

8

15

21

8

14

223402.896

0.012

316.24216

150.427

157.879

0

22

8

14

21

8

13

223402.896

0.012

316.24216

150.427

157.879

1

22

7

15

21

7

14

223410.566

0.013

327.53611

133.534

140.986

1

22

8

14

21

8

13

223419.743

0.013

316.24216

150.413

157.865

1

22

7

16

21

7

15

223420.527

0.010

327.53611

133.525

140.978

1

22

8

15

21

8

14

223421.747

0.011

316.24216

150.412

157.865

0

22

9

13

21

9

12

223430.510

0.012

303.44246

169.532

176.985

0

22

9

14

21

9

13

223430.510

0.012

303.44246

169.532

176.985


Kolesniková et al.

Page 75


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

22

6

17

21

6

16

0

22

6

16

21

6

1

22

6

16

21

6

1

22

9

13

21

1

22

9

14

21

1

22

6

17

0

22

10

12

0

22

10

1

22

10

1

22

1

22

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

223432.006

0.008

337.32431

118.896

126.349

15

223432.077

0.008

337.32431

118.896

126.349

15

223435.382

0.011

337.32431

118.891

126.344

9

12

223444.377

0.013

303.44246

169.523

176.976

9

13

223450.469

0.012

303.44246

169.516

176.970

21

6

16

223452.012

0.010

337.32431

118.875

126.329

21

10

12

223476.127

0.013

337.32431

190.847

198.301

13

21

10

11

223476.127

0.013

337.32431

190.847

198.301

12

21

10

11

223482.993

0.013

289.13702

190.842

198.297

10

13

21

10

12

223496.129

0.013

289.13702

190.832

198.287

5

17

21

5

16

223520.693

0.011

345.60179

106.497

113.953

22

5

18

21

5

17

223524.239

0.008

345.60510

106.494

113.950

22

5

17

21

5

16

223527.706

0.008

345.60510

106.494

113.950

1

22

11

11

21

11

10

223534.872

0.017

273.32416

214.358

221.814

0

22

11

12

21

11

11

223535.935

0.016

273.32416

214.358

221.814

0

22

11

11

21

11

10

223535.935

0.016

273.32416

214.358

221.814

1

22

5

18

21

5

17

223541.762

0.010

345.60179

106.476

113.933

1

22

11

12

21

11

11

223552.955

0.017

273.32416

214.346

221.803

1

22

12

10

21

12

9

223598.574

0.027

256.00556

240.053

247.511

1

22

3

20

21

3

19

223602.096

0.011

357.50036

88.460

95.919

0

22

3

20

21

3

19

223605.764

0.009

357.60306

88.453

95.912

0

22

12

11

21

12

9

223607.294

0.022

357.60306

240.051

247.510

0

22

12

10

21

12

10

223607.294

0.022

357.60306

240.051

247.510

1

22

12

11

21

12

10

223618.779

0.024

256.00556

240.044

247.503

1

22

13

9

21

13

8

223673.228

0.042

237.18286

267.913

275.374

0

22

13

9

21

13

8

223688.202

0.032

237.18286

267.911

275.372

0

22

13

10

21

13

9

223688.202

0.032

237.18286

267.911

275.372

1

22

13

10

21

13

9

223692.438

0.036

237.18286

267.908

275.370

0

22

4

19

21

4

18

223698.700

0.008

352.37518

96.355

103.817

1

22

4

19

21

4

18

223738.288

0.012

350.71041

96.346

103.809

1

22

4

18

21

4

17

223755.280

0.014

350.71041

96.370

103.834

1

22

14

9

21

14

7

223758.148

0.059

350.71041

297.920

305.384

1

22

14

8

21

14

8

223773.440

0.055

350.71041

297.920

305.384

0

22

14

9

21

14

8

223777.076

0.050

216.85276

297.919

305.383

0

22

14

8

21

14

7

223777.076

0.050

216.85276

297.919

305.383

0

22

4

18

21

4

17

223799.692

0.008

352.37518

96.363

103.828

1

22

15

8

21

15

7

223852.640

0.081

195.01691

330.059

337.526

1

22

15

7

21

15

6

223861.729

0.080

195.01691

330.060

337.527

0

22

15

7

21

15

6

223872.667

0.077

195.01691

330.057

337.525

0

22

15

8

21

15

7

223872.667

0.077

195.01691

330.057

337.525

1

22

16

6

21

16

5

223955.923

0.110

171.67531

364.308

371.778

1

22

16

7

21

16

6

223957.494

0.114

171.67531

364.307

371.777


Kolesniková et al.

Page 76


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

22

16

7

21

16

6

0

22

16

6

21

16

1

22

17

6

21

17

1

22

17

5

21

0

22

17

5

21

0

22

17

6

21

1

22

5

17

21

1

22

18

5

1

22

18

4

0

22

18

0

22

18

1

22

0

22

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

223974.053

0.111

171.67531

364.307

371.778

5

223974.053

0.111

171.67531

364.307

371.778

5

224060.991

0.157

146.82796

400.639

408.113

17

4

224067.115

0.147

146.82796

400.646

408.120

17

5

224080.637

0.153

146.82796

400.644

408.119

17

4

224080.637

0.153

146.82796

400.644

408.119

5

17

224155.909

0.444

146.82796

106.476

113.953

21

18

4

224172.409

0.209

120.47320

439.035

446.513

21

18

3

224185.273

0.196

120.47320

439.049

446.527

5

21

18

4

224192.154

0.203

120.47320

439.048

446.526

4

21

18

3

224192.154

0.203

120.47320

439.048

446.526

19

4

21

19

3

224291.763

0.270

92.61436

479.474

486.956

19

4

21

19

2

224308.639

0.264

92.61436

479.491

486.973

22

19

3

21

19

3

224308.639

0.264

92.61436

479.491

486.973

22

19

3

21

19

2

224309.448

0.257

92.61436

479.493

486.975

1

22

20

3

21

20

2

224418.852

0.340

63.24810

521.931

529.417

0

22

20

3

21

20

1

224430.365

0.338

59.37904

521.946

529.432

0

22

20

2

21

20

2

224430.365

0.338

59.37904

521.946

529.432

1

22

20

2

21

20

1

224438.756

0.332

63.24810

521.952

529.438

1

22

4

18

21

4

18

224489.777

0.316

59.35074

96.346

103.834

1

22

21

2

21

21

1

224553.249

0.421

32.37775

566.381

573.871

0

22

21

2

21

21

1

224557.741

0.426

32.37775

566.385

573.875

0

22

21

1

21

21

0

224557.741

0.426

32.37775

566.385

573.875

1

22

21

1

21

21

0

224572.452

0.420

32.37775

566.397

573.888

1

22

3

19

21

3

18

225025.723

0.012

357.52521

88.623

96.129

0

22

3

19

21

3

18

225043.528

0.012

357.62957

88.614

96.121

1

22

1

21

21

1

20

225313.967

0.016

363.00156

80.711

88.227

1

40

2

38

40

1

39

225327.482

0.755

26.24683

278.581

286.097

0

22

1

21

21

1

20

225334.936

0.016

363.00156

80.695

88.211

1

23

1

23

22

1

22

225493.297

0.017

380.00874

84.225

91.747

0

23

1

23

22

1

22

225497.951

0.017

380.00874

84.200

91.722

0

40

2

38

40

1

39

225594.600

0.763

26.24130

278.575

286.100

1

23

0

23

22

0

22

226223.282

0.017

380.13629

84.065

91.611

0

23

0

23

22

0

22

226229.203

0.017

380.13629

84.041

91.587

1

31

2

30

31

1

31

226771.130

0.707

12.46871

163.524

171.088

1

11

2

10

10

1

10

227026.477

0.555

0.00000

19.268

26.841

0

31

2

30

31

1

31

227125.891

0.745

12.46917

163.501

171.077

1

23

3

21

22

3

19

227459.037

0.063

0.93592

96.129

103.716

1

9

2

8

8

0

8

227715.157

0.723

0.00000

12.151

19.747

1

22

2

20

21

2

19

227733.617

0.014

361.53722

83.708

91.304

1

31

2

30

31

0

31

227745.801

0.724

1.62833

163.491

171.088

0

22

2

20

21

2

19

227756.116

0.015

361.53888

83.694

91.291


Kolesniková et al.

Page 77


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

33

1

32

33

1

33

227888.418

0

31

2

30

31

0

31

1

15

2

14

14

1

13

0

33

1

32

33

1

0

15

2

14

14

1

0

26

1

25

25

1

26

1

25

25

1

33

1

32

0

33

1

32

1

9

2

0

9

2

1

22

1

23

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.596

1.70784

184.684

192.286

228099.635

0.764

1.62833

163.468

171.077

228221.732

0.443

8.10761

37.447

45.060

33

228269.616

0.603

1.70784

184.662

192.276

13

228363.044

0.478

8.11269

37.426

45.043

2

24

228474.433

0.350

17.87183

113.928

121.549

2

24

228484.553

0.304

17.87122

113.942

121.563

33

0

33

228556.149

0.608

12.70350

184.662

192.286

33

0

33

228936.323

0.615

12.70304

184.640

192.276

7

8

0

8

229632.484

0.676

0.08945

12.151

19.811

7

8

0

8

229836.705

0.748

0.09276

12.123

19.790

3

19

21

3

19

229886.949

0.072

0.00000

88.461

96.129

1

23

22

0

22

230289.561

0.075

28.10502

84.065

91.747

23

1

23

22

0

22

230298.540

0.077

28.10533

84.040

91.722

14

2

12

13

1

12

230851.838

0.442

0.00000

32.619

40.319

1

11

2

9

10

1

10

230935.784

0.541

3.66133

19.269

26.972

0

11

2

9

10

1

10

231130.872

0.599

3.68947

19.242

26.952

1

23

2

22

22

2

21

231380.584

0.010

377.83543

89.798

97.516

0

23

2

22

22

2

21

231392.912

0.010

377.83709

89.784

97.502

1

41

2

39

41

2

40

231612.434

0.843

3.02972

292.314

300.040

1

24

0

24

23

1

23

231737.724

0.067

29.60680

91.746

99.476

0

24

0

24

23

1

23

231740.359

0.069

29.60710

91.722

99.452

0

41

2

39

41

2

40

231896.658

0.846

3.02972

292.308

300.043

1

23

5

19

22

5

17

233113.840

0.441

0.00828

113.953

121.729

1

23

4

20

22

4

18

233191.388

0.299

0.01656

103.835

111.613

0

23

8

15

22

8

14

233558.336

0.012

334.90252

157.879

165.670

0

23

8

16

22

8

15

233558.336

0.012

334.90252

157.879

165.670

0

23

7

17

22

7

16

233559.500

0.010

345.70615

140.996

148.787

0

23

7

16

22

7

15

233559.502

0.010

345.70615

140.996

148.787

1

23

7

16

22

7

15

233570.848

0.014

345.70615

140.986

148.777

1

23

8

15

22

8

14

233575.724

0.013

334.90252

157.865

165.656

1

23

8

16

22

8

15

233577.937

0.011

334.90252

157.865

165.656

1

23

7

17

22

7

16

233581.313

0.010

345.70615

140.978

148.769

0

23

9

15

22

9

14

233583.997

0.012

322.65940

176.984

184.776

0

23

9

14

22

9

13

233583.997

0.012

322.65940

176.984

184.776

1

23

9

14

22

9

13

233598.447

0.013

322.65940

176.976

184.768

0

23

6

18

22

6

17

233600.812

0.009

355.06698

126.349

134.141

0

23

6

17

22

6

16

233600.928

0.009

355.06698

126.349

134.141

1

23

6

17

22

6

16

233604.172

0.011

355.06698

126.344

134.136

1

23

9

15

22

9

14

233604.637

0.012

322.65940

176.970

184.762

1

23

6

18

22

6

17

233621.554

0.010

355.06698

126.328

134.121

0

23

10

13

22

10

13

233629.387

0.013

355.06698

198.301

206.094


Kolesniková et al.

Page 78


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

23

10

14

22

10

12

1

23

10

13

22

10

1

23

10

14

22

10

1

23

11

12

22

0

23

11

13

22

0

23

11

12

1

23

5

18

1

23

11

0

23

5

0

23

1

23

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

233629.387

0.013

355.06698

198.301

206.094

12

233636.584

0.013

308.97514

198.298

206.091

13

233650.094

0.013

308.97514

198.286

206.080

11

11

233689.169

0.017

293.85139

221.814

229.609

11

11

233690.195

0.017

293.85139

221.814

229.609

22

11

12

233690.195

0.017

293.85139

221.814

229.609

22

5

17

233706.058

0.011

362.98003

113.953

121.749

13

22

11

12

233707.832

0.017

293.85139

221.802

229.598

19

22

5

18

233709.141

0.008

362.98831

113.950

121.746

5

18

22

5

17

233714.316

0.008

362.98831

113.950

121.746

5

19

22

5

18

233727.987

0.011

362.98003

113.933

121.729

23

3

21

22

3

20

233743.891

0.010

374.39490

95.919

103.716

23

3

21

22

3

20

233749.888

0.009

374.45122

95.912

103.709

1

23

12

11

22

12

10

233754.504

0.028

277.28483

247.512

255.309

0

23

12

11

22

12

10

233763.471

0.023

277.28483

247.509

255.307

0

23

12

12

22

12

11

233763.471

0.023

277.28483

247.509

255.307

1

23

12

12

22

12

11

233775.394

0.026

277.28483

247.503

255.301

1

23

13

10

22

13

9

233831.554

0.044

259.28044

275.373

283.173

0

23

13

11

22

13

10

233847.007

0.034

259.28044

275.372

283.172

0

23

13

10

22

13

9

233847.007

0.034

259.28044

275.372

283.172

1

23

13

11

22

13

10

233851.440

0.038

259.28044

275.370

283.170

0

23

4

20

22

4

19

233902.156

0.009

369.46187

103.817

111.619

1

23

14

10

22

14

9

233919.525

0.063

239.83325

305.384

313.187

1

23

14

9

22

14

8

233935.371

0.058

239.83490

305.385

313.188

0

23

14

10

22

14

8

233939.075

0.054

239.83490

305.384

313.187

0

23

14

9

22

14

9

233939.075

0.054

239.83490

305.384

313.187

1

23

4

20

22

4

19

233942.877

0.016

366.88272

103.810

111.613

1

23

4

19

22

4

18

233993.008

0.016

366.88272

103.834

111.639

1

23

15

9

22

15

8

234017.639

0.086

218.94822

337.526

345.332

1

23

15

8

22

15

7

234027.070

0.085

218.94822

337.528

345.334

0

23

15

9

22

15

7

234038.327

0.082

218.94822

337.525

345.332

0

23

15

8

22

15

8

234038.327

0.082

218.94822

337.525

345.332

0

23

4

19

22

4

18

234039.220

0.008

369.46187

103.827

111.634

1

23

16

7

22

16

6

234125.040

0.116

196.62039

371.778

379.588

1

23

16

8

22

16

7

234126.688

0.120

196.62039

371.777

379.587

0

23

16

8

22

16

6

234143.767

0.118

196.62039

371.778

379.588

0

23

16

7

22

16

7

234143.767

0.118

196.62039

371.778

379.588

1

32

2

31

32

1

32

234156.105

0.715

12.51099

173.943

181.754

1

23

17

7

22

17

6

234234.466

0.166

172.85308

408.113

415.926

1

23

17

6

22

17

5

234240.782

0.156

172.85308

408.121

415.934

0

23

17

6

22

17

6

234254.750

0.161

0.41909

408.119

415.933

0

23

17

7

22

17

5

234254.750

0.161

0.41909

408.119

415.933


Kolesniková et al.

Page 79


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

23

5

18

22

5

18

234320.205

1

23

18

6

22

18

5

1

23

18

5

22

18

4

0

23

18

6

22

18

0

23

18

5

22

18

1

23

19

5

22

0

23

19

4

22

0

23

19

5

1

23

19

4

0

32

2

31

1

23

20

4

0

23

20

0

23

20

1

23

1

23

1 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.441

1.89337

113.933

121.749

234350.577

0.220

147.64627

446.514

454.331

234363.865

0.207

147.64627

446.527

454.345

5

234370.977

0.214

147.64627

446.526

454.344

4

234370.977

0.214

147.64627

446.526

454.344

19

4

234475.024

0.284

120.99666

486.956

494.777

19

4

234492.465

0.278

120.99666

486.973

494.795

22

19

3

234492.465

0.278

120.99666

486.973

494.795

22

19

3

234493.288

0.271

120.99666

486.975

494.797

32

1

32

234520.616

0.752

12.51160

173.921

181.744

22

20

3

234607.584

0.357

92.90921

529.417

537.243

3

22

20

2

234619.481

0.355

92.90921

529.432

537.258

4

22

20

3

234619.481

0.355

92.90921

529.432

537.258

20

3

22

20

2

234628.128

0.349

92.90921

529.438

537.264

4

19

22

4

19

234744.496

0.301

0.00000

103.809

111.639

23

21

3

22

21

2

234747.800

0.443

63.37896

573.871

581.701

23

21

3

22

21

1

234752.435

0.448

63.37896

573.876

581.706

0

23

21

2

22

21

2

234752.435

0.448

63.37896

573.876

581.706

1

23

21

2

22

21

1

234767.606

0.442

63.37896

573.888

581.719

0

23

22

2

22

22

1

234891.759

0.556

32.41088

620.275

628.110

0

23

22

1

22

22

0

234891.759

0.556

32.41088

620.275

628.110

1

23

22

2

22

22

1

234895.016

0.544

32.41088

620.287

628.122

1

16

2

15

15

1

14

234902.965

0.434

8.77677

42.616

50.452

1

23

22

1

22

22

0

234911.163

0.550

32.41088

620.299

628.135

1

32

2

31

32

0

32

234963.474

0.730

1.64821

173.916

181.754

0

16

2

15

15

1

14

235034.533

0.470

8.77985

42.595

50.435

1

24

1

24

23

1

23

235172.409

0.017

396.58358

91.746

99.591

1

23

1

22

22

1

21

235176.425

0.016

379.49358

88.227

96.072

0

24

1

24

23

1

23

235177.068

0.017

396.58358

91.722

99.567

0

23

1

22

22

1

21

235197.416

0.016

379.49358

88.211

96.056

0

32

2

31

32

0

32

235326.989

0.768

1.64821

173.894

181.744

1

23

3

20

22

3

19

235485.565

0.012

374.43466

96.129

103.984

0

23

3

20

22

3

19

235502.617

0.013

374.49098

96.121

103.977

1

41

2

39

41

1

40

235649.344

0.844

26.09630

292.180

300.040

1

24

0

24

23

0

23

235804.003

0.017

396.68463

91.610

99.476

0

24

0

24

23

0

23

235809.696

0.017

396.68463

91.586

99.452

1

24

3

22

23

3

20

235849.484

0.068

0.00000

103.984

111.851

0

41

2

39

41

1

40

235922.865

0.853

26.09092

292.173

300.043

1

34

1

33

34

1

34

237295.986

0.616

1.71447

195.747

203.662

0

34

1

33

34

1

34

237688.819

0.623

1.71447

195.725

203.653

1

34

1

33

34

0

34

237847.431

0.627

12.69919

195.728

203.662

1

23

2

21

22

2

20

238150.576

0.014

378.23630

91.304

99.248


Kolesniková et al.

Page 80


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

23

2

21

22

2

20

0

34

1

33

34

0

1

10

2

9

9

0

1

24

1

24

23

0

24

1

24

23

1

12

2

11

1

15

2

13

1

10

2

1

24

2

0

24

2

0

10

2

1

17

0

17

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

238174.013

0.015

378.23630

91.291

99.236

34

238239.244

0.634

12.69873

195.706

203.653

9

238392.645

0.712

13.66573

15.174

23.126

0

23

239238.688

0.068

29.68414

91.611

99.591

0

23

239246.405

0.070

29.68429

91.587

99.567

11

1

11

239952.059

0.559

0.00000

22.889

30.893

14

1

13

240411.750

0.436

0.00000

37.448

45.467

8

9

0

9

241159.174

0.681

0.11761

15.174

23.218

23

23

2

22

241271.944

0.010

394.48647

97.516

105.564

23

23

2

22

241284.636

0.011

394.48647

97.502

105.550

8

9

0

9

241383.044

0.748

0.11927

15.146

23.198

2

16

16

1

15

241423.734

0.425

9.49360

48.125

56.178

2

16

16

1

15

241545.749

0.462

9.49560

48.104

56.161

27

1

26

26

2

25

241616.988

0.334

19.33732

122.635

130.694

27

1

26

26

2

25

241620.470

0.287

19.33655

122.647

130.707

1

33

2

32

33

1

33

241648.925

0.723

12.54743

184.684

192.745

1

23

3

20

22

3

20

241770.419

0.072

0.17890

95.919

103.984

1

25

0

25

24

1

24

241952.359

0.061

31.20129

99.591

107.662

0

25

0

25

24

1

24

241955.815

0.063

31.20159

99.567

107.638

0

33

2

32

33

1

33

242023.258

0.759

12.54789

184.662

192.735

1

33

2

32

33

0

33

242316.656

0.737

1.66643

184.662

192.745

1

42

2

40

42

2

41

242538.714

0.951

3.03800

306.210

314.300

0

33

2

32

33

0

33

242689.965

0.774

1.66643

184.640

192.735

0

42

2

40

42

2

41

242827.851

0.955

3.03800

306.204

314.304

1

24

5

20

23

5

18

243325.354

0.438

27.15586

121.749

129.865

1

24

4

21

23

4

19

243343.841

0.272

27.15586

111.640

119.757

0

24

8

17

23

8

16

243713.856

0.012

353.38895

165.670

173.799

0

24

8

16

23

8

15

243713.856

0.012

353.38895

165.670

173.799

0

24

7

18

23

7

17

243720.192

0.011

363.74036

148.787

156.917

0

24

7

17

23

7

16

243720.195

0.011

363.74036

148.787

156.917

1

24

8

16

23

8

15

243731.756

0.014

353.38895

165.657

173.787

1

24

7

17

23

7

16

243731.806

0.014

363.74036

148.777

156.907

1

24

8

17

23

8

16

243734.189

0.012

353.38895

165.656

173.786

0

24

9

16

23

9

15

243737.142

0.012

341.65438

184.776

192.906

0

24

9

15

23

9

14

243737.142

0.012

341.65438

184.776

192.906

1

24

7

18

23

7

17

243742.779

0.010

363.74201

148.769

156.899

1

24

9

15

23

9

14

243752.166

0.013

341.65438

184.768

192.899

1

24

9

16

23

9

15

243758.434

0.012

341.65438

184.762

192.893

0

24

6

19

23

6

18

243771.296

0.009

372.71356

134.141

142.272

0

24

6

18

23

6

17

243771.482

0.009

372.71356

134.141

142.272

1

24

6

18

23

6

17

243774.628

0.012

372.71191

134.137

142.268

0

24

10

15

23

10

13

243782.001

0.014

372.71191

206.094

214.226


Kolesniková et al.

Page 81


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

24

10

14

23

10

14

1

24

10

14

23

10

1

24

6

19

23

6

1

24

10

15

23

1

24

11

13

23

0

24

11

14

0

24

11

13

1

24

11

1

25

3

1

24

0

24

1 0 0 1 1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

243782.001

0.014

372.71191

206.094

214.226

13

243789.529

0.013

328.54160

206.091

214.223

18

243792.757

0.010

372.71356

134.121

142.253

10

14

243803.386

0.013

328.54160

206.081

214.213

11

12

243842.604

0.018

314.04731

229.609

237.743

23

11

12

243843.584

0.018

314.04731

229.609

237.743

23

11

13

243843.584

0.018

314.04731

229.609

237.743

14

23

11

13

243861.816

0.018

314.04731

229.599

237.733

23

24

3

21

243870.949

0.076

314.04731

112.188

120.323

3

22

23

3

21

243876.012

0.010

391.24306

103.716

111.851

3

22

23

3

21

243883.777

0.010

391.27453

103.709

111.844

24

5

19

23

5

18

243894.877

0.012

380.28207

121.749

129.884

24

5

20

23

5

19

243897.126

0.008

380.30194

121.745

129.881

24

5

19

23

5

18

243904.712

0.008

380.30194

121.746

129.882

24

12

12

23

12

11

243909.405

0.030

298.17151

255.309

263.445

24

5

20

23

5

19

243917.572

0.011

380.28372

121.729

129.865

24

12

12

23

12

11

243918.602

0.025

298.17151

255.308

263.444

0

24

12

13

23

12

12

243918.602

0.025

298.17151

255.308

263.444

1

24

12

13

23

12

12

243930.951

0.027

298.17151

255.300

263.437

1

24

13

11

23

13

10

243988.722

0.046

280.91586

283.173

291.312

0

24

13

12

23

13

11

244004.628

0.037

280.91586

283.172

291.311

0

24

13

11

23

13

10

244004.628

0.037

280.91586

283.172

291.311

1

24

13

12

23

13

11

244009.257

0.041

280.91751

283.170

291.309

1

24

14

11

23

14

10

244079.638

0.066

262.28034

313.187

321.329

1

24

14

10

23

14

9

244096.018

0.061

262.28034

313.188

321.330

0

24

14

11

23

14

9

244099.779

0.057

262.28034

313.187

321.329

0

24

14

10

23

14

10

244099.779

0.057

262.28034

313.187

321.329

0

24

4

21

23

4

20

244107.766

0.009

386.50550

111.618

119.761

1

24

4

21

23

4

20

244145.461

0.020

383.32504

111.613

119.757

1

24

15

10

23

15

9

244181.285

0.091

242.26498

345.332

353.477

1

24

15

9

23

15

8

244191.046

0.089

242.26498

345.334

353.479

0

24

15

10

23

15

8

244202.602

0.087

242.26498

345.332

353.478

0

24

15

9

23

15

9

244202.602

0.087

242.26498

345.332

353.478

1

24

4

20

23

4

19

244247.174

0.020

383.32504

111.640

119.787

0

24

4

20

23

4

19

244291.091

0.009

386.50550

111.634

119.783

1

24

16

8

23

16

7

244292.728

0.123

220.86809

379.588

387.737

1

24

16

9

23

16

8

244294.453

0.127

220.86809

379.587

387.736

0

24

16

8

23

16

8

244312.024

0.125

2.25448

379.588

387.737

0

24

16

9

23

16

7

244312.024

0.125

2.25448

379.588

387.737

1

24

17

8

23

17

7

244406.456

0.174

198.09136

415.926

424.079

1

24

17

7

23

17

6

244412.955

0.165

198.09136

415.933

424.086

0

24

17

7

23

17

7

244427.346

0.170

14.58383

415.934

424.087


Kolesniková et al.

Page 82


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

24

17

8

23

17

6

1

24

5

19

23

5

1

24

18

7

23

18

1

24

18

6

23

0

24

18

6

23

0

24

18

7

1

24

19

6

0

24

19

0

24

19

1

24

1

24

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

244427.346

0.170

14.58383

415.934

424.087

19

244487.096

0.438

0.00000

121.729

129.884

6

244527.212

0.232

173.93311

454.330

462.487

18

5

244540.904

0.218

173.93311

454.345

462.502

18

5

244548.236

0.225

173.93311

454.344

462.501

23

18

6

244548.236

0.225

173.93311

454.344

462.501

23

19

5

244656.709

0.298

148.39666

494.777

502.938

5

23

19

5

244674.688

0.292

148.39666

494.795

502.956

6

23

19

4

244674.688

0.292

148.39666

494.795

502.956

19

5

23

19

4

244675.525

0.285

148.39666

494.797

502.958

20

5

23

20

4

244794.699

0.375

121.47704

537.244

545.409

24

20

5

23

20

4

244806.961

0.373

121.47704

537.258

545.424

24

20

4

23

20

3

244806.961

0.373

121.47704

537.258

545.424

1

24

20

4

23

20

3

244815.852

0.367

121.47704

537.264

545.430

1

25

1

25

24

1

24

244843.875

0.017

413.15677

99.591

107.758

0

25

1

25

24

1

24

244848.526

0.017

413.15677

99.567

107.734

1

24

21

4

23

21

3

244940.698

0.465

93.17922

581.701

589.871

0

24

21

3

23

21

3

244945.464

0.470

93.17922

581.705

589.876

0

24

21

4

23

21

2

244945.464

0.470

93.17922

581.705

589.876

1

24

21

3

23

21

2

244961.074

0.465

93.17922

581.719

589.890

1

24

1

23

23

1

22

244988.183

0.017

395.97731

96.072

104.244

0

24

1

23

23

1

22

245009.073

0.017

395.97731

96.055

104.228

1

24

4

20

23

4

20

245048.794

0.274

395.97731

111.613

119.787

0

24

22

2

23

22

1

245090.636

0.583

63.49989

628.110

636.285

0

24

22

3

23

22

2

245090.636

0.583

63.49989

628.110

636.285

1

24

22

3

23

22

2

245094.012

0.571

63.49989

628.122

636.297

1

24

22

2

23

22

1

245110.607

0.577

63.49989

628.135

636.311

0

24

23

2

23

23

1

245242.816

0.714

32.44070

676.444

684.624

0

24

23

1

23

23

0

245242.816

0.714

32.44070

676.444

684.624

1

24

23

2

23

23

1

245253.799

0.697

32.44070

676.473

684.654

1

24

23

1

23

23

0

245264.142

0.706

32.44070

676.480

684.661

1

12

2

10

11

1

11

245336.710

0.556

3.61874

22.888

31.072

1

25

0

25

24

0

24

245387.043

0.017

413.23793

99.477

107.662

0

25

0

25

24

0

24

245392.524

0.017

413.23793

99.453

107.638

0

12

2

10

11

1

11

245546.155

0.610

3.63304

22.863

31.054

1

42

2

40

42

1

41

245960.440

0.946

25.97637

306.096

314.300

1

24

3

21

23

3

20

245975.484

0.013

391.29938

103.983

112.188

0

24

3

21

23

3

20

245992.399

0.014

391.33085

103.977

112.182

0

42

2

40

42

1

41

246239.385

0.957

25.97129

306.090

314.304

1

35

1

34

35

1

35

246589.970

0.639

1.72275

207.130

215.355

0

35

1

34

35

1

35

246993.960

0.645

1.72275

207.107

215.346

1

35

1

34

35

0

35

247044.774

0.648

12.69858

207.114

215.355


Kolesniková et al.

Page 83


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

35

1

34

35

0

35

1

18

2

17

17

1

0

18

2

17

17

1

1

25

1

25

24

0

25

1

25

24

1

24

2

22

0

24

2

22

1

34

2

0

34

2

1

34

0

34

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

247447.770

0.655

12.69827

207.092

215.346

16

247804.058

0.416

10.26302

53.972

62.238

16

247916.633

0.453

10.26410

53.951

62.221

0

24

248278.560

0.061

31.26294

99.476

107.758

0

24

248285.236

0.063

31.26310

99.452

107.734

23

2

21

248535.940

0.014

394.91550

99.248

107.538

23

2

21

248560.235

0.015

394.91550

99.236

107.527

33

34

1

34

249238.722

0.734

12.57849

195.746

204.060

33

34

1

34

249622.920

0.768

12.57911

195.724

204.051

2

33

34

0

34

249790.167

0.745

1.68134

195.728

204.060

2

33

34

0

34

250173.344

0.780

1.68134

195.706

204.051

16

2

14

15

1

14

250265.689

0.429

0.00000

42.617

50.965

25

2

24

24

2

23

251145.044

0.011

411.12591

105.565

113.942

0

25

2

24

24

2

23

251158.055

0.011

411.12591

105.550

113.928

1

26

3

24

25

3

22

251482.604

0.088

45.05968

120.744

129.133

1

26

0

26

25

1

25

252081.423

0.055

32.79101

107.758

116.167

0

26

0

26

25

1

25

252085.513

0.057

32.79132

107.734

116.143

1

13

2

12

12

1

12

253131.078

0.565

0.00000

26.836

35.280

1

11

2

9

10

0

10

253158.392

0.686

0.14743

18.528

26.972

0

11

2

9

10

0

10

253395.624

0.749

0.14908

18.500

26.952

1

25

4

22

24

4

20

253442.704

0.236

0.04141

119.787

128.241

1

25

5

21

24

5

19

253541.115

0.436

0.04141

129.884

138.341

0

25

8

17

24

8

16

253869.457

0.012

371.71967

173.800

182.268

0

25

8

18

24

8

17

253869.457

0.012

371.71967

173.800

182.268

0

25

7

19

24

7

18

253881.615

0.011

381.65861

156.916

165.385

0

25

7

18

24

7

17

253881.620

0.011

381.65861

156.916

165.385

1

25

8

17

24

8

16

253887.837

0.014

371.71967

173.786

182.255

0

25

9

16

24

9

15

253889.925

0.012

360.45554

192.906

201.375

0

25

9

17

24

9

16

253889.925

0.012

360.45554

192.906

201.375

1

25

8

18

24

8

17

253890.502

0.012

371.72133

173.786

182.255

1

25

7

18

24

7

17

253893.468

0.014

381.65861

156.907

165.376

1

25

7

19

24

7

18

253904.950

0.011

381.65861

156.900

165.369

1

25

9

16

24

9

15

253905.512

0.013

360.45719

192.899

201.368

1

25

9

17

24

9

16

253911.839

0.013

360.45719

192.892

201.362

0

25

10

16

24

10

14

253933.940

0.014

360.45719

214.226

222.696

0

25

10

15

24

10

15

253933.940

0.014

360.45719

214.226

222.696

1

25

10

15

24

10

14

253941.797

0.014

347.86787

214.222

222.693

0

25

6

20

24

6

19

253943.524

0.009

390.27236

142.272

150.743

0

25

6

19

24

6

18

253943.818

0.009

390.27236

142.272

150.743

1

25

6

19

24

6

18

253946.824

0.012

390.27070

142.267

150.738

1

25

10

16

24

10

15

253955.973

0.014

347.86787

214.213

222.684

1

25

6

20

24

6

19

253965.692

0.010

390.27236

142.254

150.725


Kolesniková et al.

Page 84


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

25

11

14

24

11

13

0

25

11

15

24

11

0

25

11

14

24

11

1

25

3

23

24

1

24

3

21

23

0

25

3

23

1

25

11

15

1

25

12

1

19

2

0

25

0

25

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

253995.137

0.019

333.95170

237.743

246.215

13

253996.062

0.019

333.95170

237.743

246.215

14

253996.062

0.019

333.95170

237.743

246.215

3

22

253996.949

0.011

408.05643

111.851

120.323

3

21

254002.012

0.077

408.05643

103.715

112.188

24

3

22

254006.097

0.010

408.07466

111.844

120.317

24

11

14

254014.867

0.019

333.95170

237.733

246.206

13

24

12

12

254063.232

0.031

318.71199

263.444

271.919

18

18

1

17

254066.576

0.406

11.08932

60.155

68.630

12

13

24

12

13

254072.642

0.026

11.08932

263.444

271.919

12

14

24

12

12

254072.642

0.026

11.08932

263.444

271.919

25

12

14

24

12

13

254085.402

0.029

318.71199

263.438

271.913

25

5

20

24

5

19

254087.368

0.013

397.50956

129.885

138.360

0

25

5

21

24

5

20

254088.245

0.009

397.55760

129.882

138.357

0

25

5

20

24

5

19

254099.182

0.009

397.55760

129.882

138.358

1

25

5

21

24

5

20

254110.638

0.012

397.51122

129.865

138.341

1

25

13

12

24

13

11

254144.680

0.049

302.14709

291.312

299.789

0

25

13

12

24

13

12

254161.013

0.039

0.06792

291.311

299.789

0

25

13

13

24

13

11

254161.013

0.039

0.06792

291.311

299.789

1

25

13

13

24

13

12

254165.836

0.043

302.14709

291.309

299.787

0

19

2

18

18

1

17

254169.799

0.444

11.08994

60.136

68.614

1

25

14

12

24

14

11

254238.431

0.070

284.25700

321.329

329.809

1

25

14

11

24

14

10

254255.325

0.065

284.25700

321.330

329.811

0

25

14

12

24

14

11

254259.133

0.061

284.25700

321.329

329.810

0

25

14

11

24

14

10

254259.133

0.061

284.25700

321.329

329.810

0

25

4

22

24

4

21

254314.929

0.009

403.50937

119.761

128.244

1

25

15

11

24

15

10

254343.519

0.096

265.04171

353.477

361.961

1

25

4

22

24

4

21

254346.038

0.023

400.47137

119.757

128.241

1

25

15

10

24

15

9

254353.599

0.094

265.04171

353.479

361.963

0

25

15

10

24

15

9

254365.433

0.092

265.04171

353.477

361.962

0

25

15

11

24

15

10

254365.433

0.092

265.04171

353.477

361.962

1

25

16

9

24

16

8

254458.926

0.130

244.50124

387.736

396.224

1

25

16

10

24

16

9

254460.726

0.133

244.50124

387.736

396.224

0

25

16

9

24

16

9

254478.761

0.132

244.50124

387.738

396.226

0

25

16

10

24

16

8

254478.761

0.132

244.50124

387.738

396.226

1

26

1

26

25

1

25

254508.319

0.017

429.72664

107.759

116.248

0

26

1

26

25

1

25

254512.952

0.017

429.72664

107.734

116.224

1

25

4

21

24

4

20

254518.697

0.023

400.47302

119.787

128.277

1

28

1

27

27

2

26

254550.952

0.270

20.85324

131.682

140.173

0

28

1

27

27

2

26

254553.377

0.317

20.85416

131.669

140.160

0

25

4

21

24

4

20

254556.821

0.009

403.51103

119.783

128.274

1

25

17

9

24

17

8

254576.896

0.183

222.63557

424.079

432.571


Kolesniková et al.

Page 85


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

25

17

8

24

17

7

0

25

17

9

24

17

0

25

17

8

24

17

1

25

5

20

24

1

25

18

8

24

1

25

18

7

24

0

25

18

7

24

0

25

18

8

24

1

25

1

24

24

0

25

1

24

1

25

19

7

0

25

19

0

25

19

1

25

1

26

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

254583.569

0.174

222.63557

424.086

432.578

7

254598.361

0.179

222.63557

424.087

432.579

8

254598.361

0.179

222.63557

424.087

432.579

5

20

254656.891

0.436

222.63557

129.866

138.360

18

7

254702.248

0.243

199.44471

462.487

470.983

18

6

254716.324

0.230

199.44471

462.502

470.998

18

6

254723.863

0.237

199.44471

462.501

470.998

18

7

254723.863

0.237

199.44471

462.501

470.998

1

23

254750.296

0.018

412.45441

104.244

112.742

24

1

23

254770.967

0.018

412.45441

104.229

112.727

24

19

6

254836.749

0.313

174.92700

502.939

511.439

7

24

19

6

254855.239

0.306

174.92700

502.956

511.457

6

24

19

5

254855.239

0.306

174.92700

502.956

511.457

19

6

24

19

5

254856.089

0.300

174.92700

502.959

511.460

0

26

25

0

25

254972.939

0.017

429.79124

107.662

116.167

26

0

26

25

0

25

254978.225

0.017

429.79124

107.638

116.143

25

20

6

24

20

5

254980.129

0.394

149.08576

545.409

553.914

0

25

20

5

24

20

4

254992.734

0.391

149.08576

545.424

553.930

0

25

20

6

24

20

5

254992.734

0.391

149.08576

545.424

553.930

1

25

20

5

24

20

4

255001.855

0.386

149.08576

545.430

553.936

1

25

21

5

24

21

4

255131.870

0.488

121.91932

589.872

598.382

0

25

21

5

24

21

4

255136.758

0.492

121.91932

589.877

598.387

0

25

21

4

24

21

3

255136.758

0.492

121.91932

589.877

598.387

1

25

21

4

24

21

3

255152.781

0.487

121.91932

589.890

598.401

0

25

22

4

24

22

3

255287.752

0.611

93.42769

636.286

644.801

0

25

22

3

24

22

2

255287.752

0.611

93.42769

636.286

644.801

1

25

22

4

24

22

3

255291.244

0.599

93.42769

636.297

644.813

1

25

22

3

24

22

2

255308.257

0.605

93.42769

636.311

644.827

1

25

4

21

24

4

21

255422.030

0.237

93.42769

119.757

128.277

0

25

23

3

24

23

2

255446.058

0.748

63.61087

684.624

693.145

0

25

23

2

24

23

1

255446.058

0.748

63.61087

684.624

693.145

1

25

23

3

24

23

2

255457.370

0.730

63.61087

684.654

693.175

1

25

23

2

24

23

1

255467.957

0.740

63.61087

684.662

693.183

0

25

24

2

24

24

1

255611.820

0.902

32.46720

734.866

743.392

0

25

24

1

24

24

0

255611.820

0.902

32.46720

734.866

743.392

1

25

24

1

24

24

0

255629.292

0.884

32.46720

734.909

743.436

1

25

24

2

24

24

1

255631.848

0.895

32.46720

734.908

743.435

1

36

1

35

36

1

36

255773.554

0.663

1.72938

218.833

227.365

1

36

1

35

36

0

36

256148.195

0.672

12.70073

218.821

227.365

0

36

1

35

36

1

36

256188.261

0.669

1.72938

218.811

227.357

1

25

3

22

24

3

21

256493.645

0.014

408.13595

112.188

120.744

0

25

3

22

24

3

21

256510.854

0.015

408.15417

112.182

120.738


Kolesniková et al.

Page 86


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

36

1

35

36

0

36

1

35

2

34

35

1

0

35

2

34

35

1

1

35

2

34

35

1

26

1

26

25

0

26

1

26

0

35

2

34

1

27

3

1

25

2

0

25

1

20

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

256561.951

0.678

12.70042

218.799

227.357

35

256915.155

0.746

12.60540

207.130

215.700

35

257309.233

0.778

12.60601

207.107

215.690

0

35

257369.959

0.756

1.69625

207.115

215.700

0

25

257399.835

0.055

32.84006

107.662

116.248

25

0

25

257405.663

0.057

32.84037

107.638

116.224

35

0

35

257763.043

0.789

1.69625

207.092

215.690

25

26

3

23

258645.467

0.101

32.43859

129.652

138.279

23

24

2

22

258886.442

0.015

411.57482

107.538

116.174

2

23

24

2

22

258911.501

0.016

411.57482

107.527

116.163

2

19

19

1

18

260236.538

0.396

11.97683

66.674

75.355

20

2

19

19

1

18

260330.511

0.435

11.97729

66.655

75.339

13

2

11

12

1

12

260363.186

0.570

3.52449

26.836

35.521

1

17

2

15

16

1

15

260453.593

0.423

0.00000

48.125

56.813

0

13

2

11

12

1

12

260585.336

0.622

3.53217

26.811

35.503

1

26

2

25

25

2

24

260999.931

0.012

427.75541

113.942

122.648

0

26

2

25

25

2

24

261013.218

0.012

427.75541

113.928

122.634

1

27

0

27

26

1

26

262134.975

0.050

34.37597

116.248

124.992

0

27

0

27

26

1

26

262139.541

0.051

34.37628

116.224

124.968

1

26

4

23

25

4

21

263469.983

0.196

0.13418

128.277

137.065

1

26

5

22

25

5

20

263761.012

0.434

2.62388

138.360

147.158

0

26

8

18

25

8

17

264025.136

0.013

389.91621

182.267

191.074

0

26

8

19

25

8

18

264025.136

0.013

389.91621

182.267

191.074

0

26

9

17

25

9

16

264042.330

0.013

379.08608

201.375

210.183

0

26

9

18

25

9

17

264042.330

0.013

379.08608

201.375

210.183

0

26

7

20

25

7

19

264043.793

0.011

399.47250

165.385

174.193

0

26

7

19

25

7

18

264043.802

0.011

399.47250

165.385

174.193

1

26

8

18

25

8

17

264043.967

0.015

389.91621

182.255

191.063

1

26

8

19

25

8

18

264046.873

0.012

389.91621

182.255

191.063

1

26

7

19

25

7

18

264055.858

0.015

399.47250

165.376

174.184

1

26

9

17

25

9

16

264058.468

0.013

379.08608

201.368

210.176

1

26

9

18

25

9

17

264064.832

0.013

379.08608

201.363

210.171

1

26

7

20

25

7

19

264067.850

0.011

399.47250

165.369

174.177

0

26

10

16

25

10

15

264085.172

0.015

366.98045

222.696

231.505

0

26

10

17

25

10

16

264085.172

0.015

366.98045

222.696

231.505

1

26

10

16

25

10

15

264093.355

0.014

366.98045

222.693

231.502

1

26

3

24

25

3

23

264105.301

0.011

424.84165

120.323

129.133

1

26

10

17

25

10

16

264107.825

0..014

366.98045

222.684

231.494

0

26

3

24

25

3

23

264115.563

0.011

424.85159

120.317

129.127

0

26

6

21

25

6

20

264117.564

0.009

407.75330

150.743

159.553

0

26

6

20

25

6

19

264118.017

0.009

407.75330

150.743

159.553

1

26

6

20

25

6

19

264120.832

0.013

407.75330

150.739

159.549


Kolesniková et al.

Page 87


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

26

6

21

25

6

20

1

26

11

15

25

11

0

26

11

16

25

11

0

26

11

15

25

1

27

1

27

26

1

26

11

16

0

27

1

27

1

26

12

0

26

12

0

26

1

26

0 1 0 1 1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

264140.431

0.011

407.75330

150.725

159.536

14

264146.726

0.020

353.60098

246.215

255.026

14

264147.588

0.020

353.60098

246.215

255.026

11

15

264147.588

0.020

353.60098

246.215

255.026

1

26

264166.336

0.017

446.29651

116.247

125.059

25

11

15

264166.943

0.021

353.60098

246.205

255.017

26

1

26

264170.940

0.018

446.29651

116.224

125.036

14

25

12

13

264215.938

0.033

338.94767

271.920

280.733

15

25

12

14

264225.542

0.029

338.94767

271.918

280.732

12

14

25

12

13

264225.542

0.029

338.94767

271.918

280.732

12

15

25

12

14

264238.699

0.031

338.94767

271.913

280.727

26

5

22

25

5

21

264282.527

0.009

414.75859

138.356

147.172

26

5

21

25

5

20

264283.803

0.014

414.64926

138.359

147.175

26

5

21

25

5

20

264298.053

0.009

414.75859

138.358

147.174

26

13

13

25

13

12

264299.375

0.051

323.01886

299.789

308.605

26

5

22

25

5

21

264307.264

0.012

414.64926

138.342

147.158

26

13

14

25

13

12

264316.111

0.043

414.64926

299.789

308.606

0

26

13

13

25

13

13

264316.111

0.043

414.64926

299.789

308.606

1

26

13

14

25

13

13

264321.125

0.046

323.01886

299.787

308.604

1

26

14

13

25

14

12

264395.849

0.074

305.81787

329.809

338.628

1

26

14

12

25

14

11

264413.232

0.068

305.81787

329.811

338.631

0

26

14

12

25

14

12

264417.080

0.065

305.81787

329.810

338.630

0

26

14

13

25

14

11

264417.080

0.065

305.81787

329.810

338.630

1

26

1

25

25

1

24

264465.032

0.018

428.92821

112.741

121.563

0

26

1

25

25

1

24

264485.377

0.018

428.92821

112.727

121.549

1

26

15

12

25

15

11

264504.281

0.102

287.34138

361.961

370.784

1

26

15

11

25

15

10

264514.668

0.099

287.34138

361.964

370.787

0

26

4

23

25

4

22

264522.940

0.009

420.48011

128.244

137.068

0

26

15

11

25

15

11

264526.760

0.098

420.48011

361.962

370.786

0

26

15

12

25

15

10

264526.760

0.098

420.48011

361.962

370.786

1

26

4

23

25

4

22

264545.975

0.023

418.16931

128.241

137.065

1

27

0

27

26

0

26

264561.872

0.017

446.34786

116.167

124.992

0

27

0

27

26

0

26

264566.979

0.018

446.34786

116.143

124.968

1

26

16

10

25

16

9

264623.572

0.138

267.59105

396.224

405.051

1

26

16

11

25

16

10

264625.445

0.140

267.59105

396.224

405.051

0

26

16

11

25

16

9

264643.913

0.139

267.59105

396.225

405.053

0

26

16

10

25

16

10

264643.913

0.139

267.59105

396.225

405.053

1

36

2

35

36

1

36

264668.474

0.760

12.62877

218.834

227.662

1

26

17

10

25

17

9

264745.722

0.192

246.56522

432.571

441.402

1

26

17

9

25

17

8

264752.559

0.183

246.56522

432.578

441.409

0

26

17

9

25

17

8

264767.728

0.189

246.56522

432.579

441.411

0

26

17

10

25

17

9

264767.728

0.189

246.56522

432.579

441.411


Kolesniková et al.

Page 88


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

26

4

22

25

4

21

1

26

5

21

25

5

0

26

4

22

25

4

1

37

1

36

37

1

26

18

9

25

1

26

18

8

25

0

26

18

8

25

0

26

18

9

1

26

19

8

0

26

19

0

26

19

1

26

1

36

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

264807.165

0.023

418.17096

128.277

137.110

21

264830.056

0.434

0.00000

138.341

147.175

21

264838.075

0.010

420.48177

128.274

137.108

1

37

264851.969

0.691

1.73600

230.858

239.693

18

8

264875.617

0.255

224.26556

470.983

479.818

18

7

264890.057

0.242

224.26556

470.998

479.834

18

7

264897.790

0.249

224.26556

470.998

479.834

25

18

8

264897.790

0.249

224.26556

470.998

479.834

25

19

7

265015.076

0.328

200.69205

511.439

520.279

7

25

19

6

265034.046

0.321

200.69205

511.457

520.298

8

25

19

7

265034.046

0.321

200.69205

511.457

520.298

19

7

25

19

6

265034.911

0.315

200.69205

511.459

520.300

2

35

36

0

36

265043.114

0.769

1.70784

218.821

227.662

36

2

35

36

1

36

265072.420

0.790

12.62923

218.811

227.653

37

1

36

37

0

37

265160.227

0.699

12.70473

230.848

239.693

1

26

20

7

25

20

6

265163.802

0.413

175.84470

553.914

562.759

0

26

20

7

25

20

5

265176.729

0.409

175.84470

553.930

562.775

0

26

20

6

25

20

6

265176.729

0.409

175.84470

553.930

562.775

1

26

20

6

25

20

5

265186.068

0.405

175.84470

553.936

562.782

0

37

1

36

37

1

37

265276.994

0.696

1.73600

230.836

239.685

1

26

21

6

25

21

5

265321.246

0.511

149.72351

598.382

607.232

1

28

3

26

27

3

24

265323.769

0.117

149.72351

138.912

147.762

0

26

21

5

25

21

4

265326.244

0.515

149.72351

598.387

607.237

0

26

21

6

25

21

5

265326.244

0.515

149.72351

598.387

607.237

1

26

21

5

25

21

4

265342.655

0.511

149.72351

598.401

607.252

0

36

2

35

36

0

36

265446.110

0.800

1.70784

218.799

227.653

0

26

22

5

25

22

3

265483.032

0.639

1.70784

644.800

653.656

0

26

22

4

25

22

4

265483.032

0.639

1.70784

644.800

653.656

1

26

22

5

25

22

4

265486.640

0.627

122.32682

644.812

653.668

1

26

22

4

25

22

3

265504.039

0.633

122.32682

644.827

653.683

0

37

1

36

37

0

37

265584.356

0.704

12.70457

230.826

239.685

0

26

23

3

25

23

3

265647.439

0.781

12.70457

693.145

702.006

0

26

23

4

25

23

2

265647.439

0.781

12.70457

693.145

702.006

1

26

23

4

25

23

3

265659.067

0.764

93.65629

693.176

702.037

1

26

23

3

25

23

2

265669.875

0.773

93.65629

693.182

702.044

1

12

2

10

11

0

11

265706.557

0.691

0.17890

22.209

31.072

0

26

24

3

25

24

1

265819.606

0.943

0.17890

743.392

752.259

0

26

24

2

25

24

2

265819.606

0.943

0.17890

743.392

752.259

1

26

24

2

25

24

1

265837.534

0.925

63.71192

743.437

752.304

1

26

24

3

25

24

2

265840.120

0.935

63.71192

743.435

752.302

1

26

4

22

25

4

22

265883.158

0.198

63.71192

128.241

137.110

0

12

2

10

11

0

11

265953.781

0.750

0.17890

22.183

31.054


Kolesniková et al.

Page 89


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

21

2

20

20

1

19

0

21

2

20

20

1

1

14

2

13

13

1

1

27

1

27

26

0

27

1

27

26

1

25

3

22

1

26

3

23

0

26

3

1

29

1

0

29

1

26

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

266341.654

0.384

12.92937

73.527

82.411

19

266426.519

0.424

12.92952

73.508

82.395

13

266564.048

0.572

0.00000

31.111

40.003

0

26

266593.233

0.049

34.41518

116.166

125.059

0

26

266598.379

0.052

34.41533

116.143

125.036

24

3

22

266619.645

0.086

2.49414

111.851

120.744

25

3

22

267036.906

0.015

424.95263

120.745

129.652

23

25

3

22

267054.706

0.017

424.96257

120.738

129.646

28

28

2

27

267259.682

0.253

22.41298

141.043

149.958

1

28

28

2

27

267267.265

0.300

22.41421

141.031

149.946

2

24

25

2

23

269199.141

0.016

428.21592

116.173

125.153

26

2

24

25

2

23

269224.859

0.016

428.21592

116.164

125.144

27

2

26

26

2

25

270836.766

0.012

444.37498

122.648

131.682

0

27

2

26

26

2

25

270850.287

0.013

444.37498

122.634

131.669

1

18

2

16

17

1

16

271011.546

0.417

0.00000

53.972

63.012

1

29

3

27

28

3

25

271486.181

0.135

0.08282

148.524

157.580

1

28

0

28

27

1

27

272122.416

0.045

35.95647

125.059

134.136

0

28

0

28

27

1

27

272127.323

0.047

35.95678

125.036

134.113

1

22

2

21

21

1

20

272411.778

0.372

13.94988

80.711

89.798

0

22

2

21

21

1

20

272487.733

0.413

13.95003

80.694

89.783

1

37

2

36

37

1

37

272489.556

0.778

12.64907

230.859

239.948

1

37

2

36

37

0

37

272797.814

0.786

1.71944

230.848

239.948

0

37

2

36

37

1

37

272903.337

0.805

12.64953

230.837

239.940

0

37

2

36

37

0

37

273210.698

0.814

1.71944

230.827

239.940

1

27

4

24

26

4

22

273409.260

0.159

1.71944

137.109

146.229

1

28

1

28

27

1

27

273818.484

0.018

462.86472

125.059

134.193

0

28

1

28

27

1

27

273823.051

0.018

462.86472

125.036

134.170

1

38

1

37

38

1

38

273831.815

0.723

1.74263

243.204

252.338

1

27

5

23

26

5

21

273984.649

0.432

0.00000

147.175

156.314

1

38

1

37

38

0

38

274085.189

0.729

12.71011

243.196

252.338

1

27

1

26

26

1

25

274135.847

0.019

445.40034

121.563

130.707

1

28

0

28

27

0

27

274153.777

0.018

462.90613

124.991

134.136

0

27

1

26

26

1

25

274155.773

0.019

445.40034

121.549

130.694

0

28

0

28

27

0

27

274158.723

0.018

462.90613

124.968

134.113

0

27

8

20

26

8

19

274180.894

0.013

407.99183

191.074

200.220

0

27

8

19

26

8

18

274180.894

0.013

407.99183

191.074

200.220

0

27

9

18

26

9

17

274194.336

0.013

397.56257

210.183

219.329

0

27

9

19

26

9

18

274194.336

0.013

397.56257

210.183

219.329

1

27

3

25

26

3

24

274199.769

0.012

441.60367

129.133

138.279

1

27

8

19

26

8

18

274200.143

0.016

407.99183

191.063

200.209

1

27

8

20

26

8

19

274203.301

0.013

407.99183

191.063

200.209

0

27

7

21

26

7

20

274206.754

0.012

417.19363

174.193

183.340


Kolesniková et al.

Page 90


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

27

7

20

26

7

19

0

27

3

25

26

3

1

27

9

18

26

9

1

27

9

19

26

1

27

7

20

26

1

27

7

21

0

27

10

18

0

27

10

1

27

10

1

27

0

38

0 0 1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

274206.769

0.012

417.19363

174.193

183.340

24

274210.950

0.012

441.61030

129.127

138.274

17

274211.012

0.014

397.56257

210.176

219.323

9

18

274217.395

0.014

397.56257

210.171

219.318

7

19

274219.002

0.015

417.19363

174.184

183.331

26

7

20

274231.504

0.011

417.19363

174.178

183.325

26

10

17

274235.665

0.015

385.90585

231.504

240.652

17

26

10

16

274235.665

0.015

385.90585

231.504

240.652

17

26

10

16

274244.173

0.015

385.90585

231.502

240.650

10

18

26

10

17

274258.907

0.015

385.90585

231.494

240.642

1

37

38

1

38

274266.799

0.727

1.74263

243.182

252.331

27

6

22

26

6

21

274293.478

0.010

425.16798

159.553

168.702

27

6

21

26

6

20

274294.165

0.010

425.16798

159.553

168.702

27

6

21

26

6

20

274296.727

0.013

425.16798

159.548

168.698

27

11

16

26

11

15

274297.333

0.021

373.02167

255.026

264.176

0

27

11

16

26

11

16

274298.124

0.022

373.02167

255.026

264.176

0

27

11

17

26

11

15

274298.124

0.022

373.02167

255.026

264.176

1

27

6

22

26

6

21

274317.047

0.011

425.16798

159.536

168.686

1

27

11

17

26

11

16

274318.003

0.022

373.02167

255.018

264.168

1

27

12

15

26

12

14

274367.476

0.035

358.91003

280.732

289.884

0

27

12

16

26

12

14

274377.256

0.031

358.91003

280.732

289.884

0

27

12

15

26

12

15

274377.256

0.031

358.91003

280.732

289.884

1

27

12

16

26

12

15

274390.795

0.033

358.91003

280.726

289.879

1

27

13

14

26

13

13

274452.757

0.054

343.57259

308.605

317.760

0

27

13

14

26

13

13

274469.868

0.046

343.57259

308.606

317.761

0

27

13

15

26

13

14

274469.868

0.046

343.57259

308.606

317.761

1

27

13

15

26

13

14

274475.069

0.049

343.57259

308.604

317.760

0

27

5

23

26

5

22

274479.971

0.010

431.91320

147.172

156.328

1

27

5

22

26

5

21

274484.563

0.015

431.66307

147.175

156.331

0

27

5

22

26

5

21

274501.697

0.009

431.91320

147.174

156.330

1

27

5

23

26

5

22

274507.440

0.013

431.66473

147.157

156.314

0

38

1

37

38

0

38

274519.338

0.734

12.71011

243.174

252.331

1

27

14

14

26

14

13

274551.833

0.078

327.00769

338.628

347.786

1

27

14

13

26

14

12

274569.684

0.073

327.00769

338.630

347.789

0

27

14

14

26

14

12

274573.562

0.070

327.00769

338.630

347.789

0

27

14

13

26

14

13

274573.562

0.070

327.00769

338.630

347.789

1

27

15

13

26

15

12

274663.513

0.108

309.21533

370.783

379.945

1

27

15

12

26

15

11

274674.191

0.105

309.21533

370.787

379.949

0

27

15

12

26

15

11

274686.521

0.104

309.21533

370.786

379.949

0

27

15

13

26

15

12

274686.521

0.104

309.21533

370.786

379.949

0

27

4

24

26

4

23

274730.987

0.010

437.41938

137.068

146.232

1

27

4

24

26

4

23

274746.442

0.021

435.92688

137.064

146.229


Kolesniková et al.

Page 91


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

27

16

11

26

16

10

1

27

16

12

26

16

0

27

16

12

26

16

0

27

16

11

26

1

27

17

11

26

1

27

17

10

26

0

27

17

10

26

0

27

17

11

26

1

27

5

22

26

1

27

18

10

1

27

18

9

0

27

18

0

27

18

1

27

0

27

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

274786.602

0.145

290.19551

405.051

414.217

11

274788.545

0.148

290.19551

405.051

414.217

11

274807.419

0.147

290.19551

405.053

414.220

16

10

274807.419

0.147

290.19551

405.053

414.220

17

10

274912.869

0.202

269.94989

441.402

450.572

17

9

274919.861

0.193

269.94989

441.410

450.580

17

10

274935.381

0.199

269.94989

441.411

450.582

17

9

274935.381

0.199

269.94989

441.411

450.582

5

22

275007.355

0.433

10.90451

147.158

156.331

26

18

9

275047.254

0.267

248.47681

479.818

488.993

26

18

8

275062.037

0.255

248.47681

479.834

489.009

10

26

18

9

275069.949

0.261

248.47681

479.835

489.010

9

26

18

8

275069.949

0.261

248.47681

479.835

489.010

4

23

26

4

22

275112.399

0.020

435.93019

137.109

146.286

4

23

26

4

22

275136.657

0.010

437.42269

137.108

146.286

27

19

9

26

19

8

275191.622

0.344

225.77627

520.279

529.458

27

19

9

26

19

8

275211.042

0.337

225.77627

520.298

529.478

0

27

19

8

26

19

7

275211.042

0.337

225.77627

520.298

529.478

1

27

19

8

26

19

7

275211.921

0.331

225.77627

520.300

529.480

1

27

20

8

26

20

7

275345.650

0.432

201.84993

562.758

571.943

0

27

20

7

26

20

7

275358.876

0.428

201.84993

562.775

571.960

0

27

20

8

26

20

6

275358.876

0.428

201.84993

562.775

571.960

1

27

20

7

26

20

6

275368.419

0.424

201.84993

562.782

571.967

1

27

21

7

26

21

6

275508.753

0.535

176.69448

607.232

616.422

0

27

21

7

26

21

6

275513.849

0.538

176.69448

607.237

616.427

0

27

21

6

26

21

5

275513.849

0.538

176.69448

607.237

616.427

1

27

21

6

26

21

5

275530.624

0.534

176.69448

607.252

616.443

0

27

22

6

26

22

4

275676.404

0.667

176.69448

653.656

662.852

0

27

22

5

26

22

5

275676.404

0.667

176.69448

653.656

662.852

1

27

22

6

26

22

5

275680.127

0.656

150.31322

653.668

662.864

1

27

22

5

26

22

4

275697.879

0.662

150.31322

653.684

662.880

0

27

23

4

26

23

3

275846.885

0.816

122.70450

702.006

711.207

0

27

23

5

26

23

4

275846.885

0.816

122.70450

702.006

711.207

1

28

1

28

27

0

27

275849.845

0.045

35.98784

124.992

134.193

0

28

1

28

27

0

27

275854.451

0.047

35.98799

124.968

134.170

1

27

23

5

26

23

4

275858.816

0.799

122.70450

702.036

711.238

1

27

23

4

26

23

3

275869.821

0.808

122.70450

702.044

711.246

0

27

24

3

26

24

2

276025.431

0.984

93.86832

752.259

761.466

0

27

24

4

26

24

3

276025.431

0.984

93.86832

752.259

761.466

1

27

24

3

26

24

2

276043.790

0.966

93.86832

752.303

761.511

1

27

24

4

26

24

3

276046.395

0.976

93.86832

752.302

761.510

1

14

2

12

13

1

13

276053.360

0.586

3.38872

31.111

40.319


Kolesniková et al.

Page 92


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

14

2

12

13

1

13

276287.604

1

27

4

23

26

4

23

1

30

3

28

29

3

26

1

27

3

24

26

3

0

27

3

24

26

3

1

23

2

22

22

0

23

2

22

22

1

13

2

11

0

13

2

11

1

27

2

0

27

2

1

26

1

30

0 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.636

3.39287

31.086

40.302

276449.581

0.161

32.51690

137.065

146.286

277106.809

0.155

0.00663

158.490

167.733

23

277600.856

0.016

441.75275

129.651

138.911

23

277619.448

0.018

441.75938

129.647

138.907

1

21

278478.395

0.360

15.04003

88.227

97.516

1

21

278545.709

0.401

15.04019

88.211

97.502

12

0

12

278878.724

0.696

0.20872

26.219

35.521

12

0

12

279134.355

0.752

0.20872

26.192

35.503

25

26

2

24

279471.310

0.016

444.83714

125.153

134.475

25

26

2

24

279497.571

0.017

444.83714

125.144

134.467

3

23

25

3

23

279659.603

0.097

0.00000

120.324

129.652

1

29

29

2

28

279735.782

0.235

24.00716

150.732

160.063

30

1

29

29

2

28

279747.773

0.282

24.00855

150.721

160.052

15

2

14

14

1

14

280250.437

0.580

0.00000

35.712

45.060

1

38

2

37

38

1

38

280369.939

0.799

12.66690

243.204

252.556

1

38

2

37

38

0

38

280623.312

0.806

1.72938

243.195

252.556

1

28

2

27

27

2

26

280655.816

0.013

460.98626

131.682

141.044

0

28

2

27

27

2

26

280669.532

0.014

460.98792

131.669

141.031

0

38

2

37

38

1

38

280793.496

0.824

12.66736

243.182

252.548

0

38

2

37

38

0

38

281046.034

0.831

1.72938

243.173

252.548

1

29

0

29

28

1

28

282052.359

0.041

37.53266

134.193

143.601

0

29

0

29

28

1

28

282057.497

0.043

37.53297

134.170

143.578

1

39

1

38

39

1

39

282720.496

0.759

1.74925

255.870

265.301

1

39

1

38

39

0

39

282928.557

0.765

12.71626

255.864

265.301

0

39

1

38

39

1

39

283165.117

0.763

1.74925

255.849

265.294

1

28

4

25

27

4

23

283244.314

0.130

1.74925

146.286

155.734

0

39

1

38

39

0

39

283372.408

0.769

12.71626

255.842

265.294

1

29

1

29

28

1

28

283465.277

0.018

479.43293

134.193

143.648

0

29

1

29

28

1

28

283469.801

0.019

479.43293

134.169

143.625

1

29

0

29

28

0

28

283748.426

0.018

479.46440

134.136

143.601

0

29

0

29

28

0

28

283753.225

0.018

479.46440

134.113

143.578

1

28

1

27

27

1

26

283767.248

0.020

461.87414

130.708

140.173

0

28

1

27

27

1

26

283786.676

0.020

461.87248

130.694

140.160

1

28

6

23

27

6

21

284126.707

0.984

0.00000

168.699

178.176

1

28

5

24

27

5

22

284211.075

0.430

0.00000

156.331

165.811

1

28

3

26

27

3

25

284279.157

0.012

458.34747

138.279

147.762

0

28

3

26

27

3

25

284291.110

0.012

458.35244

138.274

147.757

0

28

8

21

27

8

20

284336.728

0.014

425.95812

200.221

209.705

0

28

8

20

27

8

19

284336.729

0.014

425.95812

200.221

209.705

0

28

9

20

27

9

19

284345.924

0.014

415.90157

219.329

228.814

0

28

9

19

27

9

18

284345.925

0.014

415.90157

219.329

228.814


Kolesniková et al.

Page 93


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

28

8

20

27

8

19

1

28

8

21

27

8

1

28

9

19

27

9

1

28

9

20

27

0

28

7

22

27

0

28

7

21

1

28

7

21

0

28

10

0

28

10

1

28

1

28

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

284356.362

0.017

425.95812

200.209

209.694

20

284359.781

0.013

425.95812

200.209

209.694

18

284363.124

0.015

415.90157

219.323

228.808

9

19

284369.506

0.015

415.90157

219.317

228.803

7

21

284370.524

0.012

434.83194

183.339

192.825

27

7

20

284370.547

0.012

434.83194

183.339

192.825

27

7

20

284382.926

0.016

434.83194

183.331

192.817

18

27

10

17

284385.389

0.016

404.66063

240.652

250.138

19

27

10

18

284385.389

0.016

404.66063

240.652

250.138

10

18

27

10

17

284394.217

0.016

404.66229

240.651

250.137

7

22

27

7

21

284395.936

0.012

434.83194

183.325

192.811

28

10

19

27

10

18

284409.188

0.017

404.66229

240.642

250.129

28

11

17

27

11

16

284446.914

0.023

392.23861

264.176

273.664

0

28

11

17

27

11

17

284447.627

0.024

392.23861

264.176

273.664

0

28

11

18

27

11

16

284447.627

0.024

392.23861

264.176

273.664

1

28

11

18

27

11

17

284468.005

0.024

392.23861

264.167

273.656

0

28

6

23

27

6

22

284471.329

0.010

442.52136

168.702

178.191

0

28

6

22

27

6

21

284472.353

0.010

442.52136

168.702

178.191

1

28

6

22

27

6

21

284474.587

0.014

442.51971

168.698

178.187

1

28

6

23

27

6

22

284495.613

0.011

442.52136

168.686

178.176

1

28

12

16

27

12

15

284517.797

0.037

378.63055

289.885

299.375

0

28

12

16

27

12

15

284527.736

0.034

378.63055

289.884

299.375

0

28

12

17

27

12

16

284527.736

0.034

378.63055

289.884

299.375

1

28

12

17

27

12

16

284541.640

0.036

378.63055

289.880

299.371

1

24

2

23

23

1

22

284573.914

0.346

16.20061

96.072

105.564

1

28

13

16

27

13

14

284604.773

0.057

16.20061

317.761

327.254

0

28

13

15

27

13

15

284622.232

0.050

16.20061

317.761

327.255

0

28

13

16

27

13

14

284622.232

0.050

16.20061

317.761

327.255

1

28

13

15

27

13

15

284627.616

0.053

16.20061

317.760

327.254

0

24

2

23

23

1

22

284632.929

0.388

16.20077

96.056

105.550

0

28

5

24

27

5

23

284680.540

0.010

449.02474

156.328

165.824

1

28

5

23

27

5

22

284690.214

0.017

448.47810

156.331

165.827

1

28

14

15

27

14

14

284706.330

0.083

347.86787

347.786

357.283

0

28

5

23

27

5

22

284710.542

0.010

449.02474

156.330

165.827

1

28

5

24

27

5

23

284710.990

0.014

448.47810

156.314

165.811

1

28

14

14

27

14

13

284724.623

0.077

347.86787

347.790

357.287

0

28

14

15

27

14

14

284728.522

0.075

347.86787

347.789

357.287

0

28

14

14

27

14

13

284728.522

0.075

347.86787

347.789

357.287

1

28

15

14

27

15

13

284821.155

0.114

330.70995

379.945

389.446

1

28

15

13

27

15

12

284832.110

0.111

330.70995

379.949

389.450

1

28

6

22

27

6

22

284843.493

0.982

330.70995

168.686

178.187

0

28

15

14

27

15

12

284844.656

0.110

330.70995

379.949

389.450


Kolesniková et al.

Page 94


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

28

15

13

27

15

13

0

28

4

25

27

4

1

28

4

25

27

4

1

28

16

12

27

1

28

16

13

27

0

28

16

13

0

28

16

12

1

28

17

1

28

17

0

28

0

28

1 0 1 1 1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

284844.656

0.110

330.70995

379.949

389.450

24

284938.159

0.011

454.33048

146.231

155.736

24

284947.452

0.018

453.45586

146.229

155.734

16

11

284947.955

0.153

312.37095

414.217

423.722

16

12

284949.965

0.155

312.37095

414.217

423.722

27

16

11

284969.214

0.155

0.00000

414.220

423.726

27

16

12

284969.214

0.155

0.00000

414.220

423.726

12

27

17

11

285078.270

0.212

292.84755

450.572

460.081

11

27

17

10

285085.409

0.204

292.84755

450.580

460.089

17

11

27

17

11

285101.254

0.209

292.84755

450.582

460.092

17

12

27

17

10

285101.254

0.209

292.84755

450.582

460.092

29

1

29

28

0

28

285161.344

0.040

37.55773

134.136

143.648

29

1

29

28

0

28

285165.528

0.043

37.55788

134.113

143.625

28

5

23

27

5

23

285190.128

0.431

0.10933

156.314

165.827

28

18

11

27

18

10

285217.089

0.280

272.14143

488.993

498.507

35

2

33

34

3

32

285217.878

0.980

16.96726

211.685

221.199

28

18

10

27

18

9

285232.196

0.268

272.14143

489.009

498.523

0

28

18

10

27

18

10

285240.272

0.274

272.14143

489.009

498.524

0

28

18

11

27

18

9

285240.272

0.274

272.14143

489.009

498.524

1

28

19

10

27

19

9

285366.317

0.360

250.25091

529.458

538.977

0

28

19

9

27

19

8

285386.156

0.353

250.25091

529.479

538.998

0

28

19

10

27

19

9

285386.156

0.353

250.25091

529.479

538.998

1

28

19

9

27

19

8

285387.052

0.348

250.25091

529.481

539.000

1

28

4

24

27

4

23

285435.383

0.018

453.46082

146.286

155.807

0

28

4

24

27

4

23

285454.480

0.012

454.33545

146.286

155.808

1

28

20

9

27

20

8

285525.601

0.452

227.17932

571.943

581.467

0

28

20

9

27

20

8

285539.103

0.448

227.17932

571.959

581.484

0

28

20

8

27

20

7

285539.103

0.448

227.17932

571.959

581.484

1

28

20

8

27

20

7

285548.838

0.444

227.17932

571.967

581.492

1

28

21

8

27

21

7

285694.320

0.559

202.92334

616.422

625.952

0

28

21

8

27

21

7

285699.502

0.562

202.92334

616.427

625.957

0

28

21

7

27

21

6

285699.502

0.562

202.92334

616.427

625.957

1

28

21

7

27

21

6

285716.615

0.559

202.92334

616.444

625.974

0

28

22

6

27

22

6

285867.794

0.696

32.25700

662.851

672.387

0

28

22

7

27

22

5

285867.794

0.696

32.25700

662.851

672.387

1

28

22

7

27

22

6

285871.633

0.686

177.48296

662.864

672.400

1

28

22

6

27

22

5

285889.703

0.691

177.48296

662.880

672.416

0

28

23

6

27

23

4

286044.322

0.851

35.94325

711.208

720.749

0

28

23

5

27

23

5

286044.322

0.851

35.94325

711.208

720.749

1

28

23

6

27

23

5

286056.543

0.834

150.86151

711.238

720.780

1

28

23

5

27

23

4

286067.720

0.843

150.86151

711.247

720.789

1

28

4

24

27

4

24

287138.521

0.133

0.00000

146.229

155.807


Kolesniková et al.

Page 95


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

28

3

25

27

3

24

0

28

3

25

27

3

1

39

2

38

39

1

1

39

2

38

39

0

39

2

38

39

0

39

2

38

1

28

2

26

0

28

2

1

29

2

0

29

1

25

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

288179.957

0.018

458.54294

138.911

148.524

24

288199.471

0.020

458.54625

138.907

148.520

39

288301.827

0.826

12.68274

255.870

265.487

0

39

288509.888

0.832

1.73766

255.863

265.487

1

39

288735.084

0.848

12.68320

255.849

265.480

39

0

39

288942.375

0.854

1.73766

255.842

265.480

27

2

25

289700.358

0.018

461.44179

134.476

144.139

26

27

2

25

289727.038

0.018

461.44179

134.467

144.131

28

28

2

27

290457.454

0.014

477.59091

141.043

150.732

2

28

28

2

27

290471.325

0.015

477.59091

141.031

150.720

2

24

24

1

23

290730.774

0.331

17.43069

104.244

113.942

25

2

24

24

1

23

290781.911

0.374

17.43069

104.229

113.928

40

1

39

40

1

40

291525.760

0.802

1.75422

268.857

278.581

1

40

1

39

40

0

40

291696.461

0.807

12.72302

268.851

278.581

1

30

0

30

29

1

29

291932.571

0.038

39.10501

143.648

153.386

0

30

0

30

29

1

29

291937.850

0.039

39.10517

143.625

153.363

1

31

1

30

30

2

29

291973.863

0.218

25.62749

160.747

170.486

0

40

1

39

40

1

40

291979.731

0.805

1.75422

268.836

278.575

0

31

1

30

30

2

29

291989.533

0.265

25.62902

160.735

170.475

0

40

1

39

40

0

40

292149.727

0.810

12.72302

268.830

278.575

1

15

2

13

14

1

14

292440.455

0.603

3.22066

35.712

45.467

0

15

2

13

14

1

14

292686.820

0.651

3.22281

35.687

45.450

1

14

2

12

13

0

13

292745.026

0.701

0.23522

30.554

40.319

1

29

4

26

28

4

24

292957.007

0.110

0.00000

155.807

165.579

0

14

2

12

13

0

13

293008.584

0.755

0.23522

30.528

40.302

1

30

1

30

29

1

29

293107.187

0.018

495.99949

143.648

153.425

0

30

1

30

29

1

29

293111.662

0.019

495.99949

143.625

153.402

1

27

3

24

26

3

24

293155.158

0.110

495.99949

129.132

138.911

1

30

0

30

29

0

29

293345.489

0.018

496.02599

143.601

153.386

0

30

0

30

29

0

29

293350.154

0.019

496.02599

143.578

153.363

1

29

1

28

28

1

27

293364.547

0.020

478.35124

140.172

149.958

0

29

1

28

28

1

27

293383.420

0.020

478.34959

140.160

149.946

1

16

2

15

15

1

15

294188.724

0.588

0.00000

40.639

50.452

1

29

6

24

28

6

22

294328.325

0.979

2.92039

178.187

188.005

1

29

3

27

28

3

26

294342.369

0.013

475.07471

147.762

157.580

0

29

3

27

28

3

26

294354.984

0.013

475.07636

147.756

157.575

1

29

5

25

28

5

23

294438.308

0.425

26.08984

165.828

175.649

0

29

8

22

28

8

21

294492.637

0.014

443.82999

209.705

219.528

0

29

8

21

28

8

20

294492.638

0.014

443.82999

209.705

219.528

0

29

9

21

28

9

20

294497.076

0.014

434.11965

228.814

238.637

0

29

9

20

28

9

19

294497.076

0.014

434.11965

228.814

238.637

1

29

8

22

28

8

20

294512.622

0.018

434.11965

209.694

219.518


Kolesniková et al.

Page 96


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

29

8

22

28

8

21

294512.884

1

29

9

20

28

9

19

1

29

8

21

28

8

20

1

29

8

21

28

8

1

30

1

30

29

0

1

29

9

21

28

0

30

1

30

29

0

29

10

19

0

29

10

20

0

29

7

0

29

7

1

29

1

29

1 1

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.691

0.00166

209.694

219.518

294514.784

0.016

434.11965

228.808

238.632

294516.049

0.690

0.00166

209.694

219.518

21

294516.311

0.014

0.00166

209.694

219.518

29

294520.105

0.037

39.12485

143.601

153.425

9

20

294521.144

0.017

434.11965

228.803

238.627

0

29

294523.966

0.039

39.12500

143.578

153.402

28

10

18

294534.311

0.018

423.26632

250.138

259.963

28

10

19

294534.311

0.018

423.26632

250.138

259.963

23

28

7

22

294535.127

0.013

452.39736

192.825

202.650

22

28

7

21

294535.163

0.013

452.39736

192.825

202.650

10

19

28

10

18

294543.456

0.018

423.26632

250.136

259.961

7

22

28

7

21

294547.655

0.017

452.39736

192.817

202.642

29

10

20

28

10

19

294558.635

0.018

423.26632

250.129

259.954

29

7

23

28

7

22

294561.172

0.012

452.39736

192.810

202.636

1

29

11

18

28

11

17

294595.430

0.025

411.27168

273.664

283.491

0

29

11

18

28

11

17

294596.058

0.026

411.27168

273.664

283.491

0

29

11

19

28

11

18

294596.058

0.026

411.27168

273.664

283.491

1

29

11

19

28

11

18

294616.908

0.026

411.27168

273.657

283.484

0

29

6

24

28

6

23

294651.176

0.011

459.82175

178.191

188.020

0

29

6

23

28

6

22

294652.681

0.011

459.82175

178.191

188.020

1

29

6

23

28

6

22

294654.492

0.015

459.81678

178.187

188.016

1

29

12

17

28

12

16

294666.856

0.040

398.13406

299.375

309.204

1

29

6

24

28

6

23

294676.205

0.012

459.81843

178.176

188.005

0

29

12

18

28

12

17

294676.934

0.038

398.13406

299.376

309.205

0

29

12

17

28

12

16

294676.934

0.038

398.13406

299.376

309.205

1

29

12

18

28

12

17

294691.188

0.039

398.13406

299.370

309.200

1

29

13

17

28

13

16

294755.370

0.061

383.85346

327.253

337.085

0

29

13

16

28

13

15

294773.150

0.055

383.85346

327.255

337.088

0

29

13

17

28

13

16

294773.150

0.055

383.85346

327.255

337.088

1

29

13

16

28

13

15

294778.711

0.057

383.85346

327.253

337.086

1

29

14

16

28

14

15

294859.281

0.087

368.43154

357.284

367.119

1

29

14

15

28

14

14

294877.992

0.082

368.43154

357.287

367.123

0

29

14

16

28

14

15

294881.904

0.080

368.43154

357.287

367.123

0

29

14

15

28

14

14

294881.904

0.080

368.43154

357.287

367.123

0

29

5

25

28

5

24

294884.161

0.011

466.09984

165.824

175.660

1

29

5

24

28

5

23

294901.632

0.018

464.96349

165.827

175.664

1

29

5

25

28

5

24

294917.447

0.015

464.96349

165.812

175.649

0

29

5

24

28

5

23

294925.075

0.011

466.09984

165.827

175.665

1

29

15

15

28

15

14

294977.146

0.120

351.86498

389.446

399.285

1

29

15

14

28

15

13

294988.362

0.117

351.86498

389.450

399.290

0

29

15

15

28

15

14

295001.106

0.117

351.86498

389.450

399.290


Kolesniková et al.

Page 97


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

29

15

14

28

15

13

1

29

6

23

28

6

1

29

16

13

28

16

1

29

16

14

28

0

29

16

13

28

0

29

16

14

0

29

4

26

1

29

4

26

1

29

17

13

1

29

17

0

29

17

0

29

1

29

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

295001.106

0.117

351.86498

389.450

399.290

23

295002.372

0.978

351.86498

178.176

188.016

12

295107.567

0.162

334.15876

423.722

433.566

16

13

295109.641

0.164

334.15876

423.721

433.565

16

12

295129.236

0.163

334.15876

423.726

433.570

28

16

13

295129.236

0.163

334.15876

423.726

433.570

28

4

25

295143.448

0.011

471.21840

155.736

165.581

28

4

25

295148.076

0.015

470.72973

155.734

165.579

28

17

12

295241.862

0.222

315.30790

460.081

469.929

12

28

17

11

295249.139

0.215

315.30790

460.090

469.938

13

28

17

12

295265.282

0.220

315.30790

460.091

469.940

17

12

28

17

11

295265.282

0.220

315.30790

460.091

469.940

5

24

28

5

24

295380.771

0.426

0.00166

165.811

175.664

29

18

12

28

18

11

295385.058

0.293

295.31572

498.507

508.360

29

18

11

28

18

10

295400.468

0.282

295.31572

498.524

508.377

0

29

18

12

28

18

11

295408.692

0.287

295.31572

498.524

508.378

0

29

18

11

28

18

10

295408.692

0.287

295.31572

498.524

508.378

1

29

19

11

28

19

10

295539.094

0.376

274.18057

538.977

548.835

0

29

19

10

28

19

9

295559.319

0.369

274.18057

538.997

548.856

0

29

19

11

28

19

10

295559.319

0.369

274.18057

538.997

548.856

1

29

19

10

28

19

9

295560.233

0.364

274.18057

539.000

548.859

1

29

20

10

28

20

9

295703.586

0.473

251.90409

581.467

591.331

0

29

20

10

28

20

8

295717.339

0.468

251.90409

581.484

591.348

0

29

20

9

28

20

9

295717.339

0.468

251.90409

581.484

591.348

1

29

20

9

28

20

8

295727.253

0.465

251.90409

581.492

591.356

1

29

4

25

28

4

24

295778.020

0.016

470.73636

155.807

165.673

0

29

4

25

28

4

24

295793.526

0.013

471.22502

155.807

165.674

1

29

21

9

28

21

8

295877.877

0.584

228.48464

625.952

635.821

0

29

21

8

28

21

8

295883.130

0.586

228.48464

625.956

635.826

0

29

21

9

28

21

7

295883.130

0.586

228.48464

625.956

635.826

1

29

21

8

28

21

7

295900.557

0.584

228.48464

625.974

635.844

0

29

22

8

28

22

7

296057.129

0.726

203.92220

672.388

682.263

0

29

22

7

28

22

6

296057.129

0.726

203.92220

672.388

682.263

1

29

22

8

28

22

7

296061.084

0.716

203.92220

672.399

682.275

1

29

22

7

28

22

6

296079.438

0.721

203.92220

672.416

682.292

0

29

23

6

28

23

6

296239.676

0.886

0.09939

720.749

730.630

0

29

23

7

28

23

5

296239.676

0.886

0.09939

720.749

730.630

1

29

23

7

28

23

6

296252.173

0.870

178.21845

720.780

730.662

1

29

23

6

28

23

5

296263.497

0.879

178.21845

720.789

730.671

1

40

2

39

40

1

40

296278.094

0.860

12.69689

268.857

278.740

1

40

2

39

40

0

40

296448.795

0.865

1.74594

268.852

278.740

0

40

2

39

40

1

40

296720.957

0.878

12.69735

268.835

278.733


Kolesniková et al.

Page 98


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

40

2

39

40

0

40

296890.954

1

26

2

25

25

1

24

0

26

2

25

25

1

24

1

29

4

25

28

4

1

29

3

26

28

3

0

29

3

26

28

1

29

2

27

28

0

29

2

27

1

30

2

29

1

41

1

0

30

2

1

41

1

36

0 0

u(νpred) (MHz)c


S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

0.884

1.74594

268.830

278.733

296980.409

0.316

18.72751

112.742

122.648

297024.162

0.359

18.72781

112.726

122.634

25

297969.089

0.114

0.00000

155.734

165.673

25

298767.790

0.019

475.32318

148.524

158.490

3

25

298788.293

0.021

475.32484

148.519

158.486

2

26

299883.787

0.019

478.02657

144.139

154.142

28

2

26

299910.753

0.020

478.02657

144.131

154.135

29

2

28

300242.146

0.016

494.18894

150.732

160.747

40

41

1

41

300255.358

0.853

1.76085

282.164

292.179

29

29

2

28

300256.134

0.016

494.19060

150.721

160.736

1

40

41

0

41

300395.293

0.857

12.73010

282.159

292.179

2

34

35

3

33

300598.579

0.954

18.21764

223.504

233.531

41

1

40

41

1

41

300718.421

0.855

1.76085

282.142

292.173

41

1

40

41

0

41

300857.717

0.859

12.73025

282.137

292.173

1

31

0

31

30

1

30

301769.967

0.035

40.67367

153.425

163.491

0

31

0

31

30

1

30

301775.316

0.036

40.67383

153.402

163.468

1

30

4

27

29

4

25

302525.931

0.100

0.00000

165.674

175.765

1

31

1

31

30

1

30

302744.637

0.019

512.56604

153.426

163.524

0

31

1

31

30

1

30

302749.059

0.019

512.56604

153.402

163.501

1

30

1

29

29

1

28

302933.554

0.021

494.83332

149.958

160.063

1

31

0

31

30

0

30

302944.583

0.019

512.58592

153.386

163.491

0

31

0

31

30

0

30

302949.127

0.019

512.58592

153.363

163.468

0

30

1

29

29

1

28

302951.833

0.021

494.83332

149.947

160.052

1

27

2

26

26

1

25

303352.143

0.299

20.08721

121.563

131.682

0

27

2

26

26

1

25

303389.072

0.344

20.08751

121.549

131.669

1

31

1

31

30

0

30

303919.254

0.033

40.68966

153.386

163.524

0

31

1

31

30

0

30

303922.871

0.035

40.68982

153.363

163.501

1

32

1

31

31

2

30

303973.752

0.201

27.26626

171.089

181.228

0

32

1

31

31

2

30

303992.407

0.247

27.26795

171.077

181.217

1

41

2

40

41

1

41

304292.268

0.901

12.70965

282.164

292.314

1

30

3

28

29

3

27

304388.418

0.014

491.78538

157.580

167.733

0

30

3

28

29

3

27

304401.602

0.014

491.78703

157.575

167.729

1

41

2

40

41

0

41

304432.204

0.905

1.75422

282.159

292.314

1

30

6

25

29

6

23

304532.731

0.975

8.54475

188.016

198.174

0

30

9

22

29

9

21

304647.771

0.015

452.22674

238.637

248.799

0

30

9

21

29

9

20

304647.771

0.015

452.22674

238.637

248.799

0

30

8

23

29

8

22

304648.619

0.015

461.61241

219.528

229.690

0

30

8

22

29

8

21

304648.620

0.015

461.61241

219.528

229.690

1

30

5

26

29

5

24

304662.613

0.414

461.61241

175.664

185.826

1

30

9

21

29

9

20

304665.969

0.017

452.22674

238.632

248.795

1

30

8

23

29

8

22

304668.919

0.020

461.61241

219.518

229.681


Kolesniková et al.

Page 99


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

30

9

22

29

9

21

1

30

8

22

29

8

0

30

10

20

29

10

0

30

10

21

29

1

30

10

20

29

0

30

7

24

0

30

7

23

1

30

10

1

30

7

1

30

1

30

0

30

0

30

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

304672.290

0.019

452.22674

238.627

248.790

21

304672.887

0.015

461.61407

219.518

229.681

19

304682.399

0.019

441.73619

259.963

270.126

10

20

304682.399

0.019

441.73619

259.963

270.126

10

19

304691.855

0.019

441.73619

259.962

270.125

29

7

23

304700.590

0.014

469.89486

202.649

212.813

29

7

22

304700.647

0.014

469.89486

202.649

212.813

21

29

10

20

304707.215

0.020

441.73619

259.954

270.118

23

29

7

22

304713.217

0.019

469.89486

202.642

212.806

7

24

29

7

23

304727.236

0.013

469.89486

202.636

212.801

11

19

29

11

18

304742.840

0.027

430.14076

283.491

293.656

11

19

29

11

18

304743.375

0.029

430.14076

283.491

293.656

11

20

29

11

19

304743.375

0.029

430.14076

283.491

293.656

41

2

40

41

1

41

304744.628

0.917

12.71011

282.143

292.308

30

11

20

29

11

19

304764.670

0.029

430.14076

283.484

293.650

1

30

12

18

29

12

17

304814.604

0.043

417.44045

309.203

319.371

0

30

12

18

29

12

17

304824.804

0.042

417.44045

309.204

319.372

0

30

12

19

29

12

18

304824.804

0.042

417.44045

309.204

319.372

0

30

6

25

29

6

24

304833.074

0.011

477.07078

188.020

198.188

0

30

6

24

29

6

23

304835.255

0.011

477.07078

188.020

198.188

1

30

6

24

29

6

23

304836.526

0.016

477.06249

188.016

198.184

1

30

12

19

29

12

18

304839.388

0.042

417.44045

309.201

319.369

1

30

6

25

29

6

24

304858.898

0.013

477.06415

188.005

198.174

0

41

2

40

41

0

41

304883.924

0.922

1.75422

282.138

292.308

1

30

13

18

29

13

17

304904.496

0.065

403.63692

337.085

347.256

0

30

13

18

29

13

16

304922.569

0.060

403.63692

337.088

347.259

0

30

13

17

29

13

17

304922.569

0.060

403.63692

337.088

347.259

1

30

13

17

29

13

16

304928.302

0.061

403.63692

337.087

347.258

1

30

14

17

29

14

16

305010.632

0.092

388.72851

367.119

377.293

1

30

14

16

29

14

15

305029.732

0.088

388.72851

367.123

377.298

0

30

14

16

29

14

16

305033.651

0.086

388.72851

367.123

377.298

0

30

14

17

29

14

15

305033.651

0.086

388.72851

367.123

377.298

0

30

5

26

29

5

25

305090.712

0.011

483.14016

175.660

185.837

1

30

5

25

29

5

24

305120.132

0.020

480.98009

175.664

185.842

1

30

5

26

29

5

25

305125.937

0.017

480.98009

175.648

185.826

1

30

15

16

29

15

15

305131.428

0.127

372.71522

399.286

409.464

1

30

15

15

29

15

14

305142.888

0.124

372.71522

399.290

409.468

0

30

5

25

29

5

24

305145.861

0.012

483.14016

175.664

185.843

0

30

15

16

29

15

15

305155.809

0.124

372.71522

399.290

409.469

0

30

15

15

29

15

14

305155.809

0.124

372.71522

399.290

409.469

1

30

6

24

29

6

24

305162.693

0.973

3.12911

188.005

198.184

1

30

16

14

29

16

13

305265.377

0.171

355.59705

433.565

443.748


Kolesniková et al.

Page 100


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

30

16

15

29

16

14

0

30

16

15

29

16

0

30

16

14

29

16

0

30

4

27

29

1

30

4

27

29

1

30

17

14

1

30

17

13

0

30

17

0

30

17

1

30

1

30

0 0 1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

305267.509

0.172

355.59705

433.565

443.748

14

305287.419

0.172

355.59705

433.570

443.753

13

305287.419

0.172

355.59705

433.570

443.753

4

26

305345.757

0.012

488.08312

165.582

175.767

4

26

305346.944

0.014

487.81477

165.580

175.765

29

17

13

305403.579

0.233

337.37566

469.929

480.116

29

17

12

305410.985

0.226

337.37566

469.938

480.125

13

29

17

13

305427.398

0.231

337.37566

469.940

480.128

14

29

17

12

305427.398

0.231

337.37566

469.940

480.128

18

13

29

18

12

305551.092

0.307

318.04939

508.360

518.552

18

12

29

18

11

305566.784

0.296

318.04939

508.377

518.570

30

18

12

29

18

11

305575.139

0.301

318.04939

508.378

518.571

30

18

13

29

18

12

305575.139

0.301

318.04939

508.378

518.571

30

5

25

29

5

25

305583.457

0.416

318.04939

175.649

185.842

30

19

12

29

19

11

305709.884

0.393

297.61990

548.835

559.032

0

30

19

12

29

19

10

305730.460

0.386

0.00123

548.856

559.054

0

30

19

11

29

19

11

305730.460

0.386

0.00123

548.856

559.054

1

30

19

11

29

19

10

305731.396

0.382

297.61990

548.859

559.057

1

30

20

11

29

20

10

305879.534

0.494

276.08553

591.331

601.534

0

30

20

11

29

20

9

305893.512

0.489

276.08553

591.348

601.552

0

30

20

10

29

20

10

305893.512

0.489

276.08553

591.348

601.552

1

30

20

10

29

20

9

305903.595

0.486

276.08553

591.356

601.560

1

30

21

10

29

21

9

306059.351

0.610

253.44628

635.821

646.030

0

30

21

10

29

21

9

306064.661

0.611

253.44628

635.827

646.036

0

30

21

9

29

21

8

306064.661

0.611

253.44628

635.827

646.036

1

30

21

9

29

21

8

306082.377

0.609

253.44628

635.844

646.054

1

30

4

26

29

4

25

306142.571

0.016

487.82471

165.673

175.885

0

30

4

26

29

4

25

306155.786

0.015

488.09306

165.674

175.886

0

30

22

9

29

22

7

306244.336

0.756

0.00323

682.263

692.478

0

30

22

8

29

22

8

306244.336

0.756

0.00323

682.263

692.478

1

30

22

9

29

22

8

306248.409

0.747

229.70381

682.276

692.491

1

30

22

8

29

22

7

306267.010

0.752

229.70381

682.292

692.508

0

30

23

8

29

23

7

306432.874

0.922

204.85481

730.630

740.852

0

30

23

7

29

23

6

306432.874

0.922

204.85481

730.630

740.852

1

30

23

8

29

23

7

306445.634

0.907

204.85481

730.662

740.884

1

30

23

7

29

23

6

306457.077

0.915

204.85481

730.671

740.893

1

28

3

25

27

3

25

307135.346

0.126

123.68680

138.279

148.524

1

15

2

13

14

0

14

307367.520

0.707

0.25676

35.214

45.467

0

15

2

13

14

0

14

307639.227

0.759

0.25676

35.188

45.450

1

42

1

41

42

1

42

308916.788

0.913

1.76582

295.792

306.096

1

30

4

26

29

4

26

308963.584

0.106

4.52316

165.579

175.885

1

42

1

41

42

0

42

309031.416

0.917

12.73732

295.788

306.096


Kolesniková et al.

Page 101


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

30

3

27

29

3

26

0

30

3

27

29

3

0

42

1

41

42

1

0

42

1

41

42

1

16

2

14

15

0

16

2

14

1

28

2

27

0

28

2

1

31

2

1

30

0

31

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

309357.359

0.021

492.09348

158.490

168.809

26

309378.871

0.023

492.09514

158.486

168.806

42

309388.713

0.915

1.76582

295.770

306.090

0

42

309502.764

0.918

12.73748

295.766

306.090

1

15

309551.448

0.621

3.02953

40.639

50.965

15

1

15

309810.365

0.667

3.03061

40.614

50.948

27

1

26

309872.112

0.283

21.50410

130.708

141.044

27

27

1

26

309902.831

0.327

21.50472

130.694

141.031

30

30

2

29

310010.445

0.017

510.78200

160.747

171.088

2

28

29

2

27

310019.187

0.021

494.59478

154.142

164.483

2

30

30

2

29

310024.514

0.017

510.78200

160.736

171.077

30

2

28

29

2

27

310046.300

0.022

494.59478

154.135

164.477

32

0

32

31

1

31

311570.637

0.033

42.23926

163.524

173.917

0

32

0

32

31

1

31

311575.999

0.034

42.23941

163.501

173.894

1

31

4

28

30

4

26

311925.925

0.100

42.83016

175.885

186.290

1

42

2

41

42

1

42

312338.514

0.952

12.72133

295.792

306.210

1

32

1

32

31

1

31

312378.007

0.020

529.13094

163.524

173.944

0

32

1

32

31

1

31

312382.372

0.020

529.13094

163.501

173.921

1

42

2

41

42

0

42

312453.142

0.956

1.76085

295.788

306.210

1

31

1

30

30

1

29

312480.227

0.021

511.32368

160.063

170.486

0

31

1

30

30

1

29

312497.894

0.022

511.32368

160.051

170.475

1

32

0

32

31

0

31

312545.308

0.019

529.14751

163.492

173.917

0

32

0

32

31

0

31

312549.743

0.020

529.14751

163.468

173.894

0

42

2

41

42

1

42

312800.247

0.966

12.72179

295.770

306.204

0

42

2

41

42

0

42

312914.298

0.970

1.76085

295.766

306.204

1

32

1

32

31

0

31

313352.678

0.031

42.25202

163.492

173.944

0

32

1

32

31

0

31

313356.116

0.033

42.25217

163.469

173.921

1

31

3

29

30

3

28

314416.426

0.015

508.48280

167.733

178.221

0

31

3

29

30

3

28

314430.101

0.015

508.48445

167.729

178.217

1

31

6

26

30

6

24

314739.970

0.970

3.14567

198.184

208.683

0

31

9

23

30

9

22

314797.988

0.017

470.23444

248.799

259.300

0

31

9

22

30

9

21

314797.988

0.017

470.23444

248.799

259.300

0

31

8

24

30

8

23

314804.672

0.017

479.31863

229.690

240.191

0

31

8

23

30

8

22

314804.674

0.017

479.31863

229.690

240.191

1

31

9

22

30

9

21

314816.659

0.019

470.23444

248.795

259.296

1

31

9

23

30

9

22

314822.922

0.021

470.23444

248.790

259.291

1

31

8

24

30

8

23

314825.252

0.022

479.31863

229.681

240.182

1

31

8

23

30

8

22

314829.504

0.017

479.31863

229.681

240.183

0

31

10

21

30

10

20

314829.621

0.021

460.08182

270.126

280.628

0

31

10

22

30

10

21

314829.621

0.021

460.08182

270.126

280.628

1

31

10

21

30

10

20

314839.381

0.022

460.08182

270.125

280.627

1

31

10

22

30

10

21

314854.894

0.023

460.08182

270.118

280.620


Kolesniková et al.

Page 102


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

31

7

25

30

7

24

0

31

7

24

30

7

1

31

5

27

30

5

1

31

7

24

30

1

31

11

20

30

0

31

11

20

30

0

31

11

21

30

1

31

7

25

1

31

11

21

1

31

12

0

31

12

0

31

1

31

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

314866.939

0.015

487.33273

212.813

223.316

23

314867.026

0.015

487.33273

212.813

223.316

25

314877.718

0.392

487.33273

185.842

196.345

7

23

314879.637

0.021

487.33273

212.806

223.309

11

19

314889.100

0.030

448.86075

293.655

304.159

11

19

314889.538

0.032

448.86075

293.655

304.159

11

20

314889.538

0.032

448.86075

293.655

304.159

30

7

24

314894.154

0.014

487.33273

212.801

223.305

30

11

20

314911.249

0.032

448.86075

293.650

304.154

19

30

12

18

314960.993

0.046

436.56960

319.371

329.877

20

30

12

18

314971.298

0.047

3.14733

319.373

329.879

12

19

30

12

19

314971.298

0.047

3.14733

319.373

329.879

12

20

30

12

19

314986.192

0.046

436.57125

319.369

329.876

31

6

26

30

6

25

315017.073

0.012

494.27674

198.188

208.696

31

6

25

30

6

24

315020.191

0.012

494.27674

198.188

208.696

1

31

6

25

30

6

24

315020.781

0.018

494.25686

198.184

208.692

1

31

6

26

30

6

25

315043.765

0.014

494.25686

198.174

208.683

1

31

13

19

30

13

18

315052.097

0.069

423.21166

347.256

357.765

0

31

13

19

30

13

18

315070.437

0.065

423.21166

347.259

357.769

0

31

13

18

30

13

17

315070.437

0.065

423.21166

347.259

357.769

1

31

13

18

30

13

17

315076.334

0.066

423.21166

347.258

357.768

1

31

14

18

30

14

17

315160.324

0.098

408.78363

377.292

387.805

1

31

14

17

30

14

16

315179.787

0.094

408.78363

377.298

387.811

0

31

14

18

30

14

16

315183.705

0.093

408.78363

377.298

387.811

0

31

14

17

30

14

17

315183.705

0.093

408.78363

377.298

387.811

1

31

15

17

30

15

16

315283.939

0.135

393.28717

409.463

419.980

1

31

15

16

30

15

15

315295.626

0.131

393.28717

409.468

419.985

0

31

5

27

30

5

26

315300.022

0.013

500.14900

185.837

196.354

0

31

15

16

30

15

16

315308.704

0.132

500.14900

409.469

419.987

0

31

15

17

30

15

15

315308.704

0.132

500.14900

409.469

419.987

1

31

6

25

30

6

25

315324.576

0.969

500.14900

198.174

208.692

1

31

5

27

30

5

26

315335.237

0.022

496.61239

185.827

196.345

1

31

5

26

30

5

25

315347.410

0.024

496.61073

185.842

196.361

0

31

5

26

30

5

25

315373.543

0.013

500.14900

185.843

196.363

1

31

16

15

30

16

14

315421.322

0.181

376.72227

443.749

454.270

1

31

16

16

30

16

15

315423.506

0.181

376.72227

443.748

454.269

0

31

16

16

30

16

15

315443.703

0.182

376.72227

443.753

454.275

0

31

16

15

30

16

14

315443.703

0.182

376.72227

443.753

454.275

1

31

4

28

30

4

27

315542.564

0.013

504.78054

175.765

186.290

0

31

4

28

30

4

27

315543.913

0.013

504.92631

175.767

186.292

1

31

17

15

30

17

14

315563.355

0.244

359.08893

480.116

490.642

1

31

17

14

30

17

13

315570.882

0.239

359.08893

480.125

490.651


Kolesniková et al.

Page 103


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

31

17

14

30

17

14

0

31

17

15

30

17

1

31

18

14

30

18

1

31

18

13

30

0

31

18

14

30

0

31

18

13

1

33

1

32

0

33

1

1

31

5

1

37

1

31

0

31

0

31

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

315587.537

0.243

359.08893

480.128

490.655

13

315587.537

0.243

359.08893

480.128

490.655

13

315715.125

0.321

340.38550

518.552

529.083

18

12

315731.079

0.311

340.38550

518.569

529.101

18

13

315739.547

0.316

340.38550

518.571

529.103

30

18

12

315739.547

0.316

340.38550

518.571

529.103

32

2

31

315739.941

0.184

28.91657

181.754

192.286

32

32

2

31

315760.936

0.231

28.91841

181.743

192.276

26

30

5

26

315804.929

0.395

28.91841

185.827

196.361

2

35

36

3

34

315805.429

0.925

19.54120

235.655

246.189

19

13

30

19

12

315878.618

0.411

320.61530

559.032

569.569

19

13

30

19

12

315899.511

0.404

320.61530

559.055

569.592

19

12

30

19

11

315899.511

0.404

320.61530

559.055

569.592

31

19

12

30

19

11

315900.472

0.400

320.61530

559.057

569.594

31

20

12

30

20

11

316053.377

0.515

299.77500

601.534

612.076

0

31

20

12

30

20

11

316067.553

0.510

299.77500

601.552

612.095

0

31

20

11

30

20

10

316067.553

0.510

299.77500

601.552

612.095

1

31

20

11

30

20

10

316077.793

0.508

299.77500

601.561

612.104

1

31

21

11

30

21

10

316238.671

0.636

277.86626

646.030

656.579

0

31

21

10

30

21

10

316244.023

0.637

277.86626

646.035

656.584

0

31

21

11

30

21

9

316244.023

0.637

277.86626

646.035

656.584

1

31

21

10

30

21

9

316262.003

0.636

277.86626

646.054

656.603

0

31

22

9

30

22

8

316429.342

0.787

254.88909

692.478

703.033

0

31

22

10

30

22

9

316429.342

0.787

254.88909

692.478

703.033

1

31

22

10

30

22

9

316433.534

0.778

254.88909

692.491

703.046

1

31

22

9

30

22

8

316452.346

0.783

254.88909

692.508

703.064

1

31

4

27

30

4

26

316531.269

0.018

504.79545

175.886

186.444

0

31

4

27

30

4

26

316543.173

0.018

504.94288

175.886

186.445

1

29

2

28

28

1

27

316562.319

0.265

22.97159

140.173

150.732

0

29

2

28

28

1

27

316587.480

0.310

22.97221

140.160

150.720

0

31

23

8

30

23

8

316623.840

0.959

22.97221

740.852

751.413

0

31

23

9

30

23

7

316623.840

0.959

22.97221

740.852

751.413

1

31

23

9

30

23

8

316636.851

0.945

230.84348

740.884

751.446

1

31

23

8

30

23

7

316648.387

0.952

230.84348

740.893

751.455

1

43

1

42

43

1

43

317517.130

0.985

1.77079

309.739

320.330

1

43

1

42

43

0

43

317610.962

0.988

12.74455

309.736

320.330

0

43

1

42

43

1

43

317997.708

0.986

1.77079

309.718

320.325

0

43

1

42

43

0

43

318091.023

0.989

12.74486

309.715

320.325

1

32

2

31

31

2

30

319762.982

0.019

527.37010

171.088

181.754

0

32

2

31

31

2

30

319777.097

0.019

527.37010

171.077

181.744

1

31

3

28

30

3

27

319941.433

0.023

508.85551

168.809

179.481

0

31

3

28

30

3

27

319963.933

0.026

508.85716

168.806

179.479


Kolesniková et al.

Page 104


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

31

2

29

30

2

28

0

31

2

29

30

2

1

31

4

27

30

4

1

32

4

29

31

1

33

0

33

32

0

33

0

33

1

29

3

26

1

33

1

1

32

1

0

33

0

32

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

320104.269

0.023

511.14478

164.482

175.160

28

320131.382

0.024

511.14478

164.477

175.155

27

320147.908

0.109

511.14478

175.765

186.444

4

27

321128.088

0.110

0.91273

186.443

197.155

1

32

321339.896

0.032

43.80207

173.943

184.662

32

1

32

321345.228

0.033

43.80223

173.921

184.640

28

3

26

321623.979

0.144

0.16731

147.762

158.490

33

32

1

32

322007.628

0.021

545.69750

173.944

184.685

31

31

1

30

322010.334

0.022

527.82232

170.487

181.228

1

33

32

1

32

322011.935

0.022

545.69750

173.921

184.662

1

31

31

1

30

322027.387

0.022

527.82066

170.475

181.217

33

0

33

32

0

32

322147.266

0.021

545.71075

173.916

184.662

33

0

33

32

0

32

322151.601

0.022

545.71075

173.894

184.640

1

16

2

14

15

0

15

322797.711

0.715

0.27166

40.198

50.965

1

33

1

33

32

0

32

322814.997

0.029

43.81222

173.917

184.685

0

33

1

33

32

0

32

322818.308

0.031

43.81237

173.894

184.662

0

16

2

14

15

0

15

323078.242

0.765

0.27166

40.171

50.948

1

30

2

29

29

1

28

323439.918

0.248

24.48197

149.958

160.747

0

30

2

29

29

1

28

323460.194

0.293

24.48290

149.947

160.736

1

32

3

30

31

3

29

324425.629

0.016

525.16696

178.221

189.043

0

32

3

30

31

3

29

324439.725

0.016

525.16862

178.217

189.039

0

32

9

24

31

9

23

324947.708

0.019

488.15269

259.300

270.139

0

32

9

23

31

9

22

324947.708

0.019

488.15269

259.300

270.139

1

32

6

27

31

6

25

324950.060

0.965

488.15269

208.692

219.531

0

32

8

25

31

8

24

324960.793

0.019

496.95197

240.190

251.030

0

32

8

24

31

8

23

324960.795

0.019

496.95197

240.190

251.030

1

32

9

23

31

9

22

324966.831

0.022

488.15269

259.296

270.136

1

32

9

24

31

9

23

324973.018

0.024

488.15269

259.291

270.131

0

32

10

23

31

10

22

324975.945

0.024

478.31646

280.628

291.468

0

32

10

22

31

10

21

324975.945

0.024

478.31646

280.628

291.468

1

32

8

25

31

8

24

324981.616

0.025

496.95197

240.182

251.022

1

32

10

22

31

10

21

324986.001

0.025

478.31646

280.627

291.467

1

32

8

24

31

8

23

324986.159

0.019

496.95197

240.183

251.023

1

32

10

23

31

10

22

325001.638

0.026

478.31646

280.620

291.461

1

32

11

21

31

11

20

325034.169

0.033

467.44657

304.159

315.001

0

32

7

26

31

7

25

325034.198

0.016

504.71594

223.316

234.158

0

32

7

25

31

7

24

325034.330

0.016

504.71594

223.316

234.158

0

32

11

22

31

11

20

325034.504

0.036

504.71594

304.159

315.001

0

32

11

21

31

11

21

325034.504

0.036

504.71594

304.159

315.001

1

32

7

25

31

7

24

325046.942

0.023

504.71594

223.310

234.152

1

32

11

22

31

11

21

325056.602

0.035

467.44657

304.154

314.997

1

32

7

26

31

7

25

325061.951

0.016

504.71594

223.305

234.148


Kolesniková et al.

Page 105


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

32

5

28

31

5

26

1

32

12

20

31

12

0

32

12

20

31

12

0

32

12

21

31

1

32

12

21

31

1

32

13

20

0

32

6

27

1

32

6

0

32

6

0

32

0

32

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

325074.622

0.355

504.71594

196.361

207.204

19

325105.975

0.050

455.53972

329.878

340.722

20

325116.367

0.052

4.27871

329.878

340.723

12

19

325116.367

0.052

4.27871

329.878

340.723

12

20

325131.552

0.050

455.53972

329.876

340.721

31

13

19

325198.122

0.073

442.59922

357.765

368.612

31

6

26

325203.216

0.014

511.44294

208.695

219.543

26

31

6

25

325207.365

0.020

511.38994

208.692

219.540

26

31

6

25

325207.623

0.014

511.44294

208.696

219.544

13

20

31

13

18

325216.699

0.071

511.44294

357.769

368.617

13

19

31

13

19

325216.699

0.071

511.44294

357.769

368.617

32

13

19

31

13

18

325222.753

0.071

442.59922

357.768

368.616

32

6

27

31

6

26

325230.872

0.016

511.38994

208.682

219.531

1

32

14

19

31

14

18

325308.301

0.104

428.62176

387.805

398.656

1

32

14

18

31

14

17

325328.097

0.100

428.62176

387.811

398.663

0

32

14

19

31

14

17

325332.009

0.100

0.00000

387.811

398.663

0

32

14

18

31

14

18

325332.009

0..100

0.00000

387.811

398.663

1

32

15

18

31

15

17

325434.622

0.142

413.61064

419.981

430.836

1

32

15

17

31

15

16

325446.516

0.139

413.61064

419.985

430.841

0

32

15

17

31

15

16

325459.732

0.140

413.61064

419.987

430.843

0

32

15

18

31

15

17

325459.732

0.140

413.61064

419.987

430.843

1

32

6

26

31

6

26

325488.177

0.964

413.61064

208.683

219.540

0

32

5

28

31

5

27

325511.860

0.014

517.12967

196.354

207.212

1

32

5

28

31

5

27

325544.314

0.029

512.48653

196.345

207.204

1

32

16

16

31

16

15

325575.339

0.191

397.56257

454.270

465.130

1

32

16

17

31

16

16

325577.570

0.191

397.56257

454.269

465.129

1

32

5

27

31

5

26

325585.003

0.029

512.48653

196.361

207.221

0

32

16

17

31

16

16

325598.022

0.192

397.56257

454.275

465.136

0

32

16

16

31

16

15

325598.022

0.192

397.56257

454.275

465.136

0

32

5

27

31

5

26

325608.860

0.015

517.13133

196.363

207.224

1

32

17

16

31

17

15

325721.125

0.256

380.47919

490.642

501.507

1

32

17

15

31

17

14

325728.766

0.251

380.47919

490.652

501.517

1

32

4

29

31

4

28

325733.432

0.014

521.67177

186.290

197.155

0

32

4

29

31

4

28

325736.678

0.015

521.75294

186.292

197.157

0

32

17

15

31

17

15

325745.633

0.255

521.75294

490.655

501.521

0

32

17

16

31

17

14

325745.633

0.255

521.75294

490.655

501.521

1

32

18

15

31

18

14

325877.090

0.336

362.36216

529.083

539.953

1

32

18

14

31

18

13

325893.284

0.326

362.36216

529.101

539.972

0

32

18

14

31

18

13

325901.848

0.331

362.36216

529.103

539.974

0

32

18

15

31

18

14

325901.848

0.331

362.36216

529.103

539.974

1

32

19

14

31

19

13

326045.227

0.429

343.20816

569.569

580.445

1

32

5

27

31

5

27

326054.695

0.358

343.20816

196.345

207.221


Kolesniková et al.

Page 106


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

32

19

13

31

19

12

0

32

19

14

31

19

1

32

19

13

31

19

1

32

20

13

31

0

32

20

13

31

0

32

20

12

1

32

20

12

1

32

21

0

32

21

0

32

1

32

0 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

326066.401

0.422

343.20816

569.592

580.468

13

326066.401

0.422

343.20816

569.592

580.468

12

326067.393

0.419

343.20816

569.594

580.470

20

12

326225.044

0.537

323.02052

612.076

622.958

20

12

326239.390

0.532

323.01886

612.095

622.977

31

20

11

326239.390

0.532

323.01886

612.095

622.977

31

20

11

326249.776

0.531

323.02052

612.103

622.986

12

31

21

11

326415.766

0.664

301.79591

656.579

667.467

11

31

21

11

326421.144

0.663

301.79591

656.585

667.473

21

12

31

21

10

326421.144

0.663

301.79591

656.585

667.473

21

11

31

21

10

326439.363

0.663

301.79591

656.603

667.492

32

22

10

31

22

9

326612.074

0.818

279.53600

703.033

713.928

32

22

11

31

22

10

326612.074

0.818

279.53600

703.033

713.928

1

32

22

11

31

22

10

326616.387

0.811

279.53600

703.046

713.941

1

32

22

10

31

22

9

326635.373

0.815

279.53600

703.064

713.959

0

32

23

9

31

23

8

326812.502

0.997

256.24244

751.414

762.315

0

32

23

10

31

23

9

326812.502

0.997

256.24244

751.414

762.315

1

32

23

10

31

23

9

326825.751

0.983

256.24244

751.446

762.348

1

32

23

9

31

23

8

326837.350

0.990

256.24244

751.456

762.358

1

32

4

28

31

4

27

326946.107

0.021

521.69330

186.443

197.349

0

32

4

28

31

4

27

326957.414

0.022

521.77447

186.445

197.351

1

34

1

33

33

2

32

327280.851

0.169

30.57256

192.745

203.662

0

34

1

33

33

2

32

327303.599

0.215

30.57456

192.735

203.653

1

17

2

15

16

1

16

327406.255

0.640

2.82411

45.892

56.813

0

17

2

15

16

1

16

327678.409

0.683

2.82457

45.867

56.797

1

33

2

32

32

2

31

329500.448

0.021

543.95322

181.754

192.745

0

33

2

32

32

2

31

329514.577

0.021

543.95322

181.744

192.735

1

33

4

30

32

4

28

330100.046

0.128

0.00000

197.349

208.360

1

32

2

30

31

2

29

330136.940

0.026

527.67820

175.161

186.173

0

32

2

30

31

2

29

330163.902

0.027

527.67820

175.156

186.169

1

32

3

29

31

3

28

330512.878

0.026

525.60759

179.481

190.506

1

31

2

30

30

1

29

330516.809

0.230

26.02788

160.063

171.088

0

31

2

30

30

1

29

330532.874

0.275

26.02880

160.052

171.077

0

32

3

29

31

3

28

330536.309

0.029

525.60759

179.479

190.505

1

38

2

36

37

3

35

330805.713

0.893

20.93489

248.136

259.170

1

34

0

34

33

1

33

331082.345

0.033

45.36228

184.684

195.728

0

34

0

34

33

1

33

331087.614

0.034

45.36243

184.662

195.706

1

33

1

32

32

1

31

331529.171

0.023

544.32758

181.227

192.286

0

33

1

32

32

1

31

331545.626

0.023

544.32758

181.217

192.276

1

32

4

28

31

4

28

331551.451

0.121

544.32758

186.290

197.349

1

34

1

34

33

1

33

331633.790

0.025

562.26240

184.685

195.747

0

34

1

34

33

1

33

331638.038

0.026

562.26240

184.662

195.724


Kolesniková et al.

Page 107


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

34

0

34

33

0

33

0

34

0

34

33

0

1

34

1

34

33

0

0

34

1

34

33

1

33

3

31

32

0

33

3

31

0

33

9

25

0

33

9

1

33

9

0

33

0

33

0 0 1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

331750.076

0.025

562.27234

184.662

195.728

33

331754.321

0.025

562.27234

184.640

195.706

33

332301.521

0.030

45.37042

184.663

195.747

0

33

332304.745

0.032

45.37058

184.640

195.724

3

30

334415.379

0.018

541.83954

189.042

200.197

32

3

30

334429.833

0.018

541.83954

189.040

200.195

32

9

24

335096.910

0.022

505.98812

270.138

281.316

24

32

9

23

335096.910

0.022

505.98812

270.138

281.316

24

32

9

23

335116.463

0.025

505.98812

270.136

281.314

8

26

32

8

25

335116.979

0.021

514.52070

251.030

262.208

8

25

32

8

24

335116.983

0.021

514.52070

251.030

262.208

33

10

24

32

10

23

335121.337

0.027

496.45005

291.468

302.646

33

10

23

32

10

22

335121.337

0.027

496.45005

291.468

302.646

33

9

25

32

9

24

335122.557

0.027

505.98812

270.132

281.310

33

10

23

32

10

22

335131.680

0.029

496.45005

291.467

302.646

1

33

8

26

32

8

25

335138.009

0.028

514.52070

251.022

262.201

1

33

8

25

32

8

24

335142.848

0.021

514.52070

251.023

262.202

1

33

10

24

32

10

23

335147.415

0.030

496.45005

291.462

302.641

1

33

6

28

32

6

26

335162.962

0.960

0.09442

219.540

230.720

1

33

11

22

32

11

21

335178.005

0.037

485.90981

315.002

326.182

0

33

11

23

32

11

21

335178.232

0.041

485.90981

315.002

326.182

0

33

11

22

32

11

22

335178.232

0.041

485.90981

315.002

326.182

1

33

11

23

32

11

22

335200.686

0.039

485.90981

314.997

326.178

0

33

7

27

32

7

26

335202.394

0.019

522.04945

234.158

245.339

0

33

7

26

32

7

25

335202.590

0.019

522.04945

234.158

245.339

1

33

7

26

32

7

25

335215.162

0.026

522.04779

234.151

245.333

1

33

7

27

32

7

26

335230.653

0.018

522.04945

234.148

245.330

1

33

5

29

32

5

27

335242.799

0.303

522.04945

207.221

218.403

1

33

12

21

32

12

20

335249.501

0.054

474.36407

340.722

351.905

0

33

12

21

32

12

20

335259.962

0.058

474.36407

340.724

351.907

0

33

12

22

32

12

21

335259.962

0.058

474.36407

340.724

351.907

1

33

12

22

32

12

21

335275.418

0.055

474.36407

340.720

351.904

1

33

13

21

32

13

20

335342.516

0.079

461.81450

368.612

379.798

0

33

13

20

32

13

20

335361.304

0.078

8.81767

368.617

379.803

0

33

13

21

32

13

19

335361.304

0.078

8.81767

368.617

379.803

1

33

13

20

32

13

19

335367.506

0.077

461.81450

368.616

379.803

0

33

6

28

32

6

27

335391.541

0.016

528.57271

219.544

230.731

1

33

6

27

32

6

26

335396.409

0.022

528.43687

219.539

230.727

0

33

6

27

32

6

26

335397.694

0.016

528.57271

219.544

230.732

1

33

6

28

32

6

27

335420.267

0.018

528.43687

219.532

230.720

1

33

14

20

32

14

19

335454.507

0.110

448.26110

398.656

409.846

1

33

14

19

32

14

18

335474.605

0.107

448.26110

398.663

409.853


Kolesniková et al.

Page 108


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

33

14

20

32

14

19

0

33

14

19

32

14

1

33

15

19

32

15

1

33

15

18

32

0

33

15

19

32

0

33

15

18

1

33

6

27

0

33

5

29

1

33

16

17

1

33

16

0

33

16

0

33

1

33

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

335478.506

0.108

448.26110

398.663

409.853

18

335478.506

0.108

448.26110

398.663

409.853

18

335583.414

0.151

433.70387

430.835

442.029

15

17

335595.496

0.147

433.70387

430.841

442.035

15

18

335608.832

0.149

433.70387

430.842

442.037

32

15

17

335608.832

0.149

433.70387

430.842

442.037

32

6

27

335653.714

0.958

433.70387

219.531

230.727

32

5

28

335725.932

0.016

534.08716

207.212

218.411

32

16

16

335727.365

0.202

418.14280

465.129

476.328

18

32

16

17

335729.636

0.201

418.14280

465.129

476.328

18

32

16

17

335750.313

0.203

418.14280

465.137

476.336

16

17

32

16

16

335750.313

0.203

418.14280

465.137

476.336

5

29

32

5

28

335753.181

0.035

529.43574

207.203

218.403

33

5

28

32

5

27

335833.445

0.034

529.43574

207.221

218.423

33

5

28

32

5

27

335852.653

0.017

534.08716

207.224

218.427

1

33

17

17

32

17

16

335876.823

0.269

401.57790

501.507

512.711

1

33

17

16

32

17

15

335884.572

0.265

401.57790

501.516

512.720

0

33

17

16

32

17

16

335901.621

0.268

401.57790

501.521

512.725

0

33

17

17

32

17

15

335901.621

0.268

401.57790

501.521

512.725

1

33

4

30

32

4

29

335918.064

0.016

538.51662

197.155

208.360

0

33

4

30

32

4

29

335922.762

0.017

538.55969

197.158

208.363

1

33

18

16

32

18

15

336036.919

0.351

384.00917

539.953

551.162

1

33

18

15

32

18

14

336053.334

0.343

384.00917

539.971

551.181

0

33

18

16

32

18

14

336061.974

0.346

4.30190

539.973

551.183

0

33

18

15

32

18

15

336061.974

0.346

4.30190

539.973

551.183

1

33

19

15

32

19

14

336209.644

0.448

365.43660

580.444

591.659

0

33

19

14

32

19

14

336231.062

0.441

0.00000

580.469

591.684

0

33

19

15

32

19

13

336231.062

0.441

0.00000

580.469

591.684

1

33

19

14

32

19

13

336232.089

0.439

365.43660

580.471

591.686

1

33

5

28

32

5

28

336343.827

0.308

0.00497

207.204

218.423

1

33

20

14

32

20

13

336394.465

0.560

345.86020

622.958

634.179

0

33

20

14

32

20

12

336408.952

0.554

345.86020

622.977

634.198

0

33

20

13

32

20

13

336408.952

0.554

345.86020

622.977

634.198

1

33

20

13

32

20

12

336419.474

0.555

345.86020

622.986

634.208

1

33

21

13

32

21

12

336590.566

0.691

325.27832

667.467

678.694

0

33

21

13

32

21

11

336595.952

0.691

325.27832

667.472

678.700

0

33

21

12

32

21

12

336595.952

0.691

325.27832

667.472

678.700

1

33

21

12

32

21

11

336614.386

0.691

325.27832

667.492

678.720

1

30

3

27

29

3

27

336638.968

0.164

12.75162

157.580

168.809

0

33

22

12

32

22

10

336792.459

0.851

6.31984

713.928

725.162

0

33

22

11

32

22

11

336792.459

0.851

6.31984

713.928

725.162

1

33

22

12

32

22

11

336796.896

0.844

303.69425

713.941

725.175


Kolesniková et al.

Page 109


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

33

22

11

32

22

10

1

33

4

29

32

4

0

33

4

29

32

4

1

32

2

31

31

0

32

2

31

31

1

35

1

34

0

35

1

34

1

34

4

1

17

2

1

34

0

34

0 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

336816.018

0.848

303.69425

713.959

725.194

28

337388.691

0.026

538.54643

197.349

208.603

28

337399.919

0.027

538.59116

197.352

208.606

1

30

337799.563

0.213

27.60115

170.486

181.754

1

30

337812.078

0.257

27.60238

170.476

181.744

34

2

33

338607.991

0.155

32.22994

204.060

215.355

34

2

33

338631.971

0.200

32.23194

204.050

215.346

31

33

4

29

338806.358

0.153

6.84985

208.604

219.905

15

16

0

16

339074.917

0.724

0.28160

45.503

56.813

2

33

33

2

32

339223.587

0.023

560.53137

192.745

204.060

2

33

33

2

32

339237.700

0.024

560.53303

192.735

204.051

17

2

15

16

0

16

339365.245

0.771

0.28160

45.477

56.797

33

2

31

32

2

30

340115.412

0.030

544.19672

186.173

197.518

0

33

2

31

32

2

30

340142.066

0.031

544.19506

186.168

197.514

1

35

0

35

34

1

34

340801.939

0.036

46.92048

195.747

207.115

0

35

0

35

34

1

34

340807.121

0.038

46.92048

195.724

207.092

1

34

1

33

33

1

32

341041.358

0.025

560.84113

192.286

203.662

0

34

1

33

33

1

32

341057.241

0.025

560.84113

192.277

203.653

1

33

3

30

32

3

29

341064.928

0.030

542.34808

190.505

201.882

0

33

3

30

32

3

29

341089.204

0.033

542.34973

190.504

201.882

1

35

1

35

34

1

34

341256.743

0.031

578.82730

195.747

207.130

0

35

1

35

34

1

34

341260.931

0.031

578.82730

195.724

207.107

1

35

0

35

34

0

34

341353.384

0.030

578.83558

195.729

207.115

0

35

0

35

34

0

34

341357.546

0.031

578.83558

195.706

207.092

1

35

1

35

34

0

34

341808.188

0.033

46.92694

195.729

207.130

0

35

1

35

34

0

34

341811.356

0.035

46.92694

195.705

207.107

1

33

4

29

32

4

29

343206.709

0.143

3.19703

197.155

208.603

1

34

3

32

33

3

31

344385.149

0.020

558.50051

200.198

211.685

0

34

3

32

33

3

31

344399.900

0.021

558.50051

200.195

211.683

0

34

9

25

33

9

24

345245.572

0.026

523.74901

281.316

292.832

0

34

9

26

33

9

25

345245.572

0.026

523.74901

281.316

292.832

1

34

9

25

33

9

24

345265.532

0.029

523.74901

281.314

292.831

0

34

10

25

33

10

24

345265.765

0.031

514.49254

302.646

314.163

0

34

10

24

33

10

23

345265.765

0.031

514.49254

302.646

314.163

1

34

9

26

33

9

25

345271.517

0.032

523.74901

281.310

292.827

0

34

8

27

33

8

26

345273.229

0.025

532.02980

262.208

273.725

0

34

8

26

33

8

25

345273.235

0.025

532.02980

262.208

273.725

1

34

10

24

33

10

23

345276.384

0.033

514.49254

302.646

314.163

1

33

2

32

32

1

31

345289.678

0.196

29.19503

181.227

192.745

1

34

10

25

33

10

24

345292.189

0.034

514.49254

302.640

314.158

1

34

8

27

33

8

26

345294.428

0.033

532.02980

262.201

273.719

0

33

2

32

32

1

31

345299.268

0.240

29.19641

181.217

192.735


Kolesniková et al.

Page 110


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

34

8

26

33

8

25

1

34

11

23

33

11

0

34

11

23

33

11

0

34

11

24

33

1

34

11

24

33

0

34

7

28

0

34

7

27

1

34

5

1

34

6

1

34

1

34

1

34

0

34

0

34

1

34

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

345299.566

0.025

532.03146

262.202

273.720

22

345320.565

0.042

504.26040

326.181

337.700

22

345320.681

0.046

504.26040

326.181

337.700

11

23

345320.681

0.046

504.26040

326.181

337.700

11

23

345343.459

0.044

504.26040

326.178

337.697

33

7

27

345371.551

0.021

539.33824

245.340

256.860

33

7

26

345371.839

0.021

539.33824

245.340

256.860

30

33

5

28

345372.297

0.246

539.33824

218.423

229.943

29

33

6

27

345378.507

0.953

539.33824

230.727

242.248

7

27

33

7

26

345384.325

0.030

539.33492

245.333

256.854

12

23

33

12

21

345391.523

0.059

0.00000

351.905

363.426

7

28

33

7

27

345400.288

0.022

539.33492

245.330

256.851

12

22

33

12

22

345402.037

0.064

539.33492

351.907

363.428

12

23

33

12

21

345402.037

0.064

539.33492

351.907

363.428

12

22

33

12

22

345417.740

0.060

539.33492

351.904

363.426

34

13

22

33

13

21

345485.227

0.084

480.87408

379.798

391.322

34

13

21

33

13

21

345504.197

0.086

38.19521

379.803

391.328

0

34

13

22

33

13

20

345504.197

0.086

38.19521

379.803

391.328

1

34

13

21

33

13

20

345510.537

0.084

480.87573

379.803

391.328

1

39

2

37

38

3

36

345569.683

0.860

22.39391

260.947

272.474

0

34

6

29

33

6

28

345582.072

0.019

545.66934

230.731

242.258

1

34

6

28

33

6

27

345588.102

0.026

545.31651

230.727

242.255

0

34

6

28

33

6

27

345590.572

0.019

545.66934

230.731

242.259

1

34

14

21

33

14

20

345598.884

0.117

467.71989

409.846

421.374

1

34

6

29

33

6

28

345611.954

0.022

545.31816

230.720

242.248

1

34

14

20

33

14

19

345619.254

0.115

467.71989

409.853

421.382

0

34

14

21

33

14

19

345623.139

0.116

467.71989

409.853

421.382

0

34

14

20

33

14

20

345623.139

0.116

467.71989

409.853

421.382

1

34

15

20

33

15

19

345730.257

0.160

453.59169

442.030

453.562

1

34

15

19

33

15

18

345742.505

0.157

453.59169

442.035

453.568

0

34

15

20

33

15

18

345755.942

0.159

0.43591

442.038

453.571

0

34

15

19

33

15

19

345755.942

0.159

0.43591

442.038

453.571

1

34

6

28

33

6

28

345821.548

0.951

43.41583

230.720

242.255

1

34

16

18

33

16

17

345877.338

0.213

438.48781

476.329

487.866

1

34

16

19

33

16

18

345879.640

0.212

438.48781

476.328

487.865

0

34

16

18

33

16

18

345900.514

0.214

438.48781

476.336

487.874

0

34

16

19

33

16

17

345900.514

0.214

438.48781

476.336

487.874

0

34

5

30

33

5

29

345941.876

0.020

551.01980

218.411

229.950

1

34

5

30

33

5

29

345962.943

0.036

547.42853

218.403

229.943

1

18

2

16

17

1

17

346017.423

0.659

2.61254

51.470

63.012

1

34

17

18

33

17

17

346030.385

0.282

422.40992

512.711

524.253

1

34

17

17

33

17

16

346038.235

0.279

422.40992

512.720

524.263


Kolesniková et al.

Page 111


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

34

17

17

33

17

16

0

34

17

18

33

17

1

34

5

29

33

5

1

34

4

31

33

0

34

4

31

33

0

34

5

29

1

34

18

17

1

34

18

0

34

18

0

34

0

18

1 0


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

346055.433

0.281

422.40992

512.726

524.269

17

346055.433

0.281

422.40992

512.726

524.269

28

346092.221

0.034

547.42853

218.424

229.968

4

30

346095.003

0.019

555.32668

208.361

219.905

4

30

346100.841

0.020

555.35152

208.362

219.907

33

5

28

346105.878

0.021

551.01980

218.427

229.972

33

18

16

346194.546

0.367

405.35801

551.162

562.710

16

33

18

15

346211.161

0.360

405.35801

551.182

562.730

17

33

18

15

346219.856

0.363

405.35801

551.183

562.732

18

16

33

18

16

346219.856

0.363

405.35801

551.183

562.732

2

16

17

1

17

346303.654

0.701

2.61254

51.445

62.996

34

19

16

33

19

15

346371.800

0.467

387.33043

591.659

603.213

34

19

16

33

19

14

346393.424

0.460

387.33043

591.684

603.238

0

34

19

15

33

19

15

346393.424

0.460

387.33043

591.684

603.238

1

34

19

15

33

19

14

346394.492

0.459

387.33043

591.686

603.240

1

34

20

15

33

20

14

346561.571

0.584

368.33049

634.179

645.739

0

34

20

15

33

20

14

346576.168

0.578

368.33049

634.198

645.759

0

34

20

14

33

20

13

346576.168

0.578

368.33049

634.198

645.759

1

34

20

14

33

20

13

346586.818

0.579

368.33049

634.208

645.769

1

34

5

29

33

5

29

346682.867

0.252

0.00000

218.404

229.968

1

34

21

14

33

21

13

346762.999

0.720

348.35488

678.694

690.261

0

34

21

13

33

21

12

346768.374

0.718

348.35488

678.700

690.267

0

34

21

14

33

21

13

346768.374

0.718

348.35488

678.700

690.267

1

34

21

13

33

21

12

346786.999

0.720

348.35488

678.720

690.288

0

34

22

13

33

22

11

346970.423

0.884

4.32841

725.161

736.735

0

34

22

12

33

22

12

346970.423

0.884

4.32841

725.161

736.735

1

34

22

13

33

22

12

346974.989

0.879

327.40525

725.175

736.749

1

34

22

12

33

22

11

346994.207

0.882

327.40525

725.195

736.769

1

35

4

32

34

4

30

347209.076

0.185

305.47995

220.206

231.788

1

34

4

30

33

4

29

347860.095

0.032

555.36975

208.604

220.207

0

34

4

30

33

4

29

347871.622

0.033

555.39459

208.605

220.209

1

35

2

34

34

2

33

348933.176

0.027

577.10786

204.061

215.700

0

35

2

34

34

2

33

348947.245

0.027

577.10786

204.050

215.690

1

36

1

35

35

2

34

349735.098

0.142

33.88501

215.699

227.365

0

36

1

35

35

2

34

349759.857

0.186

33.88701

215.690

227.357

1

34

2

32

33

2

31

350038.331

0.034

560.69867

197.518

209.194

0

34

2

32

33

2

31

350064.524

0.035

560.69702

197.514

209.191

1

36

0

36

35

1

35

350502.059

0.043

48.47653

207.130

218.821

0

36

0

36

35

1

35

350507.139

0.044

48.47653

207.107

218.799

1

35

1

34

34

1

33

350550.726

0.027

577.36296

203.662

215.355

0

35

1

34

34

1

33

350566.072

0.027

577.36296

203.652

215.346

1

36

1

36

35

1

35

350876.699

0.039

595.39220

207.130

218.834


Kolesniková et al.

Page 112


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

0

36

1

36

35

1

35

1

36

0

36

35

0

0

36

0

36

35

0

1

36

1

36

35

0

36

1

36

35

1

34

3

31

0

34

3

31

1

34

2

0

34

2

1

35

0

35

1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

350880.829

0.040

595.39220

207.108

218.812

35

350956.863

0.038

595.39883

207.114

218.821

35

350960.949

0.039

595.39883

207.092

218.799

0

35

351331.503

0.040

48.48176

207.115

218.834

0

35

351334.639

0.042

48.48176

207.093

218.812

33

3

30

351591.379

0.036

559.07697

201.882

213.610

33

3

30

351616.390

0.038

559.07697

201.882

213.611

33

33

1

32

352984.094

0.180

30.80305

192.286

204.060

33

33

1

32

352991.341

0.223

30.80443

192.276

204.051

3

33

34

3

32

354334.532

0.024

575.15155

211.685

223.504

3

33

34

3

32

354349.521

0.024

575.15155

211.683

223.503

34

4

30

33

4

30

355148.740

0.172

0.00000

208.361

220.207

36

4

33

35

4

31

355268.447

0.225

0.00000

232.161

244.011

0

35

9

27

34

9

26

355393.674

0.030

541.44032

292.832

304.687

0

35

9

26

34

9

25

355393.674

0.030

541.44032

292.832

304.687

0

35

10

25

34

10

24

355409.194

0.036

532.44889

314.163

326.018

0

35

10

26

34

10

25

355409.194

0.036

532.44889

314.163

326.018

1

35

9

26

34

9

25

355414.016

0.034

541.44198

292.831

304.686

1

35

9

27

34

9

26

355419.876

0.037

541.44032

292.826

304.682

1

35

10

25

34

10

24

355420.079

0.038

532.44889

314.163

326.019

0

35

8

28

34

8

27

355429.538

0.029

549.48589

273.725

285.581

0

35

8

27

34

8

26

355429.549

0.029

549.48589

273.725

285.581

1

35

10

26

34

10

25

355435.926

0.039

532.44889

314.158

326.014

1

35

8

28

34

8

27

355450.869

0.038

549.48589

273.719

285.576

1

35

5

31

34

5

29

355454.737

0.193

549.48589

229.967

241.824

1

35

8

27

34

8

26

355456.309

0.029

549.48755

273.720

285.577

1

35

11

24

34

11

23

355461.806

0.047

522.50995

337.700

349.557

0

35

11

25

34

11

24

355461.809

0.052

522.50995

337.700

349.557

0

35

11

24

34

11

23

355461.809

0.052

522.50995

337.700

349.557

1

35

11

25

34

11

24

355484.877

0.049

522.50995

337.697

349.555

1

35

12

24

34

12

23

355531.991

0.065

511.62516

363.426

375.285

0

35

7

29

34

7

28

355541.694

0.025

556.58395

256.859

268.719

0

35

7

28

34

7

27

355542.114

0.025

556.58395

256.859

268.719

0

35

12

23

34

12

22

355542.542

0.071

511.62516

363.428

375.288

0

35

12

24

34

12

23

355542.542

0.071

511.62516

363.428

375.288

1

35

7

28

34

7

27

355554.461

0.034

556.57567

256.854

268.714

1

35

12

23

34

12

22

355558.470

0.067

511.62516

363.426

375.286

1

35

7

29

34

7

28

355570.883

0.026

556.57733

256.851

268.712

1

35

6

30

34

6

28

355596.236

0.940

556.57733

242.255

254.116

1

35

13

23

34

13

22

355626.201

0.091

499.79285

391.323

403.185

0

35

13

23

34

13

22

355645.325

0.094

499.79285

391.328

403.191

0

35

13

22

34

13

21

355645.325

0.094

499.79285

391.328

403.191


Kolesniková et al.

Page 113


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

35

13

22

34

13

21

1

35

14

22

34

14

1

35

14

21

34

14

0

35

14

21

34

0

35

14

22

34

0

35

6

30

1

35

6

29

0

35

6

1

35

6

1

35

1

35

0 0 1 1


u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

355651.793

0.091

499.79285

391.328

403.191

21

355741.376

0.125

487.01303

421.374

433.240

20

355761.983

0.124

487.01303

421.381

433.248

14

20

355765.850

0.125

487.01303

421.382

433.249

14

21

355765.850

0.125

487.01303

421.382

433.249

34

6

29

355774.823

0.023

562.73450

242.259

254.126

34

6

28

355782.742

0.031

561.82012

242.255

254.123

29

34

6

28

355786.445

0.023

562.73450

242.259

254.127

30

34

6

29

355805.831

0.026

561.82177

242.248

254.116

15

21

34

15

20

355875.090

0.169

473.28901

453.561

465.432

15

20

34

15

19

355887.481

0.167

473.28901

453.568

465.439

35

15

20

34

15

19

355901.004

0.169

473.28901

453.570

465.442

35

15

21

34

15

20

355901.004

0.169

473.28901

453.570

465.442

35

6

29

34

6

29

355992.337

0.939

473.28901

242.248

254.123

35

16

19

34

16

18

356025.196

0.225

458.61582

487.865

499.741

1

35

16

20

34

16

19

356027.520

0.223

458.61582

487.865

499.741

0

35

16

19

34

16

18

356048.560

0.226

458.61582

487.873

499.750

0

35

16

20

34

16

19

356048.560

0.226

458.61582

487.873

499.750

0

35

5

31

34

5

30

356159.255

0.024

567.93091

229.950

241.830

1

35

5

31

34

5

30

356174.662

0.035

565.65489

229.943

241.824

1

35

17

19

34

17

18

356181.745

0.295

442.99843

524.253

536.134

1

35

17

18

34

17

17

356189.689

0.294

442.99843

524.263

536.144

0

35

17

19

34

17

17

356207.006

0.296

0.00828

524.268

536.150

0

35

17

18

34

17

18

356207.006

0.296

0.00828

524.268

536.150

1

18

2

16

17

0

17

356225.570

0.734

0.28326

51.130

63.012

1

35

4

32

34

4

31

356262.813

0.023

572.11520

219.904

231.788

0

35

4

32

34

4

31

356269.571

0.024

572.12846

219.907

231.791

1

35

18

18

34

18

17

356349.903

0.383

426.43353

562.709

574.596

1

35

5

30

34

5

29

356360.907

0.033

565.65655

229.967

241.854

1

35

18

17

34

18

16

356366.699

0.378

426.43353

562.730

574.617

0

35

5

30

34

5

29

356369.609

0.026

567.93257

229.972

241.859

0

35

18

17

34

18

16

356375.428

0.380

426.43353

562.733

574.620

0

35

18

18

34

18

17

356375.428

0.380

426.43353

562.733

574.620

0

18

2

16

17

0

17

356526.851

0.779

0.28492

51.104

62.996

1

35

19

17

34

19

16

356531.626

0.487

408.92112

603.213

615.106

0

35

19

17

34

19

15

356553.417

0.481

408.92112

603.238

615.131

0

35

19

16

34

19

16

356553.417

0.481

408.92112

603.238

615.131

1

35

19

16

34

19

15

356554.533

0.481

408.92112

603.241

615.134

1

35

20

16

34

20

15

356726.291

0.608

390.46285

645.739

657.638

0

35

20

15

34

20

15

356740.967

0.602

390.46285

645.759

657.659

0

35

20

16

34

20

14

356740.967

0.602

390.46285

645.759

657.659

1

35

20

15

34

20

14

356751.736

0.604

390.46285

645.769

657.669


Kolesniková et al.

Page 114


σa

J′

K a′

K ′c

J″

K a″

K ″c

νpred (MHz)b

1

35

21

15

34

21

14

0

35

21

14

34

21

0

35

21

15

34

21

1

35

21

14

34

1

35

5

30

34

0

35

22

14

0

35

22

13

1

35

22

1

35

22

1

35

0

35

1 0

u(νpred) (MHz)c

S µ2 (D2)d

E′(cm−1)e

E″(cm−1)f

356932.993

0.750

371.05873

690.261

702.167

13

356938.339

0.747

371.05873

690.267

702.173

14

356938.339

0.747

371.05873

690.267

702.173

21

13

356957.133

0.749

371.05873

690.287

702.194

5

30

357080.831

0.202

371.05873

229.943

241.854

34

22

12

357145.895

0.918

0.27995

736.736

748.649

34

22

13

357145.895

0.918

0.27995

736.736

748.649

14

34

22

13

357150.593

0.914

350.70709

736.749

748.662

13

34

22

12

357169.868

0.917

350.70709

736.768

748.682

4

31

34

4

30

358360.717

0.040

572.17484

220.206

232.160

4

31

34

4

30

358372.819

0.041

572.18809

220.209

232.163

36

2

35

35

2

34

358630.018

0.032

593.68105

215.699

227.662

36

2

35

35

2

34

358644.016

0.032

593.68105

215.690

227.653

1

35

2

33

34

2

32

359904.941

0.039

577.18738

209.194

221.199

0

35

2

33

34

2

32

359930.518

0.041

577.18572

209.191

221.197

Notes.

(a) The symmetry numbers σ = 0 and 1 label the A and E transitions, respectively. (b)

Predicted frequency of the rotational transitions.

(c) Uncertainty of the predicted frequency. Only transitions with uncertainty < 1 MHz are included. (d)

Calculated line strengths S multiplied by the square of the corresponding dipole moment component.


(e) Upper state energy. (f)

Lower state energy.


Laboratory measurements and astronomical search for the HSO radical.

Validation experiment of a numerically processed millimeter-wave interferometer in a laboratory.

Rotational study of the NH3-CO complex: millimeter-wave measurements and ab initio calculations.

IMPATT Diodes Based on 〈111〉, 〈100〉, and 〈110〉 Oriented GaAs: A Comparative Study to Search the Best Orientation for Millimeter-Wave Atmospheric Windows.

Thermoreflectance temperature measurement with millimeter wave.

A drunken search in crystallization space.

A 94-GHz millimeter-wave sensor for speech signal acquisition.

Free space millimeter wave-coupled electro-optic high speed nonlinear polymer phase modulator with in-plane slotted patch antennas.

Position Fingerprint-Based Beam Selection in Millimeter Wave Heterogeneous Networks.

Millimeter Wave Radiations Affect Membrane Hydration in Phosphatidylcholine Vesicles.

millimeter wave mirror array beam combiner design and analysis.

Power and polarization monitor development for high power millimeter-wave.

Induced movements of giant vesicles by millimeter wave radiation.

Beamforming Based Full-Duplex for Millimeter-Wave Communication.

Immersive experimentation in a wave propagation laboratory.

Compressive sensing for direct millimeter-wave holographic imaging.

Multi Ray Model for Near-Ground Millimeter Wave Radar.

millimeter-wave spectroscopic study of KSH (X1A').

Variable-delay polarization modulators for cryogenic millimeter-wave applications.

Direct rapid-prototyping fabrication of computer-generated volume holograms in the millimeter-wave and terahertz regime.

Epoxy-based broadband antireflection coating for millimeter-wave optics.

Detection of the Vibration Signal from Human Vocal Folds Using a 94-GHz Millimeter-Wave Radar.

A Novel Method for Speech Acquisition and Enhancement by 94 GHz Millimeter-Wave Sensor.

Crohn's disease in Nottingham: a search for time-space clustering.