A Journal of
Accepted Article Title: Vertically-oriented and tailored-shape electro catalytic metallic nanowires for galactosemia free-enzyme rapid diagnosis Authors: Laura García Carmona, María Cristina González, and Alberto Escarpa This manuscript has been accepted after peer review and appears as an Accepted Article online prior to editing, proofing, and formal publication of the final Version of Record (VoR). This work is currently citable by using the Digital Object Identifier (DOI) given below. The VoR will be published online in Early View as soon as possible and may be different to this Accepted Article as a result of editing. Readers should obtain the VoR from the journal website shown below when it is published to ensure accuracy of information. The authors are responsible for the content of this Accepted Article. To be cited as: Chem. Eur. J. 10.1002/chem.201701213 Link to VoR: http://dx.doi.org/10.1002/chem.201701213
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10.1002/chem.201701213
Chemistry - A European Journal
FULL PAPER Vertically-oriented and shape-tailored electrocatalytic metal nanowire arrays for enzyme-free galactosemia rapid diagnosis. Laura García-Carmona,[a] María Cristina González,[a] Alberto Escarpa*[a]
Abstract: Metallic catalytic nanowires such as nickel and copper nanowires (NWs) for electrochemical detection of carbohydrates involved in metabolic rare diseases are proposed. NWs were electrodeposited using a poly carbonate membrane template, which was cut with the desired shape, stuck in double-sided adhesive tape, pasted into a non-conductive substrate and in situ removed. This simple and versatile approach allowed to obtain NWs vertically oriented (v-NWs) which are contained in the double-sided adhesive tape becoming highly versatile. The high specific surface of working electrode in which the transduction is supported exclusively by the nanomaterial yielded a high analytical performance (extremely low fouling for galactose (RSD
Accepted Article Title: Vertically-oriented and tailored-shape electro catalytic metallic nanowires for galactosemia free-enzyme rapid diagnosis Authors: Laura García Carmona, María Cristina González, and Alberto Escarpa This manuscript has been accepted after peer review and appears as an Accepted Article online prior to editing, proofing, and formal publication of the final Version of Record (VoR). This work is currently citable by using the Digital Object Identifier (DOI) given below. The VoR will be published online in Early View as soon as possible and may be different to this Accepted Article as a result of editing. Readers should obtain the VoR from the journal website shown below when it is published to ensure accuracy of information. The authors are responsible for the content of this Accepted Article. To be cited as: Chem. Eur. J. 10.1002/chem.201701213 Link to VoR: http://dx.doi.org/10.1002/chem.201701213
Supported by
10.1002/chem.201701213
Chemistry - A European Journal
FULL PAPER Vertically-oriented and shape-tailored electrocatalytic metal nanowire arrays for enzyme-free galactosemia rapid diagnosis. Laura García-Carmona,[a] María Cristina González,[a] Alberto Escarpa*[a]
Abstract: Metallic catalytic nanowires such as nickel and copper nanowires (NWs) for electrochemical detection of carbohydrates involved in metabolic rare diseases are proposed. NWs were electrodeposited using a poly carbonate membrane template, which was cut with the desired shape, stuck in double-sided adhesive tape, pasted into a non-conductive substrate and in situ removed. This simple and versatile approach allowed to obtain NWs vertically oriented (v-NWs) which are contained in the double-sided adhesive tape becoming highly versatile. The high specific surface of working electrode in which the transduction is supported exclusively by the nanomaterial yielded a high analytical performance (extremely low fouling for galactose (RSD
